Valence Bond Theory
« Previous Topic: Types of Addition Compounds Next Topic: Werner’s Theory of Coordination Compounds »
CHXII09:COORDINATION COMPOUNDS

322311 The correct order of spin only magnetic moments for the following complex ions is

1 \({\left[ {{\text{Fe}}{{({\text{CN}})}_6}} \right]^{3 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\) \( < {\left[ {{\text{Co}}{{\text{F}}_6}} \right]^{3 - }} < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }}\)
2 \(\left[\mathrm{CoF}_{6}\right]^{3-} < \left[\mathrm{MnBr}_{4}\right]^{2-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
3 \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\)
4 \(\left[\mathrm{MnBr}_{4}\right]^{2-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322312 Which of the following complexes will exhibit maximum attraction to an applied magnetic field?

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
2 \(\left[\operatorname{Co}(\mathrm{en})_{3}\right]^{3+}\)
3 \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
4 \(\left[\mathrm{Zn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322313 \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\) is paramagnetic while \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is diamagnetic because

1 \(\mathrm{Cr}^{3+}\) has \(\mathrm{d}^{3}\) configuration while \(\mathrm{Ni}^{2+}\) had \(\mathrm{d}^{8}\) configuration
2 \(\mathrm{Cr}^{3+}\) form \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation while \(\mathrm{Ni}^{2+}\) forms dsp \({ }^{2}\) hybridisation
3 There are 3, 0 unpaired electrons in \(\mathrm{Cr}^{3+}\) and \(\mathrm{Ni}^{2+}\)
4 All the above
CHXII09:COORDINATION COMPOUNDS

322314 Which of the following complexes exhibits the highest paramagnetic behaviour?

1 \(\left[\mathrm{Ti}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
2 \({\left[ {{\rm{Fe( en )(bpy)}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{2}}}} \right]^{{\rm{2 + }}}}\)
3 \(\left[\mathrm{Co}(\mathrm{ox})_{2}(\mathrm{OH})_{2}\right]^{-}\)
4 \(\left[\mathrm{V}(\mathrm{gly})_{2}(\mathrm{OH})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\)
For More Updates join with Us
CHXII09:COORDINATION COMPOUNDS

322311 The correct order of spin only magnetic moments for the following complex ions is

1 \({\left[ {{\text{Fe}}{{({\text{CN}})}_6}} \right]^{3 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\) \( < {\left[ {{\text{Co}}{{\text{F}}_6}} \right]^{3 - }} < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }}\)
2 \(\left[\mathrm{CoF}_{6}\right]^{3-} < \left[\mathrm{MnBr}_{4}\right]^{2-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
3 \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\)
4 \(\left[\mathrm{MnBr}_{4}\right]^{2-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322312 Which of the following complexes will exhibit maximum attraction to an applied magnetic field?

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
2 \(\left[\operatorname{Co}(\mathrm{en})_{3}\right]^{3+}\)
3 \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
4 \(\left[\mathrm{Zn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322313 \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\) is paramagnetic while \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is diamagnetic because

1 \(\mathrm{Cr}^{3+}\) has \(\mathrm{d}^{3}\) configuration while \(\mathrm{Ni}^{2+}\) had \(\mathrm{d}^{8}\) configuration
2 \(\mathrm{Cr}^{3+}\) form \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation while \(\mathrm{Ni}^{2+}\) forms dsp \({ }^{2}\) hybridisation
3 There are 3, 0 unpaired electrons in \(\mathrm{Cr}^{3+}\) and \(\mathrm{Ni}^{2+}\)
4 All the above
CHXII09:COORDINATION COMPOUNDS

322314 Which of the following complexes exhibits the highest paramagnetic behaviour?

1 \(\left[\mathrm{Ti}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
2 \({\left[ {{\rm{Fe( en )(bpy)}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{2}}}} \right]^{{\rm{2 + }}}}\)
3 \(\left[\mathrm{Co}(\mathrm{ox})_{2}(\mathrm{OH})_{2}\right]^{-}\)
4 \(\left[\mathrm{V}(\mathrm{gly})_{2}(\mathrm{OH})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\)
NEET DIGITAL LIBRARY
CHXII09:COORDINATION COMPOUNDS

322311 The correct order of spin only magnetic moments for the following complex ions is

1 \({\left[ {{\text{Fe}}{{({\text{CN}})}_6}} \right]^{3 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\) \( < {\left[ {{\text{Co}}{{\text{F}}_6}} \right]^{3 - }} < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }}\)
2 \(\left[\mathrm{CoF}_{6}\right]^{3-} < \left[\mathrm{MnBr}_{4}\right]^{2-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
3 \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\)
4 \(\left[\mathrm{MnBr}_{4}\right]^{2-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322312 Which of the following complexes will exhibit maximum attraction to an applied magnetic field?

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
2 \(\left[\operatorname{Co}(\mathrm{en})_{3}\right]^{3+}\)
3 \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
4 \(\left[\mathrm{Zn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322313 \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\) is paramagnetic while \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is diamagnetic because

1 \(\mathrm{Cr}^{3+}\) has \(\mathrm{d}^{3}\) configuration while \(\mathrm{Ni}^{2+}\) had \(\mathrm{d}^{8}\) configuration
2 \(\mathrm{Cr}^{3+}\) form \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation while \(\mathrm{Ni}^{2+}\) forms dsp \({ }^{2}\) hybridisation
3 There are 3, 0 unpaired electrons in \(\mathrm{Cr}^{3+}\) and \(\mathrm{Ni}^{2+}\)
4 All the above
CHXII09:COORDINATION COMPOUNDS

322314 Which of the following complexes exhibits the highest paramagnetic behaviour?

1 \(\left[\mathrm{Ti}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
2 \({\left[ {{\rm{Fe( en )(bpy)}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{2}}}} \right]^{{\rm{2 + }}}}\)
3 \(\left[\mathrm{Co}(\mathrm{ox})_{2}(\mathrm{OH})_{2}\right]^{-}\)
4 \(\left[\mathrm{V}(\mathrm{gly})_{2}(\mathrm{OH})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\)
Join With Us for More Updates
CHXII09:COORDINATION COMPOUNDS

322311 The correct order of spin only magnetic moments for the following complex ions is

1 \({\left[ {{\text{Fe}}{{({\text{CN}})}_6}} \right]^{3 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\) \( < {\left[ {{\text{Co}}{{\text{F}}_6}} \right]^{3 - }} < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }}\)
2 \(\left[\mathrm{CoF}_{6}\right]^{3-} < \left[\mathrm{MnBr}_{4}\right]^{2-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
3 \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < {\left[ {{\text{MnB}}{{\text{r}}_4}} \right]^{2 - }} < {\left[ {{\text{Mn}}{{({\text{CN}})}_6}} \right]^{3 - }}\)
4 \(\left[\mathrm{MnBr}_{4}\right]^{2-} < \left[\mathrm{CoF}_{6}\right]^{3-}\) \( < \left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-} < \left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322312 Which of the following complexes will exhibit maximum attraction to an applied magnetic field?

1 \(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
2 \(\left[\operatorname{Co}(\mathrm{en})_{3}\right]^{3+}\)
3 \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
4 \(\left[\mathrm{Zn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\)
JEE - 2023
CHXII09:COORDINATION COMPOUNDS

322313 \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\) is paramagnetic while \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is diamagnetic because

1 \(\mathrm{Cr}^{3+}\) has \(\mathrm{d}^{3}\) configuration while \(\mathrm{Ni}^{2+}\) had \(\mathrm{d}^{8}\) configuration
2 \(\mathrm{Cr}^{3+}\) form \(\mathrm{d}^{2} \mathrm{sp}^{3}\) hybridisation while \(\mathrm{Ni}^{2+}\) forms dsp \({ }^{2}\) hybridisation
3 There are 3, 0 unpaired electrons in \(\mathrm{Cr}^{3+}\) and \(\mathrm{Ni}^{2+}\)
4 All the above
CHXII09:COORDINATION COMPOUNDS

322314 Which of the following complexes exhibits the highest paramagnetic behaviour?

1 \(\left[\mathrm{Ti}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
2 \({\left[ {{\rm{Fe( en )(bpy)}}{{\left( {{\rm{N}}{{\rm{H}}_{\rm{3}}}} \right)}_{\rm{2}}}} \right]^{{\rm{2 + }}}}\)
3 \(\left[\mathrm{Co}(\mathrm{ox})_{2}(\mathrm{OH})_{2}\right]^{-}\)
4 \(\left[\mathrm{V}(\mathrm{gly})_{2}(\mathrm{OH})_{2}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\)
For More Updates join with Us