Diazonium Salts
CHXII13:AMINES

324235 In the reaction
supporting img
A is:

1 \(\mathrm{Cu}_{2} \mathrm{Cl}_{2}\)
2 \(\mathrm{H}_{3} \mathrm{PO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\)
3 \(\mathrm{H}^{+} / \mathrm{H}_{2} \mathrm{O}\)
4 \(\mathrm{HgSO}_{4} / \mathrm{H}_{2} \mathrm{SO}_{4}\)
CHXII13:AMINES

324236 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Cl} \underset{\mathrm{Cu}_{2} \mathrm{O}, 200^{\circ} \mathrm{C}}{\stackrel{\mathrm{NH}_{3}}{\longrightarrow}} \mathrm{X}\)
\(X \underset{0-5^{0} \mathrm{C}}{\stackrel{\mathrm{HNO}_{2}}{\longrightarrow}} Z ; X+Z \rightarrow A\); the no.of
\(\sigma\) and \(\pi\) bonds in 'A' are

1 \(25 \sigma, 6 \pi\)
2 \(25 \sigma, 7 \pi\)
3 \(27 \sigma, 7 \pi\)
4 \(27 \sigma, 6 \pi\)
CHXII13:AMINES

324237 When benzenediazonium chloride is heated with fluoro boric acid, fluorobenzene is formed. This reaction is called

1 Hoffmann bromamide reaction
2 Balz schiemann reaction
3 Gattermann reaction
4 Sandmeyer reaction
CHXII13:AMINES

324238 The reagent ' \(R\) ' in the given sequence of chemical reaction is :
supporting img

1 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
2 \(\mathrm{HI}\)
3 \(\mathrm{CuCN} / \mathrm{KCN}\)
4 \(\mathrm{H}_{2} \mathrm{O}\)
CHXII13:AMINES

324235 In the reaction
supporting img
A is:

1 \(\mathrm{Cu}_{2} \mathrm{Cl}_{2}\)
2 \(\mathrm{H}_{3} \mathrm{PO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\)
3 \(\mathrm{H}^{+} / \mathrm{H}_{2} \mathrm{O}\)
4 \(\mathrm{HgSO}_{4} / \mathrm{H}_{2} \mathrm{SO}_{4}\)
CHXII13:AMINES

324236 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Cl} \underset{\mathrm{Cu}_{2} \mathrm{O}, 200^{\circ} \mathrm{C}}{\stackrel{\mathrm{NH}_{3}}{\longrightarrow}} \mathrm{X}\)
\(X \underset{0-5^{0} \mathrm{C}}{\stackrel{\mathrm{HNO}_{2}}{\longrightarrow}} Z ; X+Z \rightarrow A\); the no.of
\(\sigma\) and \(\pi\) bonds in 'A' are

1 \(25 \sigma, 6 \pi\)
2 \(25 \sigma, 7 \pi\)
3 \(27 \sigma, 7 \pi\)
4 \(27 \sigma, 6 \pi\)
CHXII13:AMINES

324237 When benzenediazonium chloride is heated with fluoro boric acid, fluorobenzene is formed. This reaction is called

1 Hoffmann bromamide reaction
2 Balz schiemann reaction
3 Gattermann reaction
4 Sandmeyer reaction
CHXII13:AMINES

324238 The reagent ' \(R\) ' in the given sequence of chemical reaction is :
supporting img

1 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
2 \(\mathrm{HI}\)
3 \(\mathrm{CuCN} / \mathrm{KCN}\)
4 \(\mathrm{H}_{2} \mathrm{O}\)
CHXII13:AMINES

324235 In the reaction
supporting img
A is:

1 \(\mathrm{Cu}_{2} \mathrm{Cl}_{2}\)
2 \(\mathrm{H}_{3} \mathrm{PO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\)
3 \(\mathrm{H}^{+} / \mathrm{H}_{2} \mathrm{O}\)
4 \(\mathrm{HgSO}_{4} / \mathrm{H}_{2} \mathrm{SO}_{4}\)
CHXII13:AMINES

324236 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Cl} \underset{\mathrm{Cu}_{2} \mathrm{O}, 200^{\circ} \mathrm{C}}{\stackrel{\mathrm{NH}_{3}}{\longrightarrow}} \mathrm{X}\)
\(X \underset{0-5^{0} \mathrm{C}}{\stackrel{\mathrm{HNO}_{2}}{\longrightarrow}} Z ; X+Z \rightarrow A\); the no.of
\(\sigma\) and \(\pi\) bonds in 'A' are

1 \(25 \sigma, 6 \pi\)
2 \(25 \sigma, 7 \pi\)
3 \(27 \sigma, 7 \pi\)
4 \(27 \sigma, 6 \pi\)
CHXII13:AMINES

324237 When benzenediazonium chloride is heated with fluoro boric acid, fluorobenzene is formed. This reaction is called

1 Hoffmann bromamide reaction
2 Balz schiemann reaction
3 Gattermann reaction
4 Sandmeyer reaction
CHXII13:AMINES

324238 The reagent ' \(R\) ' in the given sequence of chemical reaction is :
supporting img

1 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
2 \(\mathrm{HI}\)
3 \(\mathrm{CuCN} / \mathrm{KCN}\)
4 \(\mathrm{H}_{2} \mathrm{O}\)
CHXII13:AMINES

324235 In the reaction
supporting img
A is:

1 \(\mathrm{Cu}_{2} \mathrm{Cl}_{2}\)
2 \(\mathrm{H}_{3} \mathrm{PO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\)
3 \(\mathrm{H}^{+} / \mathrm{H}_{2} \mathrm{O}\)
4 \(\mathrm{HgSO}_{4} / \mathrm{H}_{2} \mathrm{SO}_{4}\)
CHXII13:AMINES

324236 \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Cl} \underset{\mathrm{Cu}_{2} \mathrm{O}, 200^{\circ} \mathrm{C}}{\stackrel{\mathrm{NH}_{3}}{\longrightarrow}} \mathrm{X}\)
\(X \underset{0-5^{0} \mathrm{C}}{\stackrel{\mathrm{HNO}_{2}}{\longrightarrow}} Z ; X+Z \rightarrow A\); the no.of
\(\sigma\) and \(\pi\) bonds in 'A' are

1 \(25 \sigma, 6 \pi\)
2 \(25 \sigma, 7 \pi\)
3 \(27 \sigma, 7 \pi\)
4 \(27 \sigma, 6 \pi\)
CHXII13:AMINES

324237 When benzenediazonium chloride is heated with fluoro boric acid, fluorobenzene is formed. This reaction is called

1 Hoffmann bromamide reaction
2 Balz schiemann reaction
3 Gattermann reaction
4 Sandmeyer reaction
CHXII13:AMINES

324238 The reagent ' \(R\) ' in the given sequence of chemical reaction is :
supporting img

1 \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
2 \(\mathrm{HI}\)
3 \(\mathrm{CuCN} / \mathrm{KCN}\)
4 \(\mathrm{H}_{2} \mathrm{O}\)