Valence Bond Theory
« Previous Topic: Types of Addition Compounds Next Topic: Werner’s Theory of Coordination Compounds »
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII09:COORDINATION COMPOUNDS

322264 Which of the following has square planar geometry?

1 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
2 \(\left[\mathrm{NiCl}_{4}\right]^{2-}\)
3 \(\left[\mathrm{ZnCl}_{4}\right]^{2-}\)
4 \(\left[\mathrm{CoCl}_{4}\right]^{2-}\)
CHXII09:COORDINATION COMPOUNDS

322265 Match List - I with List - II
Column I
Column II
A
\(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
P
\(\quad \mathrm{sp}^{3} \mathrm{~d}\)
B
\(\quad \mathrm{BrF}_{5}\)
Q
\(\mathrm{d}^{2} \mathrm{sp}^{3}\)
C
\(\mathrm{PCl}_{5}\)
R
\(\mathrm{dsp}^{2}\)
D
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
S
\(\mathrm{sp}^{3} \mathrm{~d}^{2}\)

1 \({\text{A - Q,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - P}}\)
2 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - Q}}\)
3 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - Q}}\)
4 \({\text{A - Q,}}\,\,\,\,{\text{B - P,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - R}}\)
JEE - 2022
CHXII09:COORDINATION COMPOUNDS

322266 Read the Statement A and Statement B carefully to mark the correct options given below:
Statement A :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\) has lower stability than \(\left[\mathrm{Ni}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}\).
Statement B :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\), the geometry of Ni is trigonal bipyramidal.

1 Both Statements are correct
2 Both Statements are incorrect
3 Statement A is correct but Statement B is incorrect
4 Statement A is incorrect but Statement B is correct
CHXII09:COORDINATION COMPOUNDS

322267 The hybridisation state of \(\mathrm{Fe}\) in
\(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{NO}_{3} \mathrm{SO}_{4}\right.\) is (At. \(\mathrm{No}\). of \(\mathrm{Fe}=26\) )

1 \(\mathrm{sp}^{3} \mathrm{~d}\)
2 \(\mathrm{dsp}^{2}\)
3 \(\mathrm{sp}^{3} \mathrm{~d}^{2}\)
4 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
NEET DIGITAL LIBRARY
CHXII09:COORDINATION COMPOUNDS

322264 Which of the following has square planar geometry?

1 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
2 \(\left[\mathrm{NiCl}_{4}\right]^{2-}\)
3 \(\left[\mathrm{ZnCl}_{4}\right]^{2-}\)
4 \(\left[\mathrm{CoCl}_{4}\right]^{2-}\)
CHXII09:COORDINATION COMPOUNDS

322265 Match List - I with List - II
Column I
Column II
A
\(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
P
\(\quad \mathrm{sp}^{3} \mathrm{~d}\)
B
\(\quad \mathrm{BrF}_{5}\)
Q
\(\mathrm{d}^{2} \mathrm{sp}^{3}\)
C
\(\mathrm{PCl}_{5}\)
R
\(\mathrm{dsp}^{2}\)
D
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
S
\(\mathrm{sp}^{3} \mathrm{~d}^{2}\)

1 \({\text{A - Q,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - P}}\)
2 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - Q}}\)
3 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - Q}}\)
4 \({\text{A - Q,}}\,\,\,\,{\text{B - P,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - R}}\)
JEE - 2022
CHXII09:COORDINATION COMPOUNDS

322266 Read the Statement A and Statement B carefully to mark the correct options given below:
Statement A :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\) has lower stability than \(\left[\mathrm{Ni}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}\).
Statement B :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\), the geometry of Ni is trigonal bipyramidal.

1 Both Statements are correct
2 Both Statements are incorrect
3 Statement A is correct but Statement B is incorrect
4 Statement A is incorrect but Statement B is correct
CHXII09:COORDINATION COMPOUNDS

322267 The hybridisation state of \(\mathrm{Fe}\) in
\(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{NO}_{3} \mathrm{SO}_{4}\right.\) is (At. \(\mathrm{No}\). of \(\mathrm{Fe}=26\) )

1 \(\mathrm{sp}^{3} \mathrm{~d}\)
2 \(\mathrm{dsp}^{2}\)
3 \(\mathrm{sp}^{3} \mathrm{~d}^{2}\)
4 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
Join With Us for More Updates
CHXII09:COORDINATION COMPOUNDS

322264 Which of the following has square planar geometry?

1 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
2 \(\left[\mathrm{NiCl}_{4}\right]^{2-}\)
3 \(\left[\mathrm{ZnCl}_{4}\right]^{2-}\)
4 \(\left[\mathrm{CoCl}_{4}\right]^{2-}\)
CHXII09:COORDINATION COMPOUNDS

322265 Match List - I with List - II
Column I
Column II
A
\(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
P
\(\quad \mathrm{sp}^{3} \mathrm{~d}\)
B
\(\quad \mathrm{BrF}_{5}\)
Q
\(\mathrm{d}^{2} \mathrm{sp}^{3}\)
C
\(\mathrm{PCl}_{5}\)
R
\(\mathrm{dsp}^{2}\)
D
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
S
\(\mathrm{sp}^{3} \mathrm{~d}^{2}\)

1 \({\text{A - Q,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - P}}\)
2 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - Q}}\)
3 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - Q}}\)
4 \({\text{A - Q,}}\,\,\,\,{\text{B - P,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - R}}\)
JEE - 2022
CHXII09:COORDINATION COMPOUNDS

322266 Read the Statement A and Statement B carefully to mark the correct options given below:
Statement A :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\) has lower stability than \(\left[\mathrm{Ni}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}\).
Statement B :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\), the geometry of Ni is trigonal bipyramidal.

1 Both Statements are correct
2 Both Statements are incorrect
3 Statement A is correct but Statement B is incorrect
4 Statement A is incorrect but Statement B is correct
CHXII09:COORDINATION COMPOUNDS

322267 The hybridisation state of \(\mathrm{Fe}\) in
\(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{NO}_{3} \mathrm{SO}_{4}\right.\) is (At. \(\mathrm{No}\). of \(\mathrm{Fe}=26\) )

1 \(\mathrm{sp}^{3} \mathrm{~d}\)
2 \(\mathrm{dsp}^{2}\)
3 \(\mathrm{sp}^{3} \mathrm{~d}^{2}\)
4 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
For More Updates join with Us
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII09:COORDINATION COMPOUNDS

322264 Which of the following has square planar geometry?

1 \(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
2 \(\left[\mathrm{NiCl}_{4}\right]^{2-}\)
3 \(\left[\mathrm{ZnCl}_{4}\right]^{2-}\)
4 \(\left[\mathrm{CoCl}_{4}\right]^{2-}\)
CHXII09:COORDINATION COMPOUNDS

322265 Match List - I with List - II
Column I
Column II
A
\(\left[\mathrm{PtCl}_{4}\right]^{2-}\)
P
\(\quad \mathrm{sp}^{3} \mathrm{~d}\)
B
\(\quad \mathrm{BrF}_{5}\)
Q
\(\mathrm{d}^{2} \mathrm{sp}^{3}\)
C
\(\mathrm{PCl}_{5}\)
R
\(\mathrm{dsp}^{2}\)
D
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\)
S
\(\mathrm{sp}^{3} \mathrm{~d}^{2}\)

1 \({\text{A - Q,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - P}}\)
2 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - P,}}\,\,\,\,\,{\text{D - Q}}\)
3 \({\text{A - R,}}\,\,\,\,{\text{B - S,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - Q}}\)
4 \({\text{A - Q,}}\,\,\,\,{\text{B - P,}}\,\,\,\,{\text{C - S,}}\,\,\,\,\,{\text{D - R}}\)
JEE - 2022
CHXII09:COORDINATION COMPOUNDS

322266 Read the Statement A and Statement B carefully to mark the correct options given below:
Statement A :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\) has lower stability than \(\left[\mathrm{Ni}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{2}\).
Statement B :
\(\operatorname{In}\left[\mathrm{Ni}(\mathrm{en})_{3}\right] \mathrm{Cl}_{2}\), the geometry of Ni is trigonal bipyramidal.

1 Both Statements are correct
2 Both Statements are incorrect
3 Statement A is correct but Statement B is incorrect
4 Statement A is incorrect but Statement B is correct
CHXII09:COORDINATION COMPOUNDS

322267 The hybridisation state of \(\mathrm{Fe}\) in
\(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{5} \mathrm{NO}_{3} \mathrm{SO}_{4}\right.\) is (At. \(\mathrm{No}\). of \(\mathrm{Fe}=26\) )

1 \(\mathrm{sp}^{3} \mathrm{~d}\)
2 \(\mathrm{dsp}^{2}\)
3 \(\mathrm{sp}^{3} \mathrm{~d}^{2}\)
4 \(\mathrm{d}^{2} \mathrm{sp}^{3}\)
NEET DIGITAL LIBRARY