Miscellaneous Questions based on Alcohols, Phenols and Ethers
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323020 Glycerine has one \({\mathrm{2^{\circ}}}\) and ____ \({\mathrm{1^{\circ}}}\) alcoholic groups.

1 1
2 2
3 3
4 4
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323021 Identify ( Z ) in the following series
Ethanol \(\xrightarrow{\mathrm{PBr}_{3}}(\mathrm{~W}) \xrightarrow{\mathrm{Alc} . \mathrm{KOH}}\)
\(({\text{X}})\xrightarrow[{{{\text{H}}_{\text{2}}}{\text{O}}\,;\,\,{\text{heat}}}]{{({\text{i}})\,\,{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}/{\text{Room}}\,{\text{temp}}}}({\text{Y}})\xrightarrow[{({\text{ii}})\,\,{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{Br}}}]{{({\text{i}})\,\,{\text{Na}}}}({\text{Z}})\)

1 \(\mathrm{CH}_{2}=\mathrm{CH}_{2}\)
2 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{OH}\)
3 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{SO}_{3} \mathrm{H}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323022 Assertion :
Alcohols are easily protonated as compared to phenols.
Reason :
Alcohols undergo intermolecular hydrogen bonding due to the presence of highly electronegative oxygen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323023 The decrease in stability of cyclohexanol is due to

1 skew interaction
2 flag-pole interaction
3 Baeyer's strain
4 1,3-diaxial interaction.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323020 Glycerine has one \({\mathrm{2^{\circ}}}\) and ____ \({\mathrm{1^{\circ}}}\) alcoholic groups.

1 1
2 2
3 3
4 4
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323021 Identify ( Z ) in the following series
Ethanol \(\xrightarrow{\mathrm{PBr}_{3}}(\mathrm{~W}) \xrightarrow{\mathrm{Alc} . \mathrm{KOH}}\)
\(({\text{X}})\xrightarrow[{{{\text{H}}_{\text{2}}}{\text{O}}\,;\,\,{\text{heat}}}]{{({\text{i}})\,\,{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}/{\text{Room}}\,{\text{temp}}}}({\text{Y}})\xrightarrow[{({\text{ii}})\,\,{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{Br}}}]{{({\text{i}})\,\,{\text{Na}}}}({\text{Z}})\)

1 \(\mathrm{CH}_{2}=\mathrm{CH}_{2}\)
2 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{OH}\)
3 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{SO}_{3} \mathrm{H}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323022 Assertion :
Alcohols are easily protonated as compared to phenols.
Reason :
Alcohols undergo intermolecular hydrogen bonding due to the presence of highly electronegative oxygen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323023 The decrease in stability of cyclohexanol is due to

1 skew interaction
2 flag-pole interaction
3 Baeyer's strain
4 1,3-diaxial interaction.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323020 Glycerine has one \({\mathrm{2^{\circ}}}\) and ____ \({\mathrm{1^{\circ}}}\) alcoholic groups.

1 1
2 2
3 3
4 4
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323021 Identify ( Z ) in the following series
Ethanol \(\xrightarrow{\mathrm{PBr}_{3}}(\mathrm{~W}) \xrightarrow{\mathrm{Alc} . \mathrm{KOH}}\)
\(({\text{X}})\xrightarrow[{{{\text{H}}_{\text{2}}}{\text{O}}\,;\,\,{\text{heat}}}]{{({\text{i}})\,\,{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}/{\text{Room}}\,{\text{temp}}}}({\text{Y}})\xrightarrow[{({\text{ii}})\,\,{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{Br}}}]{{({\text{i}})\,\,{\text{Na}}}}({\text{Z}})\)

1 \(\mathrm{CH}_{2}=\mathrm{CH}_{2}\)
2 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{OH}\)
3 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{SO}_{3} \mathrm{H}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323022 Assertion :
Alcohols are easily protonated as compared to phenols.
Reason :
Alcohols undergo intermolecular hydrogen bonding due to the presence of highly electronegative oxygen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323023 The decrease in stability of cyclohexanol is due to

1 skew interaction
2 flag-pole interaction
3 Baeyer's strain
4 1,3-diaxial interaction.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323020 Glycerine has one \({\mathrm{2^{\circ}}}\) and ____ \({\mathrm{1^{\circ}}}\) alcoholic groups.

1 1
2 2
3 3
4 4
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323021 Identify ( Z ) in the following series
Ethanol \(\xrightarrow{\mathrm{PBr}_{3}}(\mathrm{~W}) \xrightarrow{\mathrm{Alc} . \mathrm{KOH}}\)
\(({\text{X}})\xrightarrow[{{{\text{H}}_{\text{2}}}{\text{O}}\,;\,\,{\text{heat}}}]{{({\text{i}})\,\,{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}/{\text{Room}}\,{\text{temp}}}}({\text{Y}})\xrightarrow[{({\text{ii}})\,\,{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{Br}}}]{{({\text{i}})\,\,{\text{Na}}}}({\text{Z}})\)

1 \(\mathrm{CH}_{2}=\mathrm{CH}_{2}\)
2 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{OH}\)
3 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{SO}_{3} \mathrm{H}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323022 Assertion :
Alcohols are easily protonated as compared to phenols.
Reason :
Alcohols undergo intermolecular hydrogen bonding due to the presence of highly electronegative oxygen.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323023 The decrease in stability of cyclohexanol is due to

1 skew interaction
2 flag-pole interaction
3 Baeyer's strain
4 1,3-diaxial interaction.