Miscellaneous Questions on Halogen Containing Compounds
CHXII10:HALOALKANES AND HALOARENES

322555 Match Column I with Column II.
1 – Bromopropane is reacted with reagents in Column I to give product in Column II
supporting img

Choose the correct answer from the options given below :

1 A - P, B - R, C - S, D - Q
2 A - R, B - P, C - S, D - Q
3 A - P, B - Q , C - R, D - S
4 A - S, B - R, C - Q , D - P
CHXII10:HALOALKANES AND HALOARENES

322556 In the following sequence of reactions:
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{OH}}\xrightarrow{{{\text{HBr}}}}{\text{A}}\xrightarrow{{{\text{ alc}}{\text{. KOH}}}}{\text{B}}\)
\(\xrightarrow[{{\text{ peroxide }}}]{{{\text{HBr}}}}{\text{C}}\xrightarrow{{{\text{ aq}}{\text{. KOH}}}}{\text{D}}\)
The original compound and \(\mathrm{D}\) are:

1 Same
2 Position isomers
3 Metamers
4 Homologues
CHXII10:HALOALKANES AND HALOARENES

322557 Identify the correct set of reagents or reaction conditions ' X ' and ' Y ' in the following set of transformation.
\({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{Br}}\xrightarrow{{{\text{'x'}}}}{\text{Product}}\)
supporting img

1 \({\mathrm{\mathrm{X}=}}\) dil. aq. \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
2 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}}}\), \({\mathrm{\mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
3 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
4 \({\mathrm{\mathrm{X}=}}\) dil. aq \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
CHXII10:HALOALKANES AND HALOARENES

322558 The reaction between \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}\) and KCN is ____ type.

1 \(\mathrm{S}_{\mathrm{N}} 1\)
2 E1
3 E2
4 \({\rm{S}}{{\rm{N}}_{\rm{2}}}\)
CHXII10:HALOALKANES AND HALOARENES

322555 Match Column I with Column II.
1 – Bromopropane is reacted with reagents in Column I to give product in Column II
supporting img

Choose the correct answer from the options given below :

1 A - P, B - R, C - S, D - Q
2 A - R, B - P, C - S, D - Q
3 A - P, B - Q , C - R, D - S
4 A - S, B - R, C - Q , D - P
CHXII10:HALOALKANES AND HALOARENES

322556 In the following sequence of reactions:
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{OH}}\xrightarrow{{{\text{HBr}}}}{\text{A}}\xrightarrow{{{\text{ alc}}{\text{. KOH}}}}{\text{B}}\)
\(\xrightarrow[{{\text{ peroxide }}}]{{{\text{HBr}}}}{\text{C}}\xrightarrow{{{\text{ aq}}{\text{. KOH}}}}{\text{D}}\)
The original compound and \(\mathrm{D}\) are:

1 Same
2 Position isomers
3 Metamers
4 Homologues
CHXII10:HALOALKANES AND HALOARENES

322557 Identify the correct set of reagents or reaction conditions ' X ' and ' Y ' in the following set of transformation.
\({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{Br}}\xrightarrow{{{\text{'x'}}}}{\text{Product}}\)
supporting img

1 \({\mathrm{\mathrm{X}=}}\) dil. aq. \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
2 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}}}\), \({\mathrm{\mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
3 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
4 \({\mathrm{\mathrm{X}=}}\) dil. aq \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
CHXII10:HALOALKANES AND HALOARENES

322558 The reaction between \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}\) and KCN is ____ type.

1 \(\mathrm{S}_{\mathrm{N}} 1\)
2 E1
3 E2
4 \({\rm{S}}{{\rm{N}}_{\rm{2}}}\)
CHXII10:HALOALKANES AND HALOARENES

322555 Match Column I with Column II.
1 – Bromopropane is reacted with reagents in Column I to give product in Column II
supporting img

Choose the correct answer from the options given below :

1 A - P, B - R, C - S, D - Q
2 A - R, B - P, C - S, D - Q
3 A - P, B - Q , C - R, D - S
4 A - S, B - R, C - Q , D - P
CHXII10:HALOALKANES AND HALOARENES

322556 In the following sequence of reactions:
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{OH}}\xrightarrow{{{\text{HBr}}}}{\text{A}}\xrightarrow{{{\text{ alc}}{\text{. KOH}}}}{\text{B}}\)
\(\xrightarrow[{{\text{ peroxide }}}]{{{\text{HBr}}}}{\text{C}}\xrightarrow{{{\text{ aq}}{\text{. KOH}}}}{\text{D}}\)
The original compound and \(\mathrm{D}\) are:

1 Same
2 Position isomers
3 Metamers
4 Homologues
CHXII10:HALOALKANES AND HALOARENES

322557 Identify the correct set of reagents or reaction conditions ' X ' and ' Y ' in the following set of transformation.
\({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{Br}}\xrightarrow{{{\text{'x'}}}}{\text{Product}}\)
supporting img

1 \({\mathrm{\mathrm{X}=}}\) dil. aq. \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
2 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}}}\), \({\mathrm{\mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
3 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
4 \({\mathrm{\mathrm{X}=}}\) dil. aq \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
CHXII10:HALOALKANES AND HALOARENES

322558 The reaction between \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}\) and KCN is ____ type.

1 \(\mathrm{S}_{\mathrm{N}} 1\)
2 E1
3 E2
4 \({\rm{S}}{{\rm{N}}_{\rm{2}}}\)
CHXII10:HALOALKANES AND HALOARENES

322555 Match Column I with Column II.
1 – Bromopropane is reacted with reagents in Column I to give product in Column II
supporting img

Choose the correct answer from the options given below :

1 A - P, B - R, C - S, D - Q
2 A - R, B - P, C - S, D - Q
3 A - P, B - Q , C - R, D - S
4 A - S, B - R, C - Q , D - P
CHXII10:HALOALKANES AND HALOARENES

322556 In the following sequence of reactions:
\({\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{OH}}\xrightarrow{{{\text{HBr}}}}{\text{A}}\xrightarrow{{{\text{ alc}}{\text{. KOH}}}}{\text{B}}\)
\(\xrightarrow[{{\text{ peroxide }}}]{{{\text{HBr}}}}{\text{C}}\xrightarrow{{{\text{ aq}}{\text{. KOH}}}}{\text{D}}\)
The original compound and \(\mathrm{D}\) are:

1 Same
2 Position isomers
3 Metamers
4 Homologues
CHXII10:HALOALKANES AND HALOARENES

322557 Identify the correct set of reagents or reaction conditions ' X ' and ' Y ' in the following set of transformation.
\({\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{C}}{{\text{H}}_{\text{2}}} - {\text{Br}}\xrightarrow{{{\text{'x'}}}}{\text{Product}}\)
supporting img

1 \({\mathrm{\mathrm{X}=}}\) dil. aq. \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
2 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}}}\), \({\mathrm{\mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
3 \({\mathrm{\mathrm{X}=}}\) conc. alc. \({\mathrm{\mathrm{NaOH}, 80^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{HBr} /}}\) acetic acid
4 \({\mathrm{\mathrm{X}=}}\) dil. aq \({\mathrm{\mathrm{NaOH}, 20^{\circ} \mathrm{C}, \mathrm{Y}=\mathrm{Br}_{2} / \mathrm{CHCl}_{3}}}\)
CHXII10:HALOALKANES AND HALOARENES

322558 The reaction between \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Br}\) and KCN is ____ type.

1 \(\mathrm{S}_{\mathrm{N}} 1\)
2 E1
3 E2
4 \({\rm{S}}{{\rm{N}}_{\rm{2}}}\)