Physical Properties of Carboxylic Acids
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323956 Benzoic acid has higher molecular weight in benzene and less in water because

1 water has lower freezing point and higher boiling point than benzene
2 it dissociates to a greater extent in benzene than in water.
3 it associates in water and dissociates in benzene
4 it dissociates in water and associates in benzene.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323957 Assertion :
Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of comparable molecular masses.
Reason :
More extensive association of carboxylic acid molecules through intermolecular hydrogen bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323958 Assertion :
Carboxylic acids have higher boiling points than alkanes.
Reason :
Carboxylic acids are resonance hybrids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323959 Which among the following compounds has highest boiling point?

1 \(\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{COOH}\)
3 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323956 Benzoic acid has higher molecular weight in benzene and less in water because

1 water has lower freezing point and higher boiling point than benzene
2 it dissociates to a greater extent in benzene than in water.
3 it associates in water and dissociates in benzene
4 it dissociates in water and associates in benzene.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323957 Assertion :
Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of comparable molecular masses.
Reason :
More extensive association of carboxylic acid molecules through intermolecular hydrogen bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323958 Assertion :
Carboxylic acids have higher boiling points than alkanes.
Reason :
Carboxylic acids are resonance hybrids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323959 Which among the following compounds has highest boiling point?

1 \(\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{COOH}\)
3 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323956 Benzoic acid has higher molecular weight in benzene and less in water because

1 water has lower freezing point and higher boiling point than benzene
2 it dissociates to a greater extent in benzene than in water.
3 it associates in water and dissociates in benzene
4 it dissociates in water and associates in benzene.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323957 Assertion :
Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of comparable molecular masses.
Reason :
More extensive association of carboxylic acid molecules through intermolecular hydrogen bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323958 Assertion :
Carboxylic acids have higher boiling points than alkanes.
Reason :
Carboxylic acids are resonance hybrids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323959 Which among the following compounds has highest boiling point?

1 \(\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{COOH}\)
3 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323956 Benzoic acid has higher molecular weight in benzene and less in water because

1 water has lower freezing point and higher boiling point than benzene
2 it dissociates to a greater extent in benzene than in water.
3 it associates in water and dissociates in benzene
4 it dissociates in water and associates in benzene.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323957 Assertion :
Carboxylic acids are higher boiling liquids than aldehydes, ketones and even alcohols of comparable molecular masses.
Reason :
More extensive association of carboxylic acid molecules through intermolecular hydrogen bonding.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323958 Assertion :
Carboxylic acids have higher boiling points than alkanes.
Reason :
Carboxylic acids are resonance hybrids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323959 Which among the following compounds has highest boiling point?

1 \(\mathrm{C}_{4} \mathrm{H}_{9} \mathrm{NH}_{2}\)
2 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{COOH}\)
3 \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)