Alkynes
CHXI13:HYDROCARBONS

318174 \(\mathrm{CH}_{3}-\underset{\text { I }}{\mathrm{C}} \equiv \mathrm{CH} \quad \mathrm{CH}_{3}-\underset{\text { II }}{\mathrm{CH}}=\mathrm{CH}_{2}\)\(\mathrm{HC} \underset{\text { III }}{\equiv} \mathrm{CH}\)
Ease of catalytic hydrogenation among these compounds will be in the order as:

1 III \(>\) I \(>\) II
2 II \(>\) I \(>\) III
3 I \(>\) II \(>\) III
4 III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318175 The alkyne which gives pyruvic acid \(\left(\mathrm{CH}_{3} \mathrm{COCOOH}\right)\) on oxidation with alk. \(\mathrm{KMnO}_{4}\) is:

1 \(\mathrm{CH} \equiv \mathrm{CH}\)
2 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{CH}\)
3 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{C} \equiv \mathrm{CH}\)
CHXI13:HYDROCARBONS

318176 Acetylene when reacts with two molecules of \(\mathrm{HBr}\), then it gives

1 \(\mathrm{Br}-\mathrm{C} \equiv \mathrm{C}-\mathrm{Br}\)
2 \(\mathrm{Br}-\mathrm{CH}=\mathrm{CH}-\mathrm{Br}\)
3 \(\mathrm{Br}_{2} \mathrm{CH}-\mathrm{CHBr}_{2}\)
4 \(\mathrm{CH}_{3}-\mathrm{CHBr}_{2}\)
CHXI13:HYDROCARBONS

318177 The most suitable catalyst for the hydrogenation
of
2-Hexyne \(\longrightarrow\) 2-cis-Hexene is

1 \(\mathrm{Pd}-\mathrm{BaSO}_{4}\)
2 \(\left(\mathrm{Ph}_{3} \mathrm{P}\right)_{3} \mathrm{RhCl}\)
3 \(10 \% \mathrm{Pd}-\mathrm{C}\)
4 Raney Ni
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CHXI13:HYDROCARBONS

318174 \(\mathrm{CH}_{3}-\underset{\text { I }}{\mathrm{C}} \equiv \mathrm{CH} \quad \mathrm{CH}_{3}-\underset{\text { II }}{\mathrm{CH}}=\mathrm{CH}_{2}\)\(\mathrm{HC} \underset{\text { III }}{\equiv} \mathrm{CH}\)
Ease of catalytic hydrogenation among these compounds will be in the order as:

1 III \(>\) I \(>\) II
2 II \(>\) I \(>\) III
3 I \(>\) II \(>\) III
4 III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318175 The alkyne which gives pyruvic acid \(\left(\mathrm{CH}_{3} \mathrm{COCOOH}\right)\) on oxidation with alk. \(\mathrm{KMnO}_{4}\) is:

1 \(\mathrm{CH} \equiv \mathrm{CH}\)
2 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{CH}\)
3 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{C} \equiv \mathrm{CH}\)
CHXI13:HYDROCARBONS

318176 Acetylene when reacts with two molecules of \(\mathrm{HBr}\), then it gives

1 \(\mathrm{Br}-\mathrm{C} \equiv \mathrm{C}-\mathrm{Br}\)
2 \(\mathrm{Br}-\mathrm{CH}=\mathrm{CH}-\mathrm{Br}\)
3 \(\mathrm{Br}_{2} \mathrm{CH}-\mathrm{CHBr}_{2}\)
4 \(\mathrm{CH}_{3}-\mathrm{CHBr}_{2}\)
CHXI13:HYDROCARBONS

318177 The most suitable catalyst for the hydrogenation
of
2-Hexyne \(\longrightarrow\) 2-cis-Hexene is

1 \(\mathrm{Pd}-\mathrm{BaSO}_{4}\)
2 \(\left(\mathrm{Ph}_{3} \mathrm{P}\right)_{3} \mathrm{RhCl}\)
3 \(10 \% \mathrm{Pd}-\mathrm{C}\)
4 Raney Ni
CHXI13:HYDROCARBONS

318174 \(\mathrm{CH}_{3}-\underset{\text { I }}{\mathrm{C}} \equiv \mathrm{CH} \quad \mathrm{CH}_{3}-\underset{\text { II }}{\mathrm{CH}}=\mathrm{CH}_{2}\)\(\mathrm{HC} \underset{\text { III }}{\equiv} \mathrm{CH}\)
Ease of catalytic hydrogenation among these compounds will be in the order as:

1 III \(>\) I \(>\) II
2 II \(>\) I \(>\) III
3 I \(>\) II \(>\) III
4 III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318175 The alkyne which gives pyruvic acid \(\left(\mathrm{CH}_{3} \mathrm{COCOOH}\right)\) on oxidation with alk. \(\mathrm{KMnO}_{4}\) is:

1 \(\mathrm{CH} \equiv \mathrm{CH}\)
2 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{CH}\)
3 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{C} \equiv \mathrm{CH}\)
CHXI13:HYDROCARBONS

318176 Acetylene when reacts with two molecules of \(\mathrm{HBr}\), then it gives

1 \(\mathrm{Br}-\mathrm{C} \equiv \mathrm{C}-\mathrm{Br}\)
2 \(\mathrm{Br}-\mathrm{CH}=\mathrm{CH}-\mathrm{Br}\)
3 \(\mathrm{Br}_{2} \mathrm{CH}-\mathrm{CHBr}_{2}\)
4 \(\mathrm{CH}_{3}-\mathrm{CHBr}_{2}\)
CHXI13:HYDROCARBONS

318177 The most suitable catalyst for the hydrogenation
of
2-Hexyne \(\longrightarrow\) 2-cis-Hexene is

1 \(\mathrm{Pd}-\mathrm{BaSO}_{4}\)
2 \(\left(\mathrm{Ph}_{3} \mathrm{P}\right)_{3} \mathrm{RhCl}\)
3 \(10 \% \mathrm{Pd}-\mathrm{C}\)
4 Raney Ni
CHXI13:HYDROCARBONS

318174 \(\mathrm{CH}_{3}-\underset{\text { I }}{\mathrm{C}} \equiv \mathrm{CH} \quad \mathrm{CH}_{3}-\underset{\text { II }}{\mathrm{CH}}=\mathrm{CH}_{2}\)\(\mathrm{HC} \underset{\text { III }}{\equiv} \mathrm{CH}\)
Ease of catalytic hydrogenation among these compounds will be in the order as:

1 III \(>\) I \(>\) II
2 II \(>\) I \(>\) III
3 I \(>\) II \(>\) III
4 III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318175 The alkyne which gives pyruvic acid \(\left(\mathrm{CH}_{3} \mathrm{COCOOH}\right)\) on oxidation with alk. \(\mathrm{KMnO}_{4}\) is:

1 \(\mathrm{CH} \equiv \mathrm{CH}\)
2 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{CH}\)
3 \(\mathrm{CH}_{3} \mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{3}\)
4 \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{C} \equiv \mathrm{CH}\)
CHXI13:HYDROCARBONS

318176 Acetylene when reacts with two molecules of \(\mathrm{HBr}\), then it gives

1 \(\mathrm{Br}-\mathrm{C} \equiv \mathrm{C}-\mathrm{Br}\)
2 \(\mathrm{Br}-\mathrm{CH}=\mathrm{CH}-\mathrm{Br}\)
3 \(\mathrm{Br}_{2} \mathrm{CH}-\mathrm{CHBr}_{2}\)
4 \(\mathrm{CH}_{3}-\mathrm{CHBr}_{2}\)
CHXI13:HYDROCARBONS

318177 The most suitable catalyst for the hydrogenation
of
2-Hexyne \(\longrightarrow\) 2-cis-Hexene is

1 \(\mathrm{Pd}-\mathrm{BaSO}_{4}\)
2 \(\left(\mathrm{Ph}_{3} \mathrm{P}\right)_{3} \mathrm{RhCl}\)
3 \(10 \% \mathrm{Pd}-\mathrm{C}\)
4 Raney Ni