Chemical Reactions of Aldehydes and Ketones
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 \(\mathrm{CH}_{3} \mathrm{COCl}\)
2 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{CH}_{3} \mathrm{ONH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 II \(>\) IV \(>\) I \(>\) III
3 III \(>\) II \(>\) IV \(>\) I
4 IV \(>\) II \(>\) I \(>\) III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
\(\mathrm{RCHO}+\mathrm{H}_{2} \mathrm{NNH}_{2} \longrightarrow \mathrm{RCH}=\mathrm{NNH}_{2}\)
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 \(\mathrm{CH}_{3} \mathrm{COCl}\)
2 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{CH}_{3} \mathrm{ONH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 II \(>\) IV \(>\) I \(>\) III
3 III \(>\) II \(>\) IV \(>\) I
4 IV \(>\) II \(>\) I \(>\) III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
\(\mathrm{RCHO}+\mathrm{H}_{2} \mathrm{NNH}_{2} \longrightarrow \mathrm{RCH}=\mathrm{NNH}_{2}\)
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 \(\mathrm{CH}_{3} \mathrm{COCl}\)
2 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{CH}_{3} \mathrm{ONH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 II \(>\) IV \(>\) I \(>\) III
3 III \(>\) II \(>\) IV \(>\) I
4 IV \(>\) II \(>\) I \(>\) III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
\(\mathrm{RCHO}+\mathrm{H}_{2} \mathrm{NNH}_{2} \longrightarrow \mathrm{RCH}=\mathrm{NNH}_{2}\)
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 \(\mathrm{CH}_{3} \mathrm{COCl}\)
2 \(\mathrm{CH}_{3} \mathrm{COCH}_{3}\)
3 \(\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{CH}_{3} \mathrm{ONH}_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III \(>\) I \(>\) II \(>\) IV
2 II \(>\) IV \(>\) I \(>\) III
3 III \(>\) II \(>\) IV \(>\) I
4 IV \(>\) II \(>\) I \(>\) III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
\(\mathrm{RCHO}+\mathrm{H}_{2} \mathrm{NNH}_{2} \longrightarrow \mathrm{RCH}=\mathrm{NNH}_{2}\)
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction