Miscellaneous Questions based on Group – 13 and 14 Elements
CHXI11:THE P-BLOCK ELEMENTS

316674 Which is not the correct statement?

1 The \(\mathrm{S}_{8}\) ring is not planar
2 Oxygen is more electronegative than sulphur
3 \(\mathrm{SF}_{4}\) exists but \(\mathrm{OF}_{4}\) does not exist
4 \(\mathrm{SO}_{3}\) and \(\mathrm{SO}_{3}^{2-}\) both have trigonal planar geometry
CHXI11:THE P-BLOCK ELEMENTS

316675 Which one of the following is wrongly matched?

1 \({\rm{ClO}}_{\rm{3}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), pyramidal
2 \({\rm{ClO}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), tetrahedral
3 \({\rm{ICl}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}{{\rm{d}}^{\rm{2}}}\), square planar
4 \({\rm{ICl}}_{\rm{2}}^{\rm{ - }}{\rm{,}}\,\,{\rm{ds}}{{\rm{p}}^{\rm{2}}}\), trigonal bipyramidal
CHXI11:THE P-BLOCK ELEMENTS

316676 On addition of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) to a chloride salt, colourless fumes are evolved but in case of iodide salt, violet fumes come out. This is because

1 \(\mathrm{H}_{2} \mathrm{SO}_{4}\) reduces \(\mathrm{HI}\) to \(\mathrm{I}_{2}\)
2 \(\mathrm{HI}\) is of violet colour
3 \(\mathrm{HI}\) gets oxidised to \(\mathrm{I}_{2}\)
4 \(\mathrm{HI}\) changes to \(\mathrm{HIO}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316677 A green yellow gas reacts with an alkali metal hydroxide to form a halate which can be used in fireworks and safety matches. The gas and halate are, respectively.

1 \(\mathrm{Br}_{2}, \mathrm{KBrO}_{3}\)
2 \(\mathrm{Cl}_{2}, \mathrm{KClO}_{3}\)
3 \(\mathrm{I}_{2}, \mathrm{NaIO}_{3}\)
4 \(\mathrm{Cl}_{2}, \mathrm{NaClO}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316674 Which is not the correct statement?

1 The \(\mathrm{S}_{8}\) ring is not planar
2 Oxygen is more electronegative than sulphur
3 \(\mathrm{SF}_{4}\) exists but \(\mathrm{OF}_{4}\) does not exist
4 \(\mathrm{SO}_{3}\) and \(\mathrm{SO}_{3}^{2-}\) both have trigonal planar geometry
CHXI11:THE P-BLOCK ELEMENTS

316675 Which one of the following is wrongly matched?

1 \({\rm{ClO}}_{\rm{3}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), pyramidal
2 \({\rm{ClO}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), tetrahedral
3 \({\rm{ICl}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}{{\rm{d}}^{\rm{2}}}\), square planar
4 \({\rm{ICl}}_{\rm{2}}^{\rm{ - }}{\rm{,}}\,\,{\rm{ds}}{{\rm{p}}^{\rm{2}}}\), trigonal bipyramidal
CHXI11:THE P-BLOCK ELEMENTS

316676 On addition of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) to a chloride salt, colourless fumes are evolved but in case of iodide salt, violet fumes come out. This is because

1 \(\mathrm{H}_{2} \mathrm{SO}_{4}\) reduces \(\mathrm{HI}\) to \(\mathrm{I}_{2}\)
2 \(\mathrm{HI}\) is of violet colour
3 \(\mathrm{HI}\) gets oxidised to \(\mathrm{I}_{2}\)
4 \(\mathrm{HI}\) changes to \(\mathrm{HIO}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316677 A green yellow gas reacts with an alkali metal hydroxide to form a halate which can be used in fireworks and safety matches. The gas and halate are, respectively.

1 \(\mathrm{Br}_{2}, \mathrm{KBrO}_{3}\)
2 \(\mathrm{Cl}_{2}, \mathrm{KClO}_{3}\)
3 \(\mathrm{I}_{2}, \mathrm{NaIO}_{3}\)
4 \(\mathrm{Cl}_{2}, \mathrm{NaClO}_{3}\)
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CHXI11:THE P-BLOCK ELEMENTS

316674 Which is not the correct statement?

1 The \(\mathrm{S}_{8}\) ring is not planar
2 Oxygen is more electronegative than sulphur
3 \(\mathrm{SF}_{4}\) exists but \(\mathrm{OF}_{4}\) does not exist
4 \(\mathrm{SO}_{3}\) and \(\mathrm{SO}_{3}^{2-}\) both have trigonal planar geometry
CHXI11:THE P-BLOCK ELEMENTS

316675 Which one of the following is wrongly matched?

1 \({\rm{ClO}}_{\rm{3}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), pyramidal
2 \({\rm{ClO}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), tetrahedral
3 \({\rm{ICl}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}{{\rm{d}}^{\rm{2}}}\), square planar
4 \({\rm{ICl}}_{\rm{2}}^{\rm{ - }}{\rm{,}}\,\,{\rm{ds}}{{\rm{p}}^{\rm{2}}}\), trigonal bipyramidal
CHXI11:THE P-BLOCK ELEMENTS

316676 On addition of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) to a chloride salt, colourless fumes are evolved but in case of iodide salt, violet fumes come out. This is because

1 \(\mathrm{H}_{2} \mathrm{SO}_{4}\) reduces \(\mathrm{HI}\) to \(\mathrm{I}_{2}\)
2 \(\mathrm{HI}\) is of violet colour
3 \(\mathrm{HI}\) gets oxidised to \(\mathrm{I}_{2}\)
4 \(\mathrm{HI}\) changes to \(\mathrm{HIO}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316677 A green yellow gas reacts with an alkali metal hydroxide to form a halate which can be used in fireworks and safety matches. The gas and halate are, respectively.

1 \(\mathrm{Br}_{2}, \mathrm{KBrO}_{3}\)
2 \(\mathrm{Cl}_{2}, \mathrm{KClO}_{3}\)
3 \(\mathrm{I}_{2}, \mathrm{NaIO}_{3}\)
4 \(\mathrm{Cl}_{2}, \mathrm{NaClO}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316674 Which is not the correct statement?

1 The \(\mathrm{S}_{8}\) ring is not planar
2 Oxygen is more electronegative than sulphur
3 \(\mathrm{SF}_{4}\) exists but \(\mathrm{OF}_{4}\) does not exist
4 \(\mathrm{SO}_{3}\) and \(\mathrm{SO}_{3}^{2-}\) both have trigonal planar geometry
CHXI11:THE P-BLOCK ELEMENTS

316675 Which one of the following is wrongly matched?

1 \({\rm{ClO}}_{\rm{3}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), pyramidal
2 \({\rm{ClO}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}\), tetrahedral
3 \({\rm{ICl}}_{\rm{4}}^{\rm{ - }}{\rm{,}}\,\,{\rm{s}}{{\rm{p}}^{\rm{3}}}{{\rm{d}}^{\rm{2}}}\), square planar
4 \({\rm{ICl}}_{\rm{2}}^{\rm{ - }}{\rm{,}}\,\,{\rm{ds}}{{\rm{p}}^{\rm{2}}}\), trigonal bipyramidal
CHXI11:THE P-BLOCK ELEMENTS

316676 On addition of conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) to a chloride salt, colourless fumes are evolved but in case of iodide salt, violet fumes come out. This is because

1 \(\mathrm{H}_{2} \mathrm{SO}_{4}\) reduces \(\mathrm{HI}\) to \(\mathrm{I}_{2}\)
2 \(\mathrm{HI}\) is of violet colour
3 \(\mathrm{HI}\) gets oxidised to \(\mathrm{I}_{2}\)
4 \(\mathrm{HI}\) changes to \(\mathrm{HIO}_{3}\)
CHXI11:THE P-BLOCK ELEMENTS

316677 A green yellow gas reacts with an alkali metal hydroxide to form a halate which can be used in fireworks and safety matches. The gas and halate are, respectively.

1 \(\mathrm{Br}_{2}, \mathrm{KBrO}_{3}\)
2 \(\mathrm{Cl}_{2}, \mathrm{KClO}_{3}\)
3 \(\mathrm{I}_{2}, \mathrm{NaIO}_{3}\)
4 \(\mathrm{Cl}_{2}, \mathrm{NaClO}_{3}\)