Alkynes
CHXI13:HYDROCARBONS

318169 supporting img

Which of the following statements is/are correct for these two reactions?

1 The rate of first hydrohalogenation is faster than that of second hydrohalogenation.
2 The rate of first hydrohalogenation is slower than that of second hydrohalogenation.
3 Alkynes are more reactive than vinyl halide toward an electrophile.
4 Both (1) and (3)
CHXI13:HYDROCARBONS

318170 How many sp hybridized C-atoms is are present in reactant ' A '?
\({\text{A}}\xrightarrow[{{\text{Pd - C/quinoline}}}]{{{{\text{H}}_{\text{2}}}}}{{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}\)

1 1
2 2
3 3
4 4
CHXI13:HYDROCARBONS

318171 The product that results when one mole of 1-pentyne is first treated with one mole of \(\mathrm{HCl}\) and then with one mole of \(\mathrm{H}-\mathrm{Br}\) is

1 1-Chloro-2-bromopentane
2 2-Chloro-1-bromopentane
3 2-Bromo-2-chloropentane
4 1-Chloro-1-bromopentane
CHXI13:HYDROCARBONS

318172 Assertion :
Addition of \(\mathrm{H}_{2} \mathrm{O}\) to acetylene occurs in presence of dil. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HgSO}_{4}\) to give acetaldehyde.
Reason :
The reaction proceeds through electrophilic addition mechanism.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318173 But-2-yne is reacted separately with one mole of hydrogen as shown below:
\({\text{B}}\xleftarrow[{{\text{liq}}\,\,{\text{N}}{{\text{H}}_{\text{3}}}}]{{{\text{Na}}}}{\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}\mathop \equiv \limits_{ + {{\text{H}}_2}} {\text{C}} - {\text{C}}{{\text{H}}_{\text{3}}}\xrightarrow[\Delta ]{{{\text{Pd}}/{\text{C}}}}{\text{A}}\)
1. A is more soluble than B .
2. The boiling point and melting point of \({\text{A}}\) are higher and lower than B respectively.
3. A is more polar than B because dipole moment of A is zero.
4. \(\mathrm{Br}_{2}\) adds easily to B than A .
Identify the incorrect statements from the options given below.

1 1,3 and 4 only
2 1 and 2 only
3 2,3 and 4 only
4 3 and 4 only
CHXI13:HYDROCARBONS

318169 supporting img

Which of the following statements is/are correct for these two reactions?

1 The rate of first hydrohalogenation is faster than that of second hydrohalogenation.
2 The rate of first hydrohalogenation is slower than that of second hydrohalogenation.
3 Alkynes are more reactive than vinyl halide toward an electrophile.
4 Both (1) and (3)
CHXI13:HYDROCARBONS

318170 How many sp hybridized C-atoms is are present in reactant ' A '?
\({\text{A}}\xrightarrow[{{\text{Pd - C/quinoline}}}]{{{{\text{H}}_{\text{2}}}}}{{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}\)

1 1
2 2
3 3
4 4
CHXI13:HYDROCARBONS

318171 The product that results when one mole of 1-pentyne is first treated with one mole of \(\mathrm{HCl}\) and then with one mole of \(\mathrm{H}-\mathrm{Br}\) is

1 1-Chloro-2-bromopentane
2 2-Chloro-1-bromopentane
3 2-Bromo-2-chloropentane
4 1-Chloro-1-bromopentane
CHXI13:HYDROCARBONS

318172 Assertion :
Addition of \(\mathrm{H}_{2} \mathrm{O}\) to acetylene occurs in presence of dil. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HgSO}_{4}\) to give acetaldehyde.
Reason :
The reaction proceeds through electrophilic addition mechanism.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318173 But-2-yne is reacted separately with one mole of hydrogen as shown below:
\({\text{B}}\xleftarrow[{{\text{liq}}\,\,{\text{N}}{{\text{H}}_{\text{3}}}}]{{{\text{Na}}}}{\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}\mathop \equiv \limits_{ + {{\text{H}}_2}} {\text{C}} - {\text{C}}{{\text{H}}_{\text{3}}}\xrightarrow[\Delta ]{{{\text{Pd}}/{\text{C}}}}{\text{A}}\)
1. A is more soluble than B .
2. The boiling point and melting point of \({\text{A}}\) are higher and lower than B respectively.
3. A is more polar than B because dipole moment of A is zero.
4. \(\mathrm{Br}_{2}\) adds easily to B than A .
Identify the incorrect statements from the options given below.

1 1,3 and 4 only
2 1 and 2 only
3 2,3 and 4 only
4 3 and 4 only
CHXI13:HYDROCARBONS

318169 supporting img

Which of the following statements is/are correct for these two reactions?

1 The rate of first hydrohalogenation is faster than that of second hydrohalogenation.
2 The rate of first hydrohalogenation is slower than that of second hydrohalogenation.
3 Alkynes are more reactive than vinyl halide toward an electrophile.
4 Both (1) and (3)
CHXI13:HYDROCARBONS

318170 How many sp hybridized C-atoms is are present in reactant ' A '?
\({\text{A}}\xrightarrow[{{\text{Pd - C/quinoline}}}]{{{{\text{H}}_{\text{2}}}}}{{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}\)

1 1
2 2
3 3
4 4
CHXI13:HYDROCARBONS

318171 The product that results when one mole of 1-pentyne is first treated with one mole of \(\mathrm{HCl}\) and then with one mole of \(\mathrm{H}-\mathrm{Br}\) is

1 1-Chloro-2-bromopentane
2 2-Chloro-1-bromopentane
3 2-Bromo-2-chloropentane
4 1-Chloro-1-bromopentane
CHXI13:HYDROCARBONS

318172 Assertion :
Addition of \(\mathrm{H}_{2} \mathrm{O}\) to acetylene occurs in presence of dil. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HgSO}_{4}\) to give acetaldehyde.
Reason :
The reaction proceeds through electrophilic addition mechanism.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318173 But-2-yne is reacted separately with one mole of hydrogen as shown below:
\({\text{B}}\xleftarrow[{{\text{liq}}\,\,{\text{N}}{{\text{H}}_{\text{3}}}}]{{{\text{Na}}}}{\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}\mathop \equiv \limits_{ + {{\text{H}}_2}} {\text{C}} - {\text{C}}{{\text{H}}_{\text{3}}}\xrightarrow[\Delta ]{{{\text{Pd}}/{\text{C}}}}{\text{A}}\)
1. A is more soluble than B .
2. The boiling point and melting point of \({\text{A}}\) are higher and lower than B respectively.
3. A is more polar than B because dipole moment of A is zero.
4. \(\mathrm{Br}_{2}\) adds easily to B than A .
Identify the incorrect statements from the options given below.

1 1,3 and 4 only
2 1 and 2 only
3 2,3 and 4 only
4 3 and 4 only
CHXI13:HYDROCARBONS

318169 supporting img

Which of the following statements is/are correct for these two reactions?

1 The rate of first hydrohalogenation is faster than that of second hydrohalogenation.
2 The rate of first hydrohalogenation is slower than that of second hydrohalogenation.
3 Alkynes are more reactive than vinyl halide toward an electrophile.
4 Both (1) and (3)
CHXI13:HYDROCARBONS

318170 How many sp hybridized C-atoms is are present in reactant ' A '?
\({\text{A}}\xrightarrow[{{\text{Pd - C/quinoline}}}]{{{{\text{H}}_{\text{2}}}}}{{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}\)

1 1
2 2
3 3
4 4
CHXI13:HYDROCARBONS

318171 The product that results when one mole of 1-pentyne is first treated with one mole of \(\mathrm{HCl}\) and then with one mole of \(\mathrm{H}-\mathrm{Br}\) is

1 1-Chloro-2-bromopentane
2 2-Chloro-1-bromopentane
3 2-Bromo-2-chloropentane
4 1-Chloro-1-bromopentane
CHXI13:HYDROCARBONS

318172 Assertion :
Addition of \(\mathrm{H}_{2} \mathrm{O}\) to acetylene occurs in presence of dil. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HgSO}_{4}\) to give acetaldehyde.
Reason :
The reaction proceeds through electrophilic addition mechanism.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318173 But-2-yne is reacted separately with one mole of hydrogen as shown below:
\({\text{B}}\xleftarrow[{{\text{liq}}\,\,{\text{N}}{{\text{H}}_{\text{3}}}}]{{{\text{Na}}}}{\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}\mathop \equiv \limits_{ + {{\text{H}}_2}} {\text{C}} - {\text{C}}{{\text{H}}_{\text{3}}}\xrightarrow[\Delta ]{{{\text{Pd}}/{\text{C}}}}{\text{A}}\)
1. A is more soluble than B .
2. The boiling point and melting point of \({\text{A}}\) are higher and lower than B respectively.
3. A is more polar than B because dipole moment of A is zero.
4. \(\mathrm{Br}_{2}\) adds easily to B than A .
Identify the incorrect statements from the options given below.

1 1,3 and 4 only
2 1 and 2 only
3 2,3 and 4 only
4 3 and 4 only
CHXI13:HYDROCARBONS

318169 supporting img

Which of the following statements is/are correct for these two reactions?

1 The rate of first hydrohalogenation is faster than that of second hydrohalogenation.
2 The rate of first hydrohalogenation is slower than that of second hydrohalogenation.
3 Alkynes are more reactive than vinyl halide toward an electrophile.
4 Both (1) and (3)
CHXI13:HYDROCARBONS

318170 How many sp hybridized C-atoms is are present in reactant ' A '?
\({\text{A}}\xrightarrow[{{\text{Pd - C/quinoline}}}]{{{{\text{H}}_{\text{2}}}}}{{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}\)

1 1
2 2
3 3
4 4
CHXI13:HYDROCARBONS

318171 The product that results when one mole of 1-pentyne is first treated with one mole of \(\mathrm{HCl}\) and then with one mole of \(\mathrm{H}-\mathrm{Br}\) is

1 1-Chloro-2-bromopentane
2 2-Chloro-1-bromopentane
3 2-Bromo-2-chloropentane
4 1-Chloro-1-bromopentane
CHXI13:HYDROCARBONS

318172 Assertion :
Addition of \(\mathrm{H}_{2} \mathrm{O}\) to acetylene occurs in presence of dil. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HgSO}_{4}\) to give acetaldehyde.
Reason :
The reaction proceeds through electrophilic addition mechanism.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318173 But-2-yne is reacted separately with one mole of hydrogen as shown below:
\({\text{B}}\xleftarrow[{{\text{liq}}\,\,{\text{N}}{{\text{H}}_{\text{3}}}}]{{{\text{Na}}}}{\text{C}}{{\text{H}}_{\text{3}}} - {\text{C}}\mathop \equiv \limits_{ + {{\text{H}}_2}} {\text{C}} - {\text{C}}{{\text{H}}_{\text{3}}}\xrightarrow[\Delta ]{{{\text{Pd}}/{\text{C}}}}{\text{A}}\)
1. A is more soluble than B .
2. The boiling point and melting point of \({\text{A}}\) are higher and lower than B respectively.
3. A is more polar than B because dipole moment of A is zero.
4. \(\mathrm{Br}_{2}\) adds easily to B than A .
Identify the incorrect statements from the options given below.

1 1,3 and 4 only
2 1 and 2 only
3 2,3 and 4 only
4 3 and 4 only