Chemical Reactions of Aldehydes and Ketones
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 CH3COCl
2 CH3COCH3
3 CH3COOC2H5
4 CH3ONH2
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
RCHO+H2NNH2RCH=NNH2
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 CH3COCl
2 CH3COCH3
3 CH3COOC2H5
4 CH3ONH2
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III > I > II > IV
2 II > IV > I > III
3 III > II > IV > I
4 IV > II > I > III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
RCHO+H2NNH2RCH=NNH2
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 CH3COCl
2 CH3COCH3
3 CH3COOC2H5
4 CH3ONH2
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III > I > II > IV
2 II > IV > I > III
3 III > II > IV > I
4 IV > II > I > III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
RCHO+H2NNH2RCH=NNH2
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323500 Which of the following compounds will give a coloured crystalline compound with
supporting img

1 CH3COCl
2 CH3COCH3
3 CH3COOC2H5
4 CH3ONH2
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323501 Statement A :
Sodium hydrogensulphite adds to aldehyde and ketones is the useful method for separation and the purification of aldehydes.
Statement B :
The hydrogensulphite addition compound is water soluble and can be converted back to the original carbonyl compound by treating it with dilute mineral acid or alkali.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323502 Observe the following compounds
The correct reactivity order of below compounds towards nucleophilic addition reaction is
supporting img

1 III > I > II > IV
2 II > IV > I > III
3 III > II > IV > I
4 IV > II > I > III
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323503 Consider the reaction:
RCHO+H2NNH2RCH=NNH2
What sort of reaction is it?

1 Electrophilic substitution - elimination reaction
2 Electrophilic addition - elimination reaction
3 Nucleophilic addition- elimination reaction
4 Free radical addition - elimination reaction