Heat of Reaction
CHXI06:THERMODYNAMICS

369534 What is enthalpy of formation of \(\mathrm{NH}_{3}\) if bond enthalpies are as
\((\mathrm{N} \equiv \mathrm{N})=941 \mathrm{~kJ},(\mathrm{H}-\mathrm{H})=436 \mathrm{~kJ}\),
\((\mathrm{N}-\mathrm{H})=389 \mathrm{~kJ}\) ?

1 \(-84.5 \mathrm{~kJ}\)
2 \(-21.25 \mathrm{~kJ}\)
3 \(-42.5 \mathrm{~kJ}\)
4 \(-63.45 \mathrm{~kJ}\)
CHXI06:THERMODYNAMICS

369535 From the following bond energies:
\(\mathrm{H-H}\) bond energy: \(\mathrm{431.37 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C=C}\) bond energy: \(\mathrm{606.10 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-C}\) bond energy: \(\mathrm{336.49 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-H}\) bond energy: \(\mathrm{410.50 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
Enthalpy for the reaction will be :
supporting img

1 \(\mathrm{553.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
2 \(\mathrm{1523.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
3 \(\mathrm{-243.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
4 \(\mathrm{-120.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
CHXI06:THERMODYNAMICS

369536 Statement A :
The mean bond energy of all the four \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds in \(\mathrm{\mathrm{CH}_{4}}\) molecule is not equal.
Statement B :
After breaking of \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds one by one, the electronic environments changes.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI06:THERMODYNAMICS

369537 The standard enthalpy of formation of \(\mathrm{\mathrm{NH}_{3}}\) is \(\mathrm{-46.0 \mathrm{~kJ} / \mathrm{mol}}\). If the enthalpy of formation of \(\mathrm{\mathrm{H}_{2}}\) from its atoms is \(\mathrm{-436 \mathrm{~kJ} / \mathrm{mol}}\) and that of \(\mathrm{N_{2}}\) is \(\mathrm{-712 \mathrm{~kJ} / \mathrm{mol}}\), the average bond enthalpy of \(\mathrm{\mathrm{N}-\mathrm{H}}\) bond in \(\mathrm{\mathrm{NH}_{3}}\) is:

1 \(\mathrm{-1102 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-964 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{+352 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{+1056 \mathrm{~kJ} / \mathrm{mol}}\)
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CHXI06:THERMODYNAMICS

369534 What is enthalpy of formation of \(\mathrm{NH}_{3}\) if bond enthalpies are as
\((\mathrm{N} \equiv \mathrm{N})=941 \mathrm{~kJ},(\mathrm{H}-\mathrm{H})=436 \mathrm{~kJ}\),
\((\mathrm{N}-\mathrm{H})=389 \mathrm{~kJ}\) ?

1 \(-84.5 \mathrm{~kJ}\)
2 \(-21.25 \mathrm{~kJ}\)
3 \(-42.5 \mathrm{~kJ}\)
4 \(-63.45 \mathrm{~kJ}\)
CHXI06:THERMODYNAMICS

369535 From the following bond energies:
\(\mathrm{H-H}\) bond energy: \(\mathrm{431.37 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C=C}\) bond energy: \(\mathrm{606.10 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-C}\) bond energy: \(\mathrm{336.49 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-H}\) bond energy: \(\mathrm{410.50 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
Enthalpy for the reaction will be :
supporting img

1 \(\mathrm{553.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
2 \(\mathrm{1523.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
3 \(\mathrm{-243.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
4 \(\mathrm{-120.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
CHXI06:THERMODYNAMICS

369536 Statement A :
The mean bond energy of all the four \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds in \(\mathrm{\mathrm{CH}_{4}}\) molecule is not equal.
Statement B :
After breaking of \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds one by one, the electronic environments changes.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI06:THERMODYNAMICS

369537 The standard enthalpy of formation of \(\mathrm{\mathrm{NH}_{3}}\) is \(\mathrm{-46.0 \mathrm{~kJ} / \mathrm{mol}}\). If the enthalpy of formation of \(\mathrm{\mathrm{H}_{2}}\) from its atoms is \(\mathrm{-436 \mathrm{~kJ} / \mathrm{mol}}\) and that of \(\mathrm{N_{2}}\) is \(\mathrm{-712 \mathrm{~kJ} / \mathrm{mol}}\), the average bond enthalpy of \(\mathrm{\mathrm{N}-\mathrm{H}}\) bond in \(\mathrm{\mathrm{NH}_{3}}\) is:

1 \(\mathrm{-1102 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-964 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{+352 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{+1056 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369534 What is enthalpy of formation of \(\mathrm{NH}_{3}\) if bond enthalpies are as
\((\mathrm{N} \equiv \mathrm{N})=941 \mathrm{~kJ},(\mathrm{H}-\mathrm{H})=436 \mathrm{~kJ}\),
\((\mathrm{N}-\mathrm{H})=389 \mathrm{~kJ}\) ?

1 \(-84.5 \mathrm{~kJ}\)
2 \(-21.25 \mathrm{~kJ}\)
3 \(-42.5 \mathrm{~kJ}\)
4 \(-63.45 \mathrm{~kJ}\)
CHXI06:THERMODYNAMICS

369535 From the following bond energies:
\(\mathrm{H-H}\) bond energy: \(\mathrm{431.37 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C=C}\) bond energy: \(\mathrm{606.10 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-C}\) bond energy: \(\mathrm{336.49 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-H}\) bond energy: \(\mathrm{410.50 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
Enthalpy for the reaction will be :
supporting img

1 \(\mathrm{553.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
2 \(\mathrm{1523.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
3 \(\mathrm{-243.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
4 \(\mathrm{-120.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
CHXI06:THERMODYNAMICS

369536 Statement A :
The mean bond energy of all the four \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds in \(\mathrm{\mathrm{CH}_{4}}\) molecule is not equal.
Statement B :
After breaking of \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds one by one, the electronic environments changes.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI06:THERMODYNAMICS

369537 The standard enthalpy of formation of \(\mathrm{\mathrm{NH}_{3}}\) is \(\mathrm{-46.0 \mathrm{~kJ} / \mathrm{mol}}\). If the enthalpy of formation of \(\mathrm{\mathrm{H}_{2}}\) from its atoms is \(\mathrm{-436 \mathrm{~kJ} / \mathrm{mol}}\) and that of \(\mathrm{N_{2}}\) is \(\mathrm{-712 \mathrm{~kJ} / \mathrm{mol}}\), the average bond enthalpy of \(\mathrm{\mathrm{N}-\mathrm{H}}\) bond in \(\mathrm{\mathrm{NH}_{3}}\) is:

1 \(\mathrm{-1102 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-964 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{+352 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{+1056 \mathrm{~kJ} / \mathrm{mol}}\)
CHXI06:THERMODYNAMICS

369534 What is enthalpy of formation of \(\mathrm{NH}_{3}\) if bond enthalpies are as
\((\mathrm{N} \equiv \mathrm{N})=941 \mathrm{~kJ},(\mathrm{H}-\mathrm{H})=436 \mathrm{~kJ}\),
\((\mathrm{N}-\mathrm{H})=389 \mathrm{~kJ}\) ?

1 \(-84.5 \mathrm{~kJ}\)
2 \(-21.25 \mathrm{~kJ}\)
3 \(-42.5 \mathrm{~kJ}\)
4 \(-63.45 \mathrm{~kJ}\)
CHXI06:THERMODYNAMICS

369535 From the following bond energies:
\(\mathrm{H-H}\) bond energy: \(\mathrm{431.37 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C=C}\) bond energy: \(\mathrm{606.10 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-C}\) bond energy: \(\mathrm{336.49 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
\(\mathrm{C-H}\) bond energy: \(\mathrm{410.50 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
Enthalpy for the reaction will be :
supporting img

1 \(\mathrm{553.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
2 \(\mathrm{1523.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
3 \(\mathrm{-243.6 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
4 \(\mathrm{-120.0 \mathrm{~kJ} \mathrm{~mol}^{-1}}\)
CHXI06:THERMODYNAMICS

369536 Statement A :
The mean bond energy of all the four \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds in \(\mathrm{\mathrm{CH}_{4}}\) molecule is not equal.
Statement B :
After breaking of \(\mathrm{\mathrm{C}-\mathrm{H}}\) bonds one by one, the electronic environments changes.

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI06:THERMODYNAMICS

369537 The standard enthalpy of formation of \(\mathrm{\mathrm{NH}_{3}}\) is \(\mathrm{-46.0 \mathrm{~kJ} / \mathrm{mol}}\). If the enthalpy of formation of \(\mathrm{\mathrm{H}_{2}}\) from its atoms is \(\mathrm{-436 \mathrm{~kJ} / \mathrm{mol}}\) and that of \(\mathrm{N_{2}}\) is \(\mathrm{-712 \mathrm{~kJ} / \mathrm{mol}}\), the average bond enthalpy of \(\mathrm{\mathrm{N}-\mathrm{H}}\) bond in \(\mathrm{\mathrm{NH}_{3}}\) is:

1 \(\mathrm{-1102 \mathrm{~kJ} / \mathrm{mol}}\)
2 \(\mathrm{-964 \mathrm{~kJ} / \mathrm{mol}}\)
3 \(\mathrm{+352 \mathrm{~kJ} / \mathrm{mol}}\)
4 \(\mathrm{+1056 \mathrm{~kJ} / \mathrm{mol}}\)