Absolute Entropy and Third Law of Thermodynamics
CHXI06:THERMODYNAMICS

369296 Which of the following statements is true?

1 The total entropy of the universe remains constant.
2 The total entropy of the universe is continuously decreasing.
3 The total energy of the universe is continuously decreasing.
4 The total energy of the universe remains constant.
CHXI06:THERMODYNAMICS

369297 Assertion :
The enthalpy of formation of gaseous oxygen molecules at \(298 \mathrm{~K}\) and under a pressure of one atmosphere is zero
Reason :
The entropy of formation of gaseous oxygen molecule under the same conditions is zero.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion & Reason are false.
CHXI06:THERMODYNAMICS

369298 Given the following entropy values (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) at \(\mathrm{298 \mathrm{~K}}\) and 1 atm: \(\mathrm{H_{2}(g): 130.6, \mathrm{Cl}_{2}(g): 223.0, \mathrm{HCl}(\mathrm{g}): 186.7}\). The entropy change (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) for the reaction \(\mathrm{\mathrm{H}_{2}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{HCl}(\mathrm{g})}\) is

1 \({\rm{ + 540}}{\rm{.3}}\)
2 \({\rm{ + 727}}{\rm{.0}}\)
3 \({\rm{ - 166}}{\rm{.9}}\)
4 \({\rm{ + 19}}{\rm{.8}}\)
CHXI06:THERMODYNAMICS

369299 For chemical reactions, the calculation of change in entropy is normally done

1 at constant pressure.
2 at constant temperature.
3 at both constant temperature and pressure.
4 at constant volume.
CHXI06:THERMODYNAMICS

369296 Which of the following statements is true?

1 The total entropy of the universe remains constant.
2 The total entropy of the universe is continuously decreasing.
3 The total energy of the universe is continuously decreasing.
4 The total energy of the universe remains constant.
CHXI06:THERMODYNAMICS

369297 Assertion :
The enthalpy of formation of gaseous oxygen molecules at \(298 \mathrm{~K}\) and under a pressure of one atmosphere is zero
Reason :
The entropy of formation of gaseous oxygen molecule under the same conditions is zero.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion & Reason are false.
CHXI06:THERMODYNAMICS

369298 Given the following entropy values (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) at \(\mathrm{298 \mathrm{~K}}\) and 1 atm: \(\mathrm{H_{2}(g): 130.6, \mathrm{Cl}_{2}(g): 223.0, \mathrm{HCl}(\mathrm{g}): 186.7}\). The entropy change (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) for the reaction \(\mathrm{\mathrm{H}_{2}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{HCl}(\mathrm{g})}\) is

1 \({\rm{ + 540}}{\rm{.3}}\)
2 \({\rm{ + 727}}{\rm{.0}}\)
3 \({\rm{ - 166}}{\rm{.9}}\)
4 \({\rm{ + 19}}{\rm{.8}}\)
CHXI06:THERMODYNAMICS

369299 For chemical reactions, the calculation of change in entropy is normally done

1 at constant pressure.
2 at constant temperature.
3 at both constant temperature and pressure.
4 at constant volume.
CHXI06:THERMODYNAMICS

369296 Which of the following statements is true?

1 The total entropy of the universe remains constant.
2 The total entropy of the universe is continuously decreasing.
3 The total energy of the universe is continuously decreasing.
4 The total energy of the universe remains constant.
CHXI06:THERMODYNAMICS

369297 Assertion :
The enthalpy of formation of gaseous oxygen molecules at \(298 \mathrm{~K}\) and under a pressure of one atmosphere is zero
Reason :
The entropy of formation of gaseous oxygen molecule under the same conditions is zero.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion & Reason are false.
CHXI06:THERMODYNAMICS

369298 Given the following entropy values (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) at \(\mathrm{298 \mathrm{~K}}\) and 1 atm: \(\mathrm{H_{2}(g): 130.6, \mathrm{Cl}_{2}(g): 223.0, \mathrm{HCl}(\mathrm{g}): 186.7}\). The entropy change (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) for the reaction \(\mathrm{\mathrm{H}_{2}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{HCl}(\mathrm{g})}\) is

1 \({\rm{ + 540}}{\rm{.3}}\)
2 \({\rm{ + 727}}{\rm{.0}}\)
3 \({\rm{ - 166}}{\rm{.9}}\)
4 \({\rm{ + 19}}{\rm{.8}}\)
CHXI06:THERMODYNAMICS

369299 For chemical reactions, the calculation of change in entropy is normally done

1 at constant pressure.
2 at constant temperature.
3 at both constant temperature and pressure.
4 at constant volume.
CHXI06:THERMODYNAMICS

369296 Which of the following statements is true?

1 The total entropy of the universe remains constant.
2 The total entropy of the universe is continuously decreasing.
3 The total energy of the universe is continuously decreasing.
4 The total energy of the universe remains constant.
CHXI06:THERMODYNAMICS

369297 Assertion :
The enthalpy of formation of gaseous oxygen molecules at \(298 \mathrm{~K}\) and under a pressure of one atmosphere is zero
Reason :
The entropy of formation of gaseous oxygen molecule under the same conditions is zero.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion & Reason are false.
CHXI06:THERMODYNAMICS

369298 Given the following entropy values (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) at \(\mathrm{298 \mathrm{~K}}\) and 1 atm: \(\mathrm{H_{2}(g): 130.6, \mathrm{Cl}_{2}(g): 223.0, \mathrm{HCl}(\mathrm{g}): 186.7}\). The entropy change (in \(\mathrm{\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}}\) ) for the reaction \(\mathrm{\mathrm{H}_{2}(\mathrm{~g})+\mathrm{Cl}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{HCl}(\mathrm{g})}\) is

1 \({\rm{ + 540}}{\rm{.3}}\)
2 \({\rm{ + 727}}{\rm{.0}}\)
3 \({\rm{ - 166}}{\rm{.9}}\)
4 \({\rm{ + 19}}{\rm{.8}}\)
CHXI06:THERMODYNAMICS

369299 For chemical reactions, the calculation of change in entropy is normally done

1 at constant pressure.
2 at constant temperature.
3 at both constant temperature and pressure.
4 at constant volume.