00. Electronic effect and Its Applications
GENERAL ORGANIC CHEMISTRY

231596 Consider the acidity of the carboxylic acids
(i) $\mathrm{PhCOOH}$
(ii) $\mathrm{o}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iii) $\mathrm{p}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iv) $\mathrm{m}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
Which of the following order is correct?

1 (i) $>$ (ii) $>$ (iii) $>$ (iv)
2 (ii) $>$ (iv) $>$ (iii) $>$ (i)
3 (ii) $>$ (iv) $>$ (i) $>$ (iii)
4 (ii) $>$ (iii) $>$ (iv) $>$ (i)
GENERAL ORGANIC CHEMISTRY

231597 Due to the presence of an unpaired electron free radicals are

1 Cations
2 Anions
3 Chemically inactive
4 Chemically reactive
GENERAL ORGANIC CHEMISTRY

231598 The correct order of increasing basic nature for the bases $\mathrm{NH}_{3}, \mathrm{CH}_{3} \mathrm{NH}_{2}$ and $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$ is

1 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\mathrm{NH}_{3}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
2 $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}$
3 $\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
4 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}$
GENERAL ORGANIC CHEMISTRY

231599 High basicity of $\mathrm{Me}_{2} \mathrm{NH}$ relative to $\mathrm{Me}_{3} \mathrm{~N}$ is attributed. to:

1 Effect of solvent
2 Inductive effect of me
3 Shape of $\mathrm{Me}_{2} \mathrm{NH}$
4 Shape of $\mathrm{Me}_{3} \mathrm{~N}$
GENERAL ORGANIC CHEMISTRY

231601 Which out of the following is the strongest acid?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

231596 Consider the acidity of the carboxylic acids
(i) $\mathrm{PhCOOH}$
(ii) $\mathrm{o}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iii) $\mathrm{p}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iv) $\mathrm{m}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
Which of the following order is correct?

1 (i) $>$ (ii) $>$ (iii) $>$ (iv)
2 (ii) $>$ (iv) $>$ (iii) $>$ (i)
3 (ii) $>$ (iv) $>$ (i) $>$ (iii)
4 (ii) $>$ (iii) $>$ (iv) $>$ (i)
GENERAL ORGANIC CHEMISTRY

231597 Due to the presence of an unpaired electron free radicals are

1 Cations
2 Anions
3 Chemically inactive
4 Chemically reactive
GENERAL ORGANIC CHEMISTRY

231598 The correct order of increasing basic nature for the bases $\mathrm{NH}_{3}, \mathrm{CH}_{3} \mathrm{NH}_{2}$ and $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$ is

1 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\mathrm{NH}_{3}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
2 $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}$
3 $\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
4 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}$
GENERAL ORGANIC CHEMISTRY

231599 High basicity of $\mathrm{Me}_{2} \mathrm{NH}$ relative to $\mathrm{Me}_{3} \mathrm{~N}$ is attributed. to:

1 Effect of solvent
2 Inductive effect of me
3 Shape of $\mathrm{Me}_{2} \mathrm{NH}$
4 Shape of $\mathrm{Me}_{3} \mathrm{~N}$
GENERAL ORGANIC CHEMISTRY

231601 Which out of the following is the strongest acid?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

231596 Consider the acidity of the carboxylic acids
(i) $\mathrm{PhCOOH}$
(ii) $\mathrm{o}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iii) $\mathrm{p}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iv) $\mathrm{m}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
Which of the following order is correct?

1 (i) $>$ (ii) $>$ (iii) $>$ (iv)
2 (ii) $>$ (iv) $>$ (iii) $>$ (i)
3 (ii) $>$ (iv) $>$ (i) $>$ (iii)
4 (ii) $>$ (iii) $>$ (iv) $>$ (i)
GENERAL ORGANIC CHEMISTRY

231597 Due to the presence of an unpaired electron free radicals are

1 Cations
2 Anions
3 Chemically inactive
4 Chemically reactive
GENERAL ORGANIC CHEMISTRY

231598 The correct order of increasing basic nature for the bases $\mathrm{NH}_{3}, \mathrm{CH}_{3} \mathrm{NH}_{2}$ and $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$ is

1 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\mathrm{NH}_{3}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
2 $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}$
3 $\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
4 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}$
GENERAL ORGANIC CHEMISTRY

231599 High basicity of $\mathrm{Me}_{2} \mathrm{NH}$ relative to $\mathrm{Me}_{3} \mathrm{~N}$ is attributed. to:

1 Effect of solvent
2 Inductive effect of me
3 Shape of $\mathrm{Me}_{2} \mathrm{NH}$
4 Shape of $\mathrm{Me}_{3} \mathrm{~N}$
GENERAL ORGANIC CHEMISTRY

231601 Which out of the following is the strongest acid?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

231596 Consider the acidity of the carboxylic acids
(i) $\mathrm{PhCOOH}$
(ii) $\mathrm{o}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iii) $\mathrm{p}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iv) $\mathrm{m}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
Which of the following order is correct?

1 (i) $>$ (ii) $>$ (iii) $>$ (iv)
2 (ii) $>$ (iv) $>$ (iii) $>$ (i)
3 (ii) $>$ (iv) $>$ (i) $>$ (iii)
4 (ii) $>$ (iii) $>$ (iv) $>$ (i)
GENERAL ORGANIC CHEMISTRY

231597 Due to the presence of an unpaired electron free radicals are

1 Cations
2 Anions
3 Chemically inactive
4 Chemically reactive
GENERAL ORGANIC CHEMISTRY

231598 The correct order of increasing basic nature for the bases $\mathrm{NH}_{3}, \mathrm{CH}_{3} \mathrm{NH}_{2}$ and $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$ is

1 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\mathrm{NH}_{3}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
2 $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}$
3 $\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
4 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}$
GENERAL ORGANIC CHEMISTRY

231599 High basicity of $\mathrm{Me}_{2} \mathrm{NH}$ relative to $\mathrm{Me}_{3} \mathrm{~N}$ is attributed. to:

1 Effect of solvent
2 Inductive effect of me
3 Shape of $\mathrm{Me}_{2} \mathrm{NH}$
4 Shape of $\mathrm{Me}_{3} \mathrm{~N}$
GENERAL ORGANIC CHEMISTRY

231601 Which out of the following is the strongest acid?

1 original image
2 original image
3 original image
4 original image
GENERAL ORGANIC CHEMISTRY

231596 Consider the acidity of the carboxylic acids
(i) $\mathrm{PhCOOH}$
(ii) $\mathrm{o}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iii) $\mathrm{p}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
(iv) $\mathrm{m}-\mathrm{NO}_{2} \mathrm{C}_{6} \mathrm{H}_{4} \mathrm{COOH}$
Which of the following order is correct?

1 (i) $>$ (ii) $>$ (iii) $>$ (iv)
2 (ii) $>$ (iv) $>$ (iii) $>$ (i)
3 (ii) $>$ (iv) $>$ (i) $>$ (iii)
4 (ii) $>$ (iii) $>$ (iv) $>$ (i)
GENERAL ORGANIC CHEMISTRY

231597 Due to the presence of an unpaired electron free radicals are

1 Cations
2 Anions
3 Chemically inactive
4 Chemically reactive
GENERAL ORGANIC CHEMISTRY

231598 The correct order of increasing basic nature for the bases $\mathrm{NH}_{3}, \mathrm{CH}_{3} \mathrm{NH}_{2}$ and $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$ is

1 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\mathrm{NH}_{3}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
2 $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}$
3 $\mathrm{NH}_{3}<\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}$
4 $\mathrm{CH}_{3} \mathrm{NH}_{2}<\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}<\mathrm{NH}_{3}$
GENERAL ORGANIC CHEMISTRY

231599 High basicity of $\mathrm{Me}_{2} \mathrm{NH}$ relative to $\mathrm{Me}_{3} \mathrm{~N}$ is attributed. to:

1 Effect of solvent
2 Inductive effect of me
3 Shape of $\mathrm{Me}_{2} \mathrm{NH}$
4 Shape of $\mathrm{Me}_{3} \mathrm{~N}$
GENERAL ORGANIC CHEMISTRY

231601 Which out of the following is the strongest acid?

1 original image
2 original image
3 original image
4 original image