06. Application of Kp and Kc
Chemical Equilibrium

229269 At room temperature, for the reaction
$\mathbf{N H}_{4} \mathbf{S H}(\mathrm{s}) \rightleftharpoons \mathbf{N H}_{3}(\mathrm{~g})+\mathbf{H}_{2} \mathbf{S}(\mathrm{g})$

1 $\mathrm{K}_{\mathrm{p}}=\mathrm{K}_{\mathrm{c}}$
2 $\mathrm{K}_{\mathrm{p}}>\mathrm{K}_{\mathrm{c}}$
3 $\mathrm{K}_{\mathrm{p}}<\mathrm{K}_{\mathrm{c}}$
4 $K_{p}$ and $K_{c}$ do not relate.
Chemical Equilibrium

229270 On passing $\mathrm{H}_{2} \mathrm{~S}$ into a solution containing both $\mathrm{Zn}^{2+}$ and $\mathrm{Cu}^{2+}$ in acidic medium, only $\mathrm{CuS}$ gets precipitated. This is because

1 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}<\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
2 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}=\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
3 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}>\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
4 $\mathrm{CuS}$ is more stable than $\mathrm{ZnS}$.
Chemical Equilibrium

229271 The equilibrium constant $K_{\mathrm{c}}$ for the reaction
$\mathrm{SO}_{2}(\mathrm{~g})+\mathrm{NO}_{2}(\mathrm{~g}) \rightleftharpoons \quad \mathrm{SO}_{3}(\mathrm{~g})+\mathrm{NO}(\mathrm{g})$
is 16. If one mole of all four gases is taken in a one litre container, the equilibrium concentration of $\mathrm{SO}_{3}$ would be:

1 $0.4 \mathrm{~m}$
2 $0.6 \mathrm{~m}$
3 $1.4 \mathrm{~m}$
4 $1.6 \mathrm{~m}$
Chemical Equilibrium

229273 A vessel at $1000 \mathrm{~K}$ contains $\mathrm{CO}_{2}$ with a pressure of 0.5 atm. Some of the $\mathrm{CO}_{2}$ is converted into $\mathrm{CO}$ on the addition of graphite. The value of $K$ if the total pressure at equilibrium is $0.8 \mathrm{~atm}$, is

1 $1.8 \mathrm{~atm}$
2 $3 \mathrm{~atm}$
3 $0.3 \mathrm{~atm}$
4 $0.18 \mathrm{~atm}$
Chemical Equilibrium

229269 At room temperature, for the reaction
$\mathbf{N H}_{4} \mathbf{S H}(\mathrm{s}) \rightleftharpoons \mathbf{N H}_{3}(\mathrm{~g})+\mathbf{H}_{2} \mathbf{S}(\mathrm{g})$

1 $\mathrm{K}_{\mathrm{p}}=\mathrm{K}_{\mathrm{c}}$
2 $\mathrm{K}_{\mathrm{p}}>\mathrm{K}_{\mathrm{c}}$
3 $\mathrm{K}_{\mathrm{p}}<\mathrm{K}_{\mathrm{c}}$
4 $K_{p}$ and $K_{c}$ do not relate.
Chemical Equilibrium

229270 On passing $\mathrm{H}_{2} \mathrm{~S}$ into a solution containing both $\mathrm{Zn}^{2+}$ and $\mathrm{Cu}^{2+}$ in acidic medium, only $\mathrm{CuS}$ gets precipitated. This is because

1 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}<\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
2 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}=\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
3 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}>\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
4 $\mathrm{CuS}$ is more stable than $\mathrm{ZnS}$.
Chemical Equilibrium

229271 The equilibrium constant $K_{\mathrm{c}}$ for the reaction
$\mathrm{SO}_{2}(\mathrm{~g})+\mathrm{NO}_{2}(\mathrm{~g}) \rightleftharpoons \quad \mathrm{SO}_{3}(\mathrm{~g})+\mathrm{NO}(\mathrm{g})$
is 16. If one mole of all four gases is taken in a one litre container, the equilibrium concentration of $\mathrm{SO}_{3}$ would be:

1 $0.4 \mathrm{~m}$
2 $0.6 \mathrm{~m}$
3 $1.4 \mathrm{~m}$
4 $1.6 \mathrm{~m}$
Chemical Equilibrium

229273 A vessel at $1000 \mathrm{~K}$ contains $\mathrm{CO}_{2}$ with a pressure of 0.5 atm. Some of the $\mathrm{CO}_{2}$ is converted into $\mathrm{CO}$ on the addition of graphite. The value of $K$ if the total pressure at equilibrium is $0.8 \mathrm{~atm}$, is

1 $1.8 \mathrm{~atm}$
2 $3 \mathrm{~atm}$
3 $0.3 \mathrm{~atm}$
4 $0.18 \mathrm{~atm}$
Chemical Equilibrium

229269 At room temperature, for the reaction
$\mathbf{N H}_{4} \mathbf{S H}(\mathrm{s}) \rightleftharpoons \mathbf{N H}_{3}(\mathrm{~g})+\mathbf{H}_{2} \mathbf{S}(\mathrm{g})$

1 $\mathrm{K}_{\mathrm{p}}=\mathrm{K}_{\mathrm{c}}$
2 $\mathrm{K}_{\mathrm{p}}>\mathrm{K}_{\mathrm{c}}$
3 $\mathrm{K}_{\mathrm{p}}<\mathrm{K}_{\mathrm{c}}$
4 $K_{p}$ and $K_{c}$ do not relate.
Chemical Equilibrium

229270 On passing $\mathrm{H}_{2} \mathrm{~S}$ into a solution containing both $\mathrm{Zn}^{2+}$ and $\mathrm{Cu}^{2+}$ in acidic medium, only $\mathrm{CuS}$ gets precipitated. This is because

1 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}<\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
2 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}=\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
3 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}>\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
4 $\mathrm{CuS}$ is more stable than $\mathrm{ZnS}$.
Chemical Equilibrium

229271 The equilibrium constant $K_{\mathrm{c}}$ for the reaction
$\mathrm{SO}_{2}(\mathrm{~g})+\mathrm{NO}_{2}(\mathrm{~g}) \rightleftharpoons \quad \mathrm{SO}_{3}(\mathrm{~g})+\mathrm{NO}(\mathrm{g})$
is 16. If one mole of all four gases is taken in a one litre container, the equilibrium concentration of $\mathrm{SO}_{3}$ would be:

1 $0.4 \mathrm{~m}$
2 $0.6 \mathrm{~m}$
3 $1.4 \mathrm{~m}$
4 $1.6 \mathrm{~m}$
Chemical Equilibrium

229273 A vessel at $1000 \mathrm{~K}$ contains $\mathrm{CO}_{2}$ with a pressure of 0.5 atm. Some of the $\mathrm{CO}_{2}$ is converted into $\mathrm{CO}$ on the addition of graphite. The value of $K$ if the total pressure at equilibrium is $0.8 \mathrm{~atm}$, is

1 $1.8 \mathrm{~atm}$
2 $3 \mathrm{~atm}$
3 $0.3 \mathrm{~atm}$
4 $0.18 \mathrm{~atm}$
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Chemical Equilibrium

229269 At room temperature, for the reaction
$\mathbf{N H}_{4} \mathbf{S H}(\mathrm{s}) \rightleftharpoons \mathbf{N H}_{3}(\mathrm{~g})+\mathbf{H}_{2} \mathbf{S}(\mathrm{g})$

1 $\mathrm{K}_{\mathrm{p}}=\mathrm{K}_{\mathrm{c}}$
2 $\mathrm{K}_{\mathrm{p}}>\mathrm{K}_{\mathrm{c}}$
3 $\mathrm{K}_{\mathrm{p}}<\mathrm{K}_{\mathrm{c}}$
4 $K_{p}$ and $K_{c}$ do not relate.
Chemical Equilibrium

229270 On passing $\mathrm{H}_{2} \mathrm{~S}$ into a solution containing both $\mathrm{Zn}^{2+}$ and $\mathrm{Cu}^{2+}$ in acidic medium, only $\mathrm{CuS}$ gets precipitated. This is because

1 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}<\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
2 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}=\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
3 $\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{CuS}>\mathrm{K}_{\mathrm{sp}}$ of $\mathrm{ZnS}$
4 $\mathrm{CuS}$ is more stable than $\mathrm{ZnS}$.
Chemical Equilibrium

229271 The equilibrium constant $K_{\mathrm{c}}$ for the reaction
$\mathrm{SO}_{2}(\mathrm{~g})+\mathrm{NO}_{2}(\mathrm{~g}) \rightleftharpoons \quad \mathrm{SO}_{3}(\mathrm{~g})+\mathrm{NO}(\mathrm{g})$
is 16. If one mole of all four gases is taken in a one litre container, the equilibrium concentration of $\mathrm{SO}_{3}$ would be:

1 $0.4 \mathrm{~m}$
2 $0.6 \mathrm{~m}$
3 $1.4 \mathrm{~m}$
4 $1.6 \mathrm{~m}$
Chemical Equilibrium

229273 A vessel at $1000 \mathrm{~K}$ contains $\mathrm{CO}_{2}$ with a pressure of 0.5 atm. Some of the $\mathrm{CO}_{2}$ is converted into $\mathrm{CO}$ on the addition of graphite. The value of $K$ if the total pressure at equilibrium is $0.8 \mathrm{~atm}$, is

1 $1.8 \mathrm{~atm}$
2 $3 \mathrm{~atm}$
3 $0.3 \mathrm{~atm}$
4 $0.18 \mathrm{~atm}$