323883
Identify the total number of compounds from the following which will yield monocarboxylic acid on oxidation with \({\mathrm{\mathrm{KMnO}_{4}}}\) in acidic medium.
1 6
2 4
3 3
4 2
Explanation:
In case of aromatic compounds, the complete side chain (consisting of an alkyl group) is oxidised to \( - {\text{COOH}}\) group irrespective of the length of the chain except in case of tert-butylbenzene. In case of cyclohexene, it gives dicarboxylic acid. \(\therefore \) Compounds (i), (ii), and (v) will yield monocarboxylic acids on oxidation with \({\text{KMn}}{{\text{O}}_{\text{4}}}\) in acidic medium.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323884
\(\mathrm{CH}_{3} \mathrm{Cl} \stackrel{\mathrm{KCN}}{\longrightarrow} \mathrm{A} ; \mathrm{A} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{B}\) (Final product) In this reaction ' \(\mathrm{B}\) ' is
323885
In the reaction of Ethanol \(\xrightarrow{\mathrm{PI}_{3}} \mathrm{~A} \xrightarrow{\mathrm{KCN}} \mathrm{B} \xrightarrow{\mathrm{H}_{3} \mathrm{O}^{+}} \mathrm{C}\); Cis:
1 Acetamide
2 Propionamide
3 Propanoic acid
4 Acetic acid
Explanation:
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323886
\(\mathrm{RMgX}+\mathrm{CO}_{2} \underset{\text { ether }}{\longrightarrow} \mathrm{Y} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{RCOOH}\) What is \(\mathrm{Y}\) in the above reaction :
323883
Identify the total number of compounds from the following which will yield monocarboxylic acid on oxidation with \({\mathrm{\mathrm{KMnO}_{4}}}\) in acidic medium.
1 6
2 4
3 3
4 2
Explanation:
In case of aromatic compounds, the complete side chain (consisting of an alkyl group) is oxidised to \( - {\text{COOH}}\) group irrespective of the length of the chain except in case of tert-butylbenzene. In case of cyclohexene, it gives dicarboxylic acid. \(\therefore \) Compounds (i), (ii), and (v) will yield monocarboxylic acids on oxidation with \({\text{KMn}}{{\text{O}}_{\text{4}}}\) in acidic medium.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323884
\(\mathrm{CH}_{3} \mathrm{Cl} \stackrel{\mathrm{KCN}}{\longrightarrow} \mathrm{A} ; \mathrm{A} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{B}\) (Final product) In this reaction ' \(\mathrm{B}\) ' is
323885
In the reaction of Ethanol \(\xrightarrow{\mathrm{PI}_{3}} \mathrm{~A} \xrightarrow{\mathrm{KCN}} \mathrm{B} \xrightarrow{\mathrm{H}_{3} \mathrm{O}^{+}} \mathrm{C}\); Cis:
1 Acetamide
2 Propionamide
3 Propanoic acid
4 Acetic acid
Explanation:
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323886
\(\mathrm{RMgX}+\mathrm{CO}_{2} \underset{\text { ether }}{\longrightarrow} \mathrm{Y} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{RCOOH}\) What is \(\mathrm{Y}\) in the above reaction :
323883
Identify the total number of compounds from the following which will yield monocarboxylic acid on oxidation with \({\mathrm{\mathrm{KMnO}_{4}}}\) in acidic medium.
1 6
2 4
3 3
4 2
Explanation:
In case of aromatic compounds, the complete side chain (consisting of an alkyl group) is oxidised to \( - {\text{COOH}}\) group irrespective of the length of the chain except in case of tert-butylbenzene. In case of cyclohexene, it gives dicarboxylic acid. \(\therefore \) Compounds (i), (ii), and (v) will yield monocarboxylic acids on oxidation with \({\text{KMn}}{{\text{O}}_{\text{4}}}\) in acidic medium.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323884
\(\mathrm{CH}_{3} \mathrm{Cl} \stackrel{\mathrm{KCN}}{\longrightarrow} \mathrm{A} ; \mathrm{A} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{B}\) (Final product) In this reaction ' \(\mathrm{B}\) ' is
323885
In the reaction of Ethanol \(\xrightarrow{\mathrm{PI}_{3}} \mathrm{~A} \xrightarrow{\mathrm{KCN}} \mathrm{B} \xrightarrow{\mathrm{H}_{3} \mathrm{O}^{+}} \mathrm{C}\); Cis:
1 Acetamide
2 Propionamide
3 Propanoic acid
4 Acetic acid
Explanation:
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323886
\(\mathrm{RMgX}+\mathrm{CO}_{2} \underset{\text { ether }}{\longrightarrow} \mathrm{Y} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{RCOOH}\) What is \(\mathrm{Y}\) in the above reaction :
323883
Identify the total number of compounds from the following which will yield monocarboxylic acid on oxidation with \({\mathrm{\mathrm{KMnO}_{4}}}\) in acidic medium.
1 6
2 4
3 3
4 2
Explanation:
In case of aromatic compounds, the complete side chain (consisting of an alkyl group) is oxidised to \( - {\text{COOH}}\) group irrespective of the length of the chain except in case of tert-butylbenzene. In case of cyclohexene, it gives dicarboxylic acid. \(\therefore \) Compounds (i), (ii), and (v) will yield monocarboxylic acids on oxidation with \({\text{KMn}}{{\text{O}}_{\text{4}}}\) in acidic medium.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323884
\(\mathrm{CH}_{3} \mathrm{Cl} \stackrel{\mathrm{KCN}}{\longrightarrow} \mathrm{A} ; \mathrm{A} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{B}\) (Final product) In this reaction ' \(\mathrm{B}\) ' is
323885
In the reaction of Ethanol \(\xrightarrow{\mathrm{PI}_{3}} \mathrm{~A} \xrightarrow{\mathrm{KCN}} \mathrm{B} \xrightarrow{\mathrm{H}_{3} \mathrm{O}^{+}} \mathrm{C}\); Cis:
1 Acetamide
2 Propionamide
3 Propanoic acid
4 Acetic acid
Explanation:
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323886
\(\mathrm{RMgX}+\mathrm{CO}_{2} \underset{\text { ether }}{\longrightarrow} \mathrm{Y} \stackrel{\mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{RCOOH}\) What is \(\mathrm{Y}\) in the above reaction :