324058 Correct order of basic strength of Pyrrole

324060 Assertion :
${\mathrm{Me}}_3\mathrm{N}$ reacts with ${\mathrm{BF}}_3$ whereas ${\mathrm{Ph}}_3\mathrm{N}$ does not.
Reason :
The electron pair on nitrogen atom in $\text{N}{\text{H}}_{\text{3}}$ is delocalised in the benzene ring and is not available to boron in ${\mathrm{BF}}_3$.

324044 Assertion :
Basicity of ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$ (I), ${\mathrm{NH}}_3$ (II) and ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2$ (III) is in the order I $>$ II $>$ III.
Reason :
Electron-donating groups (such as alkyl group) increase the basicity of amines, and electron-withdrawing groups (such as aryl group) decrease the basicity of amines.

324058 Correct order of basic strength of Pyrrole

324059 Aniline is more basic than

324060 Assertion :
${\mathrm{Me}}_3\mathrm{N}$ reacts with ${\mathrm{BF}}_3$ whereas ${\mathrm{Ph}}_3\mathrm{N}$ does not.
Reason :
The electron pair on nitrogen atom in $\text{N}{\text{H}}_{\text{3}}$ is delocalised in the benzene ring and is not available to boron in ${\mathrm{BF}}_3$.

324044 Assertion :
Basicity of ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$ (I), ${\mathrm{NH}}_3$ (II) and ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2$ (III) is in the order I $>$ II $>$ III.
Reason :
Electron-donating groups (such as alkyl group) increase the basicity of amines, and electron-withdrawing groups (such as aryl group) decrease the basicity of amines.

324058 Correct order of basic strength of Pyrrole

324059 Aniline is more basic than

324060 Assertion :
${\mathrm{Me}}_3\mathrm{N}$ reacts with ${\mathrm{BF}}_3$ whereas ${\mathrm{Ph}}_3\mathrm{N}$ does not.
Reason :
The electron pair on nitrogen atom in $\text{N}{\text{H}}_{\text{3}}$ is delocalised in the benzene ring and is not available to boron in ${\mathrm{BF}}_3$.

324044 Assertion :
Basicity of ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$ (I), ${\mathrm{NH}}_3$ (II) and ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2$ (III) is in the order I $>$ II $>$ III.
Reason :
Electron-donating groups (such as alkyl group) increase the basicity of amines, and electron-withdrawing groups (such as aryl group) decrease the basicity of amines.

324058 Correct order of basic strength of Pyrrole

324059 Aniline is more basic than

324060 Assertion :
${\mathrm{Me}}_3\mathrm{N}$ reacts with ${\mathrm{BF}}_3$ whereas ${\mathrm{Ph}}_3\mathrm{N}$ does not.
Reason :
The electron pair on nitrogen atom in $\text{N}{\text{H}}_{\text{3}}$ is delocalised in the benzene ring and is not available to boron in ${\mathrm{BF}}_3$.

324044 Assertion :
Basicity of ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$ (I), ${\mathrm{NH}}_3$ (II) and ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NH}}_2$ (III) is in the order I $>$ II $>$ III.
Reason :
Electron-donating groups (such as alkyl group) increase the basicity of amines, and electron-withdrawing groups (such as aryl group) decrease the basicity of amines.