Valence Bond Theory
CHXII09:COORDINATION COMPOUNDS

322268 Which among the following statements about \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is NOT true?

1 In this, electrons are paired prior to hybridization.
2 Oxidation state of \(\mathrm{Ni}\) is +6
3 Ni undergoes dsp \({ }^{2}\) hybridization
4 It is a square planar complex
CHXII09:COORDINATION COMPOUNDS

322269 \(\mathrm{Ag}^{+}\)forms many complexes, some of these are \(\left[\operatorname{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+},\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}\)and \(\left[\operatorname{Ag}\left(\mathrm{S}_{2} \mathrm{O}_{3}\right)_{2}\right]^{3-}\).
Which of the following statement is true?

1 In these complexes, \(\mathrm{Ag}^{+}\)is a Lewis base.
2 The hybridisation of \({\rm{A}}{{\rm{g}}^{{\rm{ + }}}}\) is \({\rm{s}}{{\rm{p}}^{\rm{2}}}{\rm{.}}\)
3 The \(\mathrm{Ag}^{+}\)complexes are good reducing agents.
4 These complexes are all linear.
CHXII09:COORDINATION COMPOUNDS

322270 Match Column I with Column II
supporting img

1 \({\rm{A}} - {\rm{P,B}} - {\rm{R,C}} - {\rm{Q,D}} - {\rm{S}}\)
2 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{S,D}} - {\rm{Q}}\)
3 \({\rm{A}} - {\rm{R,B}} - {\rm{Q,C}} - {\rm{S,D}} - {\rm{P}}\)
4 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{Q,D}} - {\rm{S}}\)
CHXII09:COORDINATION COMPOUNDS

322271 Assertion :
\(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) and \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) are reducing in nature.
Reason :
Unpaired electrons are present in their d-orbitals.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII09:COORDINATION COMPOUNDS

322272 In the complex ion \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\), the \(\mathrm{NH}_{3}\) molecules are linked to the central metal ion by

1 ionic bonds
2 covalent bonds
3 coordinate bonds
4 hydrogen bonds
CHXII09:COORDINATION COMPOUNDS

322268 Which among the following statements about \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is NOT true?

1 In this, electrons are paired prior to hybridization.
2 Oxidation state of \(\mathrm{Ni}\) is +6
3 Ni undergoes dsp \({ }^{2}\) hybridization
4 It is a square planar complex
CHXII09:COORDINATION COMPOUNDS

322269 \(\mathrm{Ag}^{+}\)forms many complexes, some of these are \(\left[\operatorname{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+},\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}\)and \(\left[\operatorname{Ag}\left(\mathrm{S}_{2} \mathrm{O}_{3}\right)_{2}\right]^{3-}\).
Which of the following statement is true?

1 In these complexes, \(\mathrm{Ag}^{+}\)is a Lewis base.
2 The hybridisation of \({\rm{A}}{{\rm{g}}^{{\rm{ + }}}}\) is \({\rm{s}}{{\rm{p}}^{\rm{2}}}{\rm{.}}\)
3 The \(\mathrm{Ag}^{+}\)complexes are good reducing agents.
4 These complexes are all linear.
CHXII09:COORDINATION COMPOUNDS

322270 Match Column I with Column II
supporting img

1 \({\rm{A}} - {\rm{P,B}} - {\rm{R,C}} - {\rm{Q,D}} - {\rm{S}}\)
2 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{S,D}} - {\rm{Q}}\)
3 \({\rm{A}} - {\rm{R,B}} - {\rm{Q,C}} - {\rm{S,D}} - {\rm{P}}\)
4 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{Q,D}} - {\rm{S}}\)
CHXII09:COORDINATION COMPOUNDS

322271 Assertion :
\(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) and \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) are reducing in nature.
Reason :
Unpaired electrons are present in their d-orbitals.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII09:COORDINATION COMPOUNDS

322272 In the complex ion \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\), the \(\mathrm{NH}_{3}\) molecules are linked to the central metal ion by

1 ionic bonds
2 covalent bonds
3 coordinate bonds
4 hydrogen bonds
CHXII09:COORDINATION COMPOUNDS

322268 Which among the following statements about \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is NOT true?

1 In this, electrons are paired prior to hybridization.
2 Oxidation state of \(\mathrm{Ni}\) is +6
3 Ni undergoes dsp \({ }^{2}\) hybridization
4 It is a square planar complex
CHXII09:COORDINATION COMPOUNDS

322269 \(\mathrm{Ag}^{+}\)forms many complexes, some of these are \(\left[\operatorname{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+},\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}\)and \(\left[\operatorname{Ag}\left(\mathrm{S}_{2} \mathrm{O}_{3}\right)_{2}\right]^{3-}\).
Which of the following statement is true?

1 In these complexes, \(\mathrm{Ag}^{+}\)is a Lewis base.
2 The hybridisation of \({\rm{A}}{{\rm{g}}^{{\rm{ + }}}}\) is \({\rm{s}}{{\rm{p}}^{\rm{2}}}{\rm{.}}\)
3 The \(\mathrm{Ag}^{+}\)complexes are good reducing agents.
4 These complexes are all linear.
CHXII09:COORDINATION COMPOUNDS

322270 Match Column I with Column II
supporting img

1 \({\rm{A}} - {\rm{P,B}} - {\rm{R,C}} - {\rm{Q,D}} - {\rm{S}}\)
2 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{S,D}} - {\rm{Q}}\)
3 \({\rm{A}} - {\rm{R,B}} - {\rm{Q,C}} - {\rm{S,D}} - {\rm{P}}\)
4 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{Q,D}} - {\rm{S}}\)
CHXII09:COORDINATION COMPOUNDS

322271 Assertion :
\(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) and \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) are reducing in nature.
Reason :
Unpaired electrons are present in their d-orbitals.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII09:COORDINATION COMPOUNDS

322272 In the complex ion \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\), the \(\mathrm{NH}_{3}\) molecules are linked to the central metal ion by

1 ionic bonds
2 covalent bonds
3 coordinate bonds
4 hydrogen bonds
CHXII09:COORDINATION COMPOUNDS

322268 Which among the following statements about \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is NOT true?

1 In this, electrons are paired prior to hybridization.
2 Oxidation state of \(\mathrm{Ni}\) is +6
3 Ni undergoes dsp \({ }^{2}\) hybridization
4 It is a square planar complex
CHXII09:COORDINATION COMPOUNDS

322269 \(\mathrm{Ag}^{+}\)forms many complexes, some of these are \(\left[\operatorname{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+},\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}\)and \(\left[\operatorname{Ag}\left(\mathrm{S}_{2} \mathrm{O}_{3}\right)_{2}\right]^{3-}\).
Which of the following statement is true?

1 In these complexes, \(\mathrm{Ag}^{+}\)is a Lewis base.
2 The hybridisation of \({\rm{A}}{{\rm{g}}^{{\rm{ + }}}}\) is \({\rm{s}}{{\rm{p}}^{\rm{2}}}{\rm{.}}\)
3 The \(\mathrm{Ag}^{+}\)complexes are good reducing agents.
4 These complexes are all linear.
CHXII09:COORDINATION COMPOUNDS

322270 Match Column I with Column II
supporting img

1 \({\rm{A}} - {\rm{P,B}} - {\rm{R,C}} - {\rm{Q,D}} - {\rm{S}}\)
2 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{S,D}} - {\rm{Q}}\)
3 \({\rm{A}} - {\rm{R,B}} - {\rm{Q,C}} - {\rm{S,D}} - {\rm{P}}\)
4 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{Q,D}} - {\rm{S}}\)
CHXII09:COORDINATION COMPOUNDS

322271 Assertion :
\(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) and \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) are reducing in nature.
Reason :
Unpaired electrons are present in their d-orbitals.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII09:COORDINATION COMPOUNDS

322272 In the complex ion \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\), the \(\mathrm{NH}_{3}\) molecules are linked to the central metal ion by

1 ionic bonds
2 covalent bonds
3 coordinate bonds
4 hydrogen bonds
CHXII09:COORDINATION COMPOUNDS

322268 Which among the following statements about \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) is NOT true?

1 In this, electrons are paired prior to hybridization.
2 Oxidation state of \(\mathrm{Ni}\) is +6
3 Ni undergoes dsp \({ }^{2}\) hybridization
4 It is a square planar complex
CHXII09:COORDINATION COMPOUNDS

322269 \(\mathrm{Ag}^{+}\)forms many complexes, some of these are \(\left[\operatorname{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+},\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}\)and \(\left[\operatorname{Ag}\left(\mathrm{S}_{2} \mathrm{O}_{3}\right)_{2}\right]^{3-}\).
Which of the following statement is true?

1 In these complexes, \(\mathrm{Ag}^{+}\)is a Lewis base.
2 The hybridisation of \({\rm{A}}{{\rm{g}}^{{\rm{ + }}}}\) is \({\rm{s}}{{\rm{p}}^{\rm{2}}}{\rm{.}}\)
3 The \(\mathrm{Ag}^{+}\)complexes are good reducing agents.
4 These complexes are all linear.
CHXII09:COORDINATION COMPOUNDS

322270 Match Column I with Column II
supporting img

1 \({\rm{A}} - {\rm{P,B}} - {\rm{R,C}} - {\rm{Q,D}} - {\rm{S}}\)
2 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{S,D}} - {\rm{Q}}\)
3 \({\rm{A}} - {\rm{R,B}} - {\rm{Q,C}} - {\rm{S,D}} - {\rm{P}}\)
4 \({\rm{A}} - {\rm{R,B}} - {\rm{P,C}} - {\rm{Q,D}} - {\rm{S}}\)
CHXII09:COORDINATION COMPOUNDS

322271 Assertion :
\(\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) and \(\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}\) are reducing in nature.
Reason :
Unpaired electrons are present in their d-orbitals.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII09:COORDINATION COMPOUNDS

322272 In the complex ion \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\), the \(\mathrm{NH}_{3}\) molecules are linked to the central metal ion by

1 ionic bonds
2 covalent bonds
3 coordinate bonds
4 hydrogen bonds