Amines
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CHXII13:AMINES

324336 Which of the following should be most volatile?
(I) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\)
(II) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\)
(III)
supporting img
(IV) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

1 II
2 IV
3 I
4 III
CHXII13:AMINES

324337 Arrange the following compound in increasing order of boiling point

1 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5}\)
4 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
CHXII13:AMINES

324338 The amine with least boiling point is

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{NHCH}_{3}\)
CHXII13:AMINES

324339 Identify the compound from the following having lowest boiling point.

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
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CHXII13:AMINES

324336 Which of the following should be most volatile?
(I) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\)
(II) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\)
(III)
supporting img
(IV) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

1 II
2 IV
3 I
4 III
CHXII13:AMINES

324337 Arrange the following compound in increasing order of boiling point

1 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5}\)
4 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
CHXII13:AMINES

324338 The amine with least boiling point is

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{NHCH}_{3}\)
CHXII13:AMINES

324339 Identify the compound from the following having lowest boiling point.

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
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CHXII13:AMINES

324336 Which of the following should be most volatile?
(I) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\)
(II) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\)
(III)
supporting img
(IV) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

1 II
2 IV
3 I
4 III
CHXII13:AMINES

324337 Arrange the following compound in increasing order of boiling point

1 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5}\)
4 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
CHXII13:AMINES

324338 The amine with least boiling point is

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{NHCH}_{3}\)
CHXII13:AMINES

324339 Identify the compound from the following having lowest boiling point.

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
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CHXII13:AMINES

324336 Which of the following should be most volatile?
(I) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\)
(II) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\)
(III)
supporting img
(IV) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

1 II
2 IV
3 I
4 III
CHXII13:AMINES

324337 Arrange the following compound in increasing order of boiling point

1 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) \( < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5}\)
4 \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N} < \mathrm{CH}_{3} \mathrm{NHC}_{2} \mathrm{H}_{5} < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{NH}_{2}\) \( < \mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\)
CHXII13:AMINES

324338 The amine with least boiling point is

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}_{2} \mathrm{NHCH}_{3}\)
CHXII13:AMINES

324339 Identify the compound from the following having lowest boiling point.

1 \(\mathrm{n}-\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
3 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{~N}\left(\mathrm{CH}_{3}\right)_{2}\)
4 \(\left(\mathrm{C}_{2} \mathrm{H}_{5}\right)_{2} \mathrm{NH}\)
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