(reductive ozonolysis) It is Friedel-Crafts acylation reaction. Secondary alcohols are oxidised to ketones by \({\mathrm{\mathrm{CrO}_{3}}}\) Irrespective of length of side chain, alkyl benzenes with one benzylic hydrogen are oxidised to benzoic acids.
NEET - 2024
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323907
Statement A : Compounds containing - \(\mathrm{CHO}\) group are easily oxidised to corresponding carboxylic acids. Statement B : Carboxylic acids can be reduced to alcohols by treatment with \(\mathrm{LiAlH}_{4}\).
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
Explanation:
Conceptual Questions
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323908
The product of acid hydrolysis of \((P)\) and \((Q)\) can be distinguished by
1 Lucas reagent
2 2,4-DNP
3 Fehling's solution
4 \({\rm{NaHS}}{{\rm{O}}_{\rm{3}}}\)
Explanation:
The product of (P) and (Q) are \(\because\) Fehling solution cannot be reduced with acetone.Thus it can be used to differentiate ketone (acetone) and aldehyde.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323909 (a) and (b) are number of moles of \({\rm{NaB}}{{\rm{H}}_{\rm{4}}}\) and LAH \(\therefore \) a + b=
(reductive ozonolysis) It is Friedel-Crafts acylation reaction. Secondary alcohols are oxidised to ketones by \({\mathrm{\mathrm{CrO}_{3}}}\) Irrespective of length of side chain, alkyl benzenes with one benzylic hydrogen are oxidised to benzoic acids.
NEET - 2024
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323907
Statement A : Compounds containing - \(\mathrm{CHO}\) group are easily oxidised to corresponding carboxylic acids. Statement B : Carboxylic acids can be reduced to alcohols by treatment with \(\mathrm{LiAlH}_{4}\).
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
Explanation:
Conceptual Questions
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323908
The product of acid hydrolysis of \((P)\) and \((Q)\) can be distinguished by
1 Lucas reagent
2 2,4-DNP
3 Fehling's solution
4 \({\rm{NaHS}}{{\rm{O}}_{\rm{3}}}\)
Explanation:
The product of (P) and (Q) are \(\because\) Fehling solution cannot be reduced with acetone.Thus it can be used to differentiate ketone (acetone) and aldehyde.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323909 (a) and (b) are number of moles of \({\rm{NaB}}{{\rm{H}}_{\rm{4}}}\) and LAH \(\therefore \) a + b=
(reductive ozonolysis) It is Friedel-Crafts acylation reaction. Secondary alcohols are oxidised to ketones by \({\mathrm{\mathrm{CrO}_{3}}}\) Irrespective of length of side chain, alkyl benzenes with one benzylic hydrogen are oxidised to benzoic acids.
NEET - 2024
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323907
Statement A : Compounds containing - \(\mathrm{CHO}\) group are easily oxidised to corresponding carboxylic acids. Statement B : Carboxylic acids can be reduced to alcohols by treatment with \(\mathrm{LiAlH}_{4}\).
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
Explanation:
Conceptual Questions
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323908
The product of acid hydrolysis of \((P)\) and \((Q)\) can be distinguished by
1 Lucas reagent
2 2,4-DNP
3 Fehling's solution
4 \({\rm{NaHS}}{{\rm{O}}_{\rm{3}}}\)
Explanation:
The product of (P) and (Q) are \(\because\) Fehling solution cannot be reduced with acetone.Thus it can be used to differentiate ketone (acetone) and aldehyde.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323909 (a) and (b) are number of moles of \({\rm{NaB}}{{\rm{H}}_{\rm{4}}}\) and LAH \(\therefore \) a + b=
(reductive ozonolysis) It is Friedel-Crafts acylation reaction. Secondary alcohols are oxidised to ketones by \({\mathrm{\mathrm{CrO}_{3}}}\) Irrespective of length of side chain, alkyl benzenes with one benzylic hydrogen are oxidised to benzoic acids.
NEET - 2024
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323907
Statement A : Compounds containing - \(\mathrm{CHO}\) group are easily oxidised to corresponding carboxylic acids. Statement B : Carboxylic acids can be reduced to alcohols by treatment with \(\mathrm{LiAlH}_{4}\).
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
Explanation:
Conceptual Questions
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323908
The product of acid hydrolysis of \((P)\) and \((Q)\) can be distinguished by
1 Lucas reagent
2 2,4-DNP
3 Fehling's solution
4 \({\rm{NaHS}}{{\rm{O}}_{\rm{3}}}\)
Explanation:
The product of (P) and (Q) are \(\because\) Fehling solution cannot be reduced with acetone.Thus it can be used to differentiate ketone (acetone) and aldehyde.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323909 (a) and (b) are number of moles of \({\rm{NaB}}{{\rm{H}}_{\rm{4}}}\) and LAH \(\therefore \) a + b=