Dependence of Rate on Concentration
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII04:CHEMICAL KINETICS

320189 The rate expression for the reaction \({\rm{A(g) + B(g)}} \to {\rm{C(g)}}\) is rate \(=\mathrm{k}[\mathrm{A}][\mathrm{B}]^{-1}\).

What changes in the initial concentrations of A and B will cause the rate of reaction to decrease by a factor of half?

1 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 2[B]}}\)
2 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]/2}}\)
3 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 4[B]}}\)
4 \(\left[ {{\rm{A'}}} \right]{\rm{ = 4[A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]}}\)
CHXII04:CHEMICAL KINETICS

320190 The rate law for a reaction between the
substances \(\mathrm{A}\) and \(\mathrm{B}\) is given by
Rate \(=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}\)
On doubling the concentration of A and halving
the concentration of \(B\), the ratio of the new rate
to the earlier rate of the reaction will be as

1 \(\frac{1}{{{2^{{\rm{(m + n)}}}}}}\)
2 \(({\rm{m}} + {\rm{n}})\)
3 \(({\rm{n}} - {\rm{m}})\)
4 \({2^{({\rm{n}} - {\rm{m}})}}\)
CHXII04:CHEMICAL KINETICS

320191 The chemical reaction \(2 \mathrm{O}_{3} \longrightarrow 3 \mathrm{O}_{2}\) proceeds as
follows:
\(\mathrm{O}_{3} \xrightarrow{\text { Fast }} \mathrm{O}_{2}+\mathrm{O} ; \quad \mathrm{O}+\mathrm{O}_{3} \xrightarrow{\text { Slow }} 2 \mathrm{O}_{2}\)
the rate law expression should be

1 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\)
2 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\left[\mathrm{O}_{2}\right]^{-1}\)
3 \(\mathrm{r}=\mathrm{k}^{3}\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
4 \(\mathrm{r}=\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
CHXII04:CHEMICAL KINETICS

320192 The reaction \({\text{2NO(g)}} + {{\text{O}}_{\text{2}}}{\text{(g)}} \rightleftharpoons {\text{2N}}{{\text{O}}_{\text{2}}}{\text{(g)}}\) is of first order. If volume of reaction vessel is reduced to \(1 / 3\) the rate of reaction would be

1 \(\dfrac{1}{3}\) times
2 \(\dfrac{2}{3}\) times
3 3 times
4 6 times
CHXII04:CHEMICAL KINETICS

320189 The rate expression for the reaction \({\rm{A(g) + B(g)}} \to {\rm{C(g)}}\) is rate \(=\mathrm{k}[\mathrm{A}][\mathrm{B}]^{-1}\).

What changes in the initial concentrations of A and B will cause the rate of reaction to decrease by a factor of half?

1 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 2[B]}}\)
2 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]/2}}\)
3 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 4[B]}}\)
4 \(\left[ {{\rm{A'}}} \right]{\rm{ = 4[A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]}}\)
CHXII04:CHEMICAL KINETICS

320190 The rate law for a reaction between the
substances \(\mathrm{A}\) and \(\mathrm{B}\) is given by
Rate \(=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}\)
On doubling the concentration of A and halving
the concentration of \(B\), the ratio of the new rate
to the earlier rate of the reaction will be as

1 \(\frac{1}{{{2^{{\rm{(m + n)}}}}}}\)
2 \(({\rm{m}} + {\rm{n}})\)
3 \(({\rm{n}} - {\rm{m}})\)
4 \({2^{({\rm{n}} - {\rm{m}})}}\)
CHXII04:CHEMICAL KINETICS

320191 The chemical reaction \(2 \mathrm{O}_{3} \longrightarrow 3 \mathrm{O}_{2}\) proceeds as
follows:
\(\mathrm{O}_{3} \xrightarrow{\text { Fast }} \mathrm{O}_{2}+\mathrm{O} ; \quad \mathrm{O}+\mathrm{O}_{3} \xrightarrow{\text { Slow }} 2 \mathrm{O}_{2}\)
the rate law expression should be

1 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\)
2 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\left[\mathrm{O}_{2}\right]^{-1}\)
3 \(\mathrm{r}=\mathrm{k}^{3}\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
4 \(\mathrm{r}=\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
CHXII04:CHEMICAL KINETICS

320192 The reaction \({\text{2NO(g)}} + {{\text{O}}_{\text{2}}}{\text{(g)}} \rightleftharpoons {\text{2N}}{{\text{O}}_{\text{2}}}{\text{(g)}}\) is of first order. If volume of reaction vessel is reduced to \(1 / 3\) the rate of reaction would be

1 \(\dfrac{1}{3}\) times
2 \(\dfrac{2}{3}\) times
3 3 times
4 6 times
CHXII04:CHEMICAL KINETICS

320189 The rate expression for the reaction \({\rm{A(g) + B(g)}} \to {\rm{C(g)}}\) is rate \(=\mathrm{k}[\mathrm{A}][\mathrm{B}]^{-1}\).

What changes in the initial concentrations of A and B will cause the rate of reaction to decrease by a factor of half?

1 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 2[B]}}\)
2 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]/2}}\)
3 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 4[B]}}\)
4 \(\left[ {{\rm{A'}}} \right]{\rm{ = 4[A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]}}\)
CHXII04:CHEMICAL KINETICS

320190 The rate law for a reaction between the
substances \(\mathrm{A}\) and \(\mathrm{B}\) is given by
Rate \(=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}\)
On doubling the concentration of A and halving
the concentration of \(B\), the ratio of the new rate
to the earlier rate of the reaction will be as

1 \(\frac{1}{{{2^{{\rm{(m + n)}}}}}}\)
2 \(({\rm{m}} + {\rm{n}})\)
3 \(({\rm{n}} - {\rm{m}})\)
4 \({2^{({\rm{n}} - {\rm{m}})}}\)
CHXII04:CHEMICAL KINETICS

320191 The chemical reaction \(2 \mathrm{O}_{3} \longrightarrow 3 \mathrm{O}_{2}\) proceeds as
follows:
\(\mathrm{O}_{3} \xrightarrow{\text { Fast }} \mathrm{O}_{2}+\mathrm{O} ; \quad \mathrm{O}+\mathrm{O}_{3} \xrightarrow{\text { Slow }} 2 \mathrm{O}_{2}\)
the rate law expression should be

1 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\)
2 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\left[\mathrm{O}_{2}\right]^{-1}\)
3 \(\mathrm{r}=\mathrm{k}^{3}\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
4 \(\mathrm{r}=\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
CHXII04:CHEMICAL KINETICS

320192 The reaction \({\text{2NO(g)}} + {{\text{O}}_{\text{2}}}{\text{(g)}} \rightleftharpoons {\text{2N}}{{\text{O}}_{\text{2}}}{\text{(g)}}\) is of first order. If volume of reaction vessel is reduced to \(1 / 3\) the rate of reaction would be

1 \(\dfrac{1}{3}\) times
2 \(\dfrac{2}{3}\) times
3 3 times
4 6 times
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII04:CHEMICAL KINETICS

320189 The rate expression for the reaction \({\rm{A(g) + B(g)}} \to {\rm{C(g)}}\) is rate \(=\mathrm{k}[\mathrm{A}][\mathrm{B}]^{-1}\).

What changes in the initial concentrations of A and B will cause the rate of reaction to decrease by a factor of half?

1 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 2[B]}}\)
2 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]/2}}\)
3 \(\left[ {{\rm{A'}}} \right]{\rm{ = [A];}}\left[ {{\rm{B'}}} \right]{\rm{ = 4[B]}}\)
4 \(\left[ {{\rm{A'}}} \right]{\rm{ = 4[A];}}\left[ {{\rm{B'}}} \right]{\rm{ = [B]}}\)
CHXII04:CHEMICAL KINETICS

320190 The rate law for a reaction between the
substances \(\mathrm{A}\) and \(\mathrm{B}\) is given by
Rate \(=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}\)
On doubling the concentration of A and halving
the concentration of \(B\), the ratio of the new rate
to the earlier rate of the reaction will be as

1 \(\frac{1}{{{2^{{\rm{(m + n)}}}}}}\)
2 \(({\rm{m}} + {\rm{n}})\)
3 \(({\rm{n}} - {\rm{m}})\)
4 \({2^{({\rm{n}} - {\rm{m}})}}\)
CHXII04:CHEMICAL KINETICS

320191 The chemical reaction \(2 \mathrm{O}_{3} \longrightarrow 3 \mathrm{O}_{2}\) proceeds as
follows:
\(\mathrm{O}_{3} \xrightarrow{\text { Fast }} \mathrm{O}_{2}+\mathrm{O} ; \quad \mathrm{O}+\mathrm{O}_{3} \xrightarrow{\text { Slow }} 2 \mathrm{O}_{2}\)
the rate law expression should be

1 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\)
2 \(\mathrm{r}=\mathrm{k}\left[\mathrm{O}_{3}\right]^{2}\left[\mathrm{O}_{2}\right]^{-1}\)
3 \(\mathrm{r}=\mathrm{k}^{3}\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
4 \(\mathrm{r}=\left[\mathrm{O}_{3}\right]\left[\mathrm{O}_{2}\right]^{2}\)
CHXII04:CHEMICAL KINETICS

320192 The reaction \({\text{2NO(g)}} + {{\text{O}}_{\text{2}}}{\text{(g)}} \rightleftharpoons {\text{2N}}{{\text{O}}_{\text{2}}}{\text{(g)}}\) is of first order. If volume of reaction vessel is reduced to \(1 / 3\) the rate of reaction would be

1 \(\dfrac{1}{3}\) times
2 \(\dfrac{2}{3}\) times
3 3 times
4 6 times