Nomenclature, Preparation and Properties of Nitro Compounds
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CHXII13:AMINES

324313 Which of the following reaction can produce aniline as main product?

1 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{KOH}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{LiAlH}_{4}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{HCl}\)
CHXII13:AMINES

324314 Nitrobenzene on reaction with conc.
\(\mathrm{HNO}_{3} / \mathrm{H}_{2} \mathrm{SO}_{4}\) at \(80-100^{\circ} \mathrm{C}\) forms which one of the following products?

1 1,3-Dinitrobenzene
2 1,4-Dinitrobenzene
3 1, 2, 4-Trinitrobenzene
4 1,2-Dinitrobenzene
CHXII13:AMINES

324315 Identify the compound ' \({\rm{X}}\) ' in the following reaction:
\(\mathrm{CH}_{3} \mathrm{NO}_{2} \xrightarrow[\text { Excess }]{\mathrm{Cl}_{2} / \mathrm{NaOH}} \mathrm{X}\)

1 \(\mathrm{ClCH}_{2} \mathrm{NO}_{2}\)
2 \(\mathrm{Cl}_{2} \mathrm{CHNO}_{2}\)
3 \(\mathrm{Cl}_{3} \mathrm{CNO}_{2}\)
4 \(\mathrm{CH}_{3} \mathrm{Cl}\)
CHXII13:AMINES

324316 supporting img

In the above conversion the correct sequence of reagents to be added is

1 (i) \(\mathrm{KMnO}_{4}\), (ii) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (iii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iv) \(\mathrm{Cl}_{2}\)
2 (i) \(\mathrm{Fe} / \mathrm{H}^{+}\), (ii) HONO , (iii) CuCl , (iv) \(\mathrm{KMnO}_{4}\),
(v) \(\mathrm{Br}_{2}\)
3 (i) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) HONO ,(iv) CuCl ,
(v) \(\mathrm{KMnO}_{4}\)
4 (i) \(\mathrm{Br} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) \(\mathrm{KMnO}_{4}\), (iv) \(\mathrm{Cl}_{2}\)
JEE - 2023
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CHXII13:AMINES

324313 Which of the following reaction can produce aniline as main product?

1 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{KOH}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{LiAlH}_{4}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{HCl}\)
CHXII13:AMINES

324314 Nitrobenzene on reaction with conc.
\(\mathrm{HNO}_{3} / \mathrm{H}_{2} \mathrm{SO}_{4}\) at \(80-100^{\circ} \mathrm{C}\) forms which one of the following products?

1 1,3-Dinitrobenzene
2 1,4-Dinitrobenzene
3 1, 2, 4-Trinitrobenzene
4 1,2-Dinitrobenzene
CHXII13:AMINES

324315 Identify the compound ' \({\rm{X}}\) ' in the following reaction:
\(\mathrm{CH}_{3} \mathrm{NO}_{2} \xrightarrow[\text { Excess }]{\mathrm{Cl}_{2} / \mathrm{NaOH}} \mathrm{X}\)

1 \(\mathrm{ClCH}_{2} \mathrm{NO}_{2}\)
2 \(\mathrm{Cl}_{2} \mathrm{CHNO}_{2}\)
3 \(\mathrm{Cl}_{3} \mathrm{CNO}_{2}\)
4 \(\mathrm{CH}_{3} \mathrm{Cl}\)
CHXII13:AMINES

324316 supporting img

In the above conversion the correct sequence of reagents to be added is

1 (i) \(\mathrm{KMnO}_{4}\), (ii) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (iii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iv) \(\mathrm{Cl}_{2}\)
2 (i) \(\mathrm{Fe} / \mathrm{H}^{+}\), (ii) HONO , (iii) CuCl , (iv) \(\mathrm{KMnO}_{4}\),
(v) \(\mathrm{Br}_{2}\)
3 (i) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) HONO ,(iv) CuCl ,
(v) \(\mathrm{KMnO}_{4}\)
4 (i) \(\mathrm{Br} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) \(\mathrm{KMnO}_{4}\), (iv) \(\mathrm{Cl}_{2}\)
JEE - 2023
NEET DIGITAL LIBRARY
CHXII13:AMINES

324313 Which of the following reaction can produce aniline as main product?

1 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{KOH}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{LiAlH}_{4}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{HCl}\)
CHXII13:AMINES

324314 Nitrobenzene on reaction with conc.
\(\mathrm{HNO}_{3} / \mathrm{H}_{2} \mathrm{SO}_{4}\) at \(80-100^{\circ} \mathrm{C}\) forms which one of the following products?

1 1,3-Dinitrobenzene
2 1,4-Dinitrobenzene
3 1, 2, 4-Trinitrobenzene
4 1,2-Dinitrobenzene
CHXII13:AMINES

324315 Identify the compound ' \({\rm{X}}\) ' in the following reaction:
\(\mathrm{CH}_{3} \mathrm{NO}_{2} \xrightarrow[\text { Excess }]{\mathrm{Cl}_{2} / \mathrm{NaOH}} \mathrm{X}\)

1 \(\mathrm{ClCH}_{2} \mathrm{NO}_{2}\)
2 \(\mathrm{Cl}_{2} \mathrm{CHNO}_{2}\)
3 \(\mathrm{Cl}_{3} \mathrm{CNO}_{2}\)
4 \(\mathrm{CH}_{3} \mathrm{Cl}\)
CHXII13:AMINES

324316 supporting img

In the above conversion the correct sequence of reagents to be added is

1 (i) \(\mathrm{KMnO}_{4}\), (ii) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (iii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iv) \(\mathrm{Cl}_{2}\)
2 (i) \(\mathrm{Fe} / \mathrm{H}^{+}\), (ii) HONO , (iii) CuCl , (iv) \(\mathrm{KMnO}_{4}\),
(v) \(\mathrm{Br}_{2}\)
3 (i) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) HONO ,(iv) CuCl ,
(v) \(\mathrm{KMnO}_{4}\)
4 (i) \(\mathrm{Br} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) \(\mathrm{KMnO}_{4}\), (iv) \(\mathrm{Cl}_{2}\)
JEE - 2023
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CHXII13:AMINES

324313 Which of the following reaction can produce aniline as main product?

1 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{KOH}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{LiAlH}_{4}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{NO}_{2}+\mathrm{Zn} / \mathrm{HCl}\)
CHXII13:AMINES

324314 Nitrobenzene on reaction with conc.
\(\mathrm{HNO}_{3} / \mathrm{H}_{2} \mathrm{SO}_{4}\) at \(80-100^{\circ} \mathrm{C}\) forms which one of the following products?

1 1,3-Dinitrobenzene
2 1,4-Dinitrobenzene
3 1, 2, 4-Trinitrobenzene
4 1,2-Dinitrobenzene
CHXII13:AMINES

324315 Identify the compound ' \({\rm{X}}\) ' in the following reaction:
\(\mathrm{CH}_{3} \mathrm{NO}_{2} \xrightarrow[\text { Excess }]{\mathrm{Cl}_{2} / \mathrm{NaOH}} \mathrm{X}\)

1 \(\mathrm{ClCH}_{2} \mathrm{NO}_{2}\)
2 \(\mathrm{Cl}_{2} \mathrm{CHNO}_{2}\)
3 \(\mathrm{Cl}_{3} \mathrm{CNO}_{2}\)
4 \(\mathrm{CH}_{3} \mathrm{Cl}\)
CHXII13:AMINES

324316 supporting img

In the above conversion the correct sequence of reagents to be added is

1 (i) \(\mathrm{KMnO}_{4}\), (ii) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (iii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iv) \(\mathrm{Cl}_{2}\)
2 (i) \(\mathrm{Fe} / \mathrm{H}^{+}\), (ii) HONO , (iii) CuCl , (iv) \(\mathrm{KMnO}_{4}\),
(v) \(\mathrm{Br}_{2}\)
3 (i) \(\mathrm{Br}_{2} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) HONO ,(iv) CuCl ,
(v) \(\mathrm{KMnO}_{4}\)
4 (i) \(\mathrm{Br} / \mathrm{Fe}\), (ii) \(\mathrm{Fe} / \mathrm{H}^{+}\), (iii) \(\mathrm{KMnO}_{4}\), (iv) \(\mathrm{Cl}_{2}\)
JEE - 2023
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