05. Gibbs Energy Change and Equilibrium
Thermodynamics

273052 Given below are two statements:
Statement I: According to the Ellingham diagram, any metal oxide with higher $\Delta \mathrm{G}^{\circ}$ is more stable than the one with lower $\Delta \mathrm{G}^{\circ}$
Statement II: The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Statement I and Statement II are correct.
2 Both Statement I and Statement II are incorrect
3 Statement I is correct but Statement II is incorrect.
4 Statement I is incorrect but Statement II is correct.
Thermodynamics

273055 An endothermic reaction is found to have +ve entropy change. The reaction will be

1 possible at high temperature
2 possible only at low temperature
3 not possible at any temperature
4 possible at any temperature.
Thermodynamics

273058 Following reaction occurrs in an automobile
$2 \mathrm{C}_8 \mathrm{H}_{18}(\mathrm{~g})+25 \mathrm{O}_2(\mathrm{~g}) \rightarrow 16 \mathrm{CO}_2(\mathrm{~g})+18 \mathrm{H}_2 \mathrm{O}(\mathrm{g})$
The sign of $\Delta H, \Delta S$ and $\Delta G$ would be

1 ,,+-+
2 ,,-+-
3 ,,-++
4 ,,++-
Thermodynamics

273059 For a reaction to be spontaneous at all temperatures,

1 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=+$ ve and $\Delta \mathrm{S}=+\mathrm{ve}$
2 $\Delta \mathrm{G}=+\mathrm{ve}, \Delta \mathrm{H}=-\mathrm{ve}$ and $\Delta \mathrm{S}=+\mathrm{ve}$
3 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=-\mathrm{ve}$
4 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=+$ ve
Thermodynamics

273052 Given below are two statements:
Statement I: According to the Ellingham diagram, any metal oxide with higher $\Delta \mathrm{G}^{\circ}$ is more stable than the one with lower $\Delta \mathrm{G}^{\circ}$
Statement II: The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Statement I and Statement II are correct.
2 Both Statement I and Statement II are incorrect
3 Statement I is correct but Statement II is incorrect.
4 Statement I is incorrect but Statement II is correct.
Thermodynamics

273055 An endothermic reaction is found to have +ve entropy change. The reaction will be

1 possible at high temperature
2 possible only at low temperature
3 not possible at any temperature
4 possible at any temperature.
Thermodynamics

273058 Following reaction occurrs in an automobile
$2 \mathrm{C}_8 \mathrm{H}_{18}(\mathrm{~g})+25 \mathrm{O}_2(\mathrm{~g}) \rightarrow 16 \mathrm{CO}_2(\mathrm{~g})+18 \mathrm{H}_2 \mathrm{O}(\mathrm{g})$
The sign of $\Delta H, \Delta S$ and $\Delta G$ would be

1 ,,+-+
2 ,,-+-
3 ,,-++
4 ,,++-
Thermodynamics

273059 For a reaction to be spontaneous at all temperatures,

1 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=+$ ve and $\Delta \mathrm{S}=+\mathrm{ve}$
2 $\Delta \mathrm{G}=+\mathrm{ve}, \Delta \mathrm{H}=-\mathrm{ve}$ and $\Delta \mathrm{S}=+\mathrm{ve}$
3 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=-\mathrm{ve}$
4 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=+$ ve
Thermodynamics

273052 Given below are two statements:
Statement I: According to the Ellingham diagram, any metal oxide with higher $\Delta \mathrm{G}^{\circ}$ is more stable than the one with lower $\Delta \mathrm{G}^{\circ}$
Statement II: The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Statement I and Statement II are correct.
2 Both Statement I and Statement II are incorrect
3 Statement I is correct but Statement II is incorrect.
4 Statement I is incorrect but Statement II is correct.
Thermodynamics

273055 An endothermic reaction is found to have +ve entropy change. The reaction will be

1 possible at high temperature
2 possible only at low temperature
3 not possible at any temperature
4 possible at any temperature.
Thermodynamics

273058 Following reaction occurrs in an automobile
$2 \mathrm{C}_8 \mathrm{H}_{18}(\mathrm{~g})+25 \mathrm{O}_2(\mathrm{~g}) \rightarrow 16 \mathrm{CO}_2(\mathrm{~g})+18 \mathrm{H}_2 \mathrm{O}(\mathrm{g})$
The sign of $\Delta H, \Delta S$ and $\Delta G$ would be

1 ,,+-+
2 ,,-+-
3 ,,-++
4 ,,++-
Thermodynamics

273059 For a reaction to be spontaneous at all temperatures,

1 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=+$ ve and $\Delta \mathrm{S}=+\mathrm{ve}$
2 $\Delta \mathrm{G}=+\mathrm{ve}, \Delta \mathrm{H}=-\mathrm{ve}$ and $\Delta \mathrm{S}=+\mathrm{ve}$
3 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=-\mathrm{ve}$
4 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=+$ ve
Thermodynamics

273052 Given below are two statements:
Statement I: According to the Ellingham diagram, any metal oxide with higher $\Delta \mathrm{G}^{\circ}$ is more stable than the one with lower $\Delta \mathrm{G}^{\circ}$
Statement II: The metal involved in the formation of oxide placed lower in the Ellingham diagram can reduce the oxide of a metal placed higher in the diagram.
In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Statement I and Statement II are correct.
2 Both Statement I and Statement II are incorrect
3 Statement I is correct but Statement II is incorrect.
4 Statement I is incorrect but Statement II is correct.
Thermodynamics

273055 An endothermic reaction is found to have +ve entropy change. The reaction will be

1 possible at high temperature
2 possible only at low temperature
3 not possible at any temperature
4 possible at any temperature.
Thermodynamics

273058 Following reaction occurrs in an automobile
$2 \mathrm{C}_8 \mathrm{H}_{18}(\mathrm{~g})+25 \mathrm{O}_2(\mathrm{~g}) \rightarrow 16 \mathrm{CO}_2(\mathrm{~g})+18 \mathrm{H}_2 \mathrm{O}(\mathrm{g})$
The sign of $\Delta H, \Delta S$ and $\Delta G$ would be

1 ,,+-+
2 ,,-+-
3 ,,-++
4 ,,++-
Thermodynamics

273059 For a reaction to be spontaneous at all temperatures,

1 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=+$ ve and $\Delta \mathrm{S}=+\mathrm{ve}$
2 $\Delta \mathrm{G}=+\mathrm{ve}, \Delta \mathrm{H}=-\mathrm{ve}$ and $\Delta \mathrm{S}=+\mathrm{ve}$
3 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=-\mathrm{ve}$
4 $\Delta \mathrm{G}=-\mathrm{ve}, \Delta \mathrm{H}=-$ ve and $\Delta \mathrm{S}=+$ ve
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