02. Second Law of Thermodynamics and Entropy
Thermodynamics

272762 If one mole of ammonia and one mole of hydrogen chloride are mixed in a closed container to form ammonium chloride gas, then

1 $\Delta \mathrm{H}>\Delta \mathrm{U}$
2 $\Delta \mathrm{H}=\Delta \mathrm{U}$
3 $\Delta \mathrm{H}<\Delta \mathrm{U}$
4 there is no relationship
Thermodynamics

272763 In the reaction; $A_2(\mathrm{~g})+3 B_2(\mathrm{~g}) \longrightarrow 2 A B_3(\mathrm{~g})$ the standard entropies in $\left(\mathrm{JK}^{-1} \mathrm{~mol}^{-1}\right)$ of $\mathrm{A}_2(\mathrm{~g})$
$B_2(g)$ and $\mathrm{AB}_3(\mathrm{~g})$ are respectively 190,130 and 195 and the enthalpy change for the reaction is
$-95 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The temperature (in $\mathrm{K}$ ) at which the reaction attains equilibrium is (assuming both the standard entropy change and standard enthalpy change for this reaction are constant over a wide range of temperature)

1 500
2 400
3 300
4 600
5 700
Thermodynamics

272766 The enthalpy of vaporization of a certain liquid at its boiling point of $35^{\circ} \mathrm{C}$ is $24.64 \mathrm{~kJ}$ mol $^{-1}$. The value of change in entropy for the process is

1 $704 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
2 $80 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
3 $24.64 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
4 $7.04 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
Thermodynamics

272734 For one mole of $\mathrm{NaCl}(\mathrm{s})$ the lattice enthalpy is
\[
\begin{array} { l }
{ \left[ \Delta _ { a } \mathrm { H } ^ { - } ( \mathrm { Na } ) = 108.4 , \Delta _ { i } \mathrm { H } ^ { * } ( \mathrm { Na } ) = 496 , \Delta _ { \mathrm { ond } } \mathrm { H } ^ { * } ( \mathrm { Cl } \rangle \right.} \\
= 242 , \Delta _ { \mathrm { od } } \mathrm { H } ^ { \circ } ( \mathrm { Cl } ) = - 348.6 \text { and } \Delta \mathrm { H } \left( \mathrm { NaCl } ^ { 2 } \right) \\
= - 411.2 ]
\end{array}
\]

1 \(-788 \mathrm{~kJ} / \mathrm{mol}\)
2 \(+878 \mathrm{~kJ} / \mathrm{mol}\)
3 \(+788 \mathrm{~kJ} / \mathrm{mol}\)
4 \(-878 \mathrm{~kJ} / \mathrm{mol}\)
Thermodynamics

272762 If one mole of ammonia and one mole of hydrogen chloride are mixed in a closed container to form ammonium chloride gas, then

1 $\Delta \mathrm{H}>\Delta \mathrm{U}$
2 $\Delta \mathrm{H}=\Delta \mathrm{U}$
3 $\Delta \mathrm{H}<\Delta \mathrm{U}$
4 there is no relationship
Thermodynamics

272763 In the reaction; $A_2(\mathrm{~g})+3 B_2(\mathrm{~g}) \longrightarrow 2 A B_3(\mathrm{~g})$ the standard entropies in $\left(\mathrm{JK}^{-1} \mathrm{~mol}^{-1}\right)$ of $\mathrm{A}_2(\mathrm{~g})$
$B_2(g)$ and $\mathrm{AB}_3(\mathrm{~g})$ are respectively 190,130 and 195 and the enthalpy change for the reaction is
$-95 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The temperature (in $\mathrm{K}$ ) at which the reaction attains equilibrium is (assuming both the standard entropy change and standard enthalpy change for this reaction are constant over a wide range of temperature)

1 500
2 400
3 300
4 600
5 700
Thermodynamics

272766 The enthalpy of vaporization of a certain liquid at its boiling point of $35^{\circ} \mathrm{C}$ is $24.64 \mathrm{~kJ}$ mol $^{-1}$. The value of change in entropy for the process is

1 $704 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
2 $80 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
3 $24.64 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
4 $7.04 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
Thermodynamics

272734 For one mole of $\mathrm{NaCl}(\mathrm{s})$ the lattice enthalpy is
\[
\begin{array} { l }
{ \left[ \Delta _ { a } \mathrm { H } ^ { - } ( \mathrm { Na } ) = 108.4 , \Delta _ { i } \mathrm { H } ^ { * } ( \mathrm { Na } ) = 496 , \Delta _ { \mathrm { ond } } \mathrm { H } ^ { * } ( \mathrm { Cl } \rangle \right.} \\
= 242 , \Delta _ { \mathrm { od } } \mathrm { H } ^ { \circ } ( \mathrm { Cl } ) = - 348.6 \text { and } \Delta \mathrm { H } \left( \mathrm { NaCl } ^ { 2 } \right) \\
= - 411.2 ]
\end{array}
\]

1 \(-788 \mathrm{~kJ} / \mathrm{mol}\)
2 \(+878 \mathrm{~kJ} / \mathrm{mol}\)
3 \(+788 \mathrm{~kJ} / \mathrm{mol}\)
4 \(-878 \mathrm{~kJ} / \mathrm{mol}\)
Thermodynamics

272762 If one mole of ammonia and one mole of hydrogen chloride are mixed in a closed container to form ammonium chloride gas, then

1 $\Delta \mathrm{H}>\Delta \mathrm{U}$
2 $\Delta \mathrm{H}=\Delta \mathrm{U}$
3 $\Delta \mathrm{H}<\Delta \mathrm{U}$
4 there is no relationship
Thermodynamics

272763 In the reaction; $A_2(\mathrm{~g})+3 B_2(\mathrm{~g}) \longrightarrow 2 A B_3(\mathrm{~g})$ the standard entropies in $\left(\mathrm{JK}^{-1} \mathrm{~mol}^{-1}\right)$ of $\mathrm{A}_2(\mathrm{~g})$
$B_2(g)$ and $\mathrm{AB}_3(\mathrm{~g})$ are respectively 190,130 and 195 and the enthalpy change for the reaction is
$-95 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The temperature (in $\mathrm{K}$ ) at which the reaction attains equilibrium is (assuming both the standard entropy change and standard enthalpy change for this reaction are constant over a wide range of temperature)

1 500
2 400
3 300
4 600
5 700
Thermodynamics

272766 The enthalpy of vaporization of a certain liquid at its boiling point of $35^{\circ} \mathrm{C}$ is $24.64 \mathrm{~kJ}$ mol $^{-1}$. The value of change in entropy for the process is

1 $704 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
2 $80 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
3 $24.64 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
4 $7.04 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
Thermodynamics

272734 For one mole of $\mathrm{NaCl}(\mathrm{s})$ the lattice enthalpy is
\[
\begin{array} { l }
{ \left[ \Delta _ { a } \mathrm { H } ^ { - } ( \mathrm { Na } ) = 108.4 , \Delta _ { i } \mathrm { H } ^ { * } ( \mathrm { Na } ) = 496 , \Delta _ { \mathrm { ond } } \mathrm { H } ^ { * } ( \mathrm { Cl } \rangle \right.} \\
= 242 , \Delta _ { \mathrm { od } } \mathrm { H } ^ { \circ } ( \mathrm { Cl } ) = - 348.6 \text { and } \Delta \mathrm { H } \left( \mathrm { NaCl } ^ { 2 } \right) \\
= - 411.2 ]
\end{array}
\]

1 \(-788 \mathrm{~kJ} / \mathrm{mol}\)
2 \(+878 \mathrm{~kJ} / \mathrm{mol}\)
3 \(+788 \mathrm{~kJ} / \mathrm{mol}\)
4 \(-878 \mathrm{~kJ} / \mathrm{mol}\)
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Thermodynamics

272762 If one mole of ammonia and one mole of hydrogen chloride are mixed in a closed container to form ammonium chloride gas, then

1 $\Delta \mathrm{H}>\Delta \mathrm{U}$
2 $\Delta \mathrm{H}=\Delta \mathrm{U}$
3 $\Delta \mathrm{H}<\Delta \mathrm{U}$
4 there is no relationship
Thermodynamics

272763 In the reaction; $A_2(\mathrm{~g})+3 B_2(\mathrm{~g}) \longrightarrow 2 A B_3(\mathrm{~g})$ the standard entropies in $\left(\mathrm{JK}^{-1} \mathrm{~mol}^{-1}\right)$ of $\mathrm{A}_2(\mathrm{~g})$
$B_2(g)$ and $\mathrm{AB}_3(\mathrm{~g})$ are respectively 190,130 and 195 and the enthalpy change for the reaction is
$-95 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The temperature (in $\mathrm{K}$ ) at which the reaction attains equilibrium is (assuming both the standard entropy change and standard enthalpy change for this reaction are constant over a wide range of temperature)

1 500
2 400
3 300
4 600
5 700
Thermodynamics

272766 The enthalpy of vaporization of a certain liquid at its boiling point of $35^{\circ} \mathrm{C}$ is $24.64 \mathrm{~kJ}$ mol $^{-1}$. The value of change in entropy for the process is

1 $704 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
2 $80 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
3 $24.64 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
4 $7.04 \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$
Thermodynamics

272734 For one mole of $\mathrm{NaCl}(\mathrm{s})$ the lattice enthalpy is
\[
\begin{array} { l }
{ \left[ \Delta _ { a } \mathrm { H } ^ { - } ( \mathrm { Na } ) = 108.4 , \Delta _ { i } \mathrm { H } ^ { * } ( \mathrm { Na } ) = 496 , \Delta _ { \mathrm { ond } } \mathrm { H } ^ { * } ( \mathrm { Cl } \rangle \right.} \\
= 242 , \Delta _ { \mathrm { od } } \mathrm { H } ^ { \circ } ( \mathrm { Cl } ) = - 348.6 \text { and } \Delta \mathrm { H } \left( \mathrm { NaCl } ^ { 2 } \right) \\
= - 411.2 ]
\end{array}
\]

1 \(-788 \mathrm{~kJ} / \mathrm{mol}\)
2 \(+878 \mathrm{~kJ} / \mathrm{mol}\)
3 \(+788 \mathrm{~kJ} / \mathrm{mol}\)
4 \(-878 \mathrm{~kJ} / \mathrm{mol}\)