323760
Assertion : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not give \(\mathrm{HVZ}\) reaction. Reason : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not have \(\alpha\) hydrogen atom.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The HVZ reaction is a method used to introduce a bromine atom at the \(\alpha\)-carbon position (the carbon adjacent to the carboxyl group) of carboxylic acids. But \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) cannot undergo this reaction because the \(\alpha\)-carbon in this compound does not contain a hydrogen atom. So the option (1) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323761
The carboxylic acid which does not undergo HellVolhard Zelinsky reaction is
\(\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\alpha}{\mathrm{C}} \mathrm{COOH}\) does not have \({\rm{\alpha - H}}\) atom/s and hence does not undergo HVZ reaction.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323762
Assertion : \(\mathrm{CH}_{3} \mathrm{COOH}\) but not \(\mathrm{HCOOH}\) can be halogenated in presence of red \(\mathrm{P}\) and \(\mathrm{Cl}_{2}\). Reason : Both formic acid and \(\mathrm{CH}_{3} \mathrm{COOH}\) are highly soluble in water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
It is HVZ reaction, in which carboxylic acids are halogenated using red \(\mathrm{P}\) and halogen, to replace \(\alpha\) - hydrogen. Formic acid lacks an \(\alpha\) - carbon and cannot be halogenated this way. Aliphatic carboxylic acids up to four carbon atoms are water miscible due to hydrogen bonding with water. \({\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}\xrightarrow[{{\text{ (ii) }}{{\text{H}}_{\text{2}}}{\text{O}}}]{{{\text{ (i) C}}{{\text{l}}_{\text{2}}}{\text{/}}\,\,{\text{Red}}\,\,{\text{P}}}}{\text{ClC}}{{\text{H}}_{\text{2}}}{\text{COOH}}\) So the option (2) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323763
The end product \({\rm{(Z)}}\) in the following reaction sequence is
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CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323760
Assertion : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not give \(\mathrm{HVZ}\) reaction. Reason : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not have \(\alpha\) hydrogen atom.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The HVZ reaction is a method used to introduce a bromine atom at the \(\alpha\)-carbon position (the carbon adjacent to the carboxyl group) of carboxylic acids. But \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) cannot undergo this reaction because the \(\alpha\)-carbon in this compound does not contain a hydrogen atom. So the option (1) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323761
The carboxylic acid which does not undergo HellVolhard Zelinsky reaction is
\(\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\alpha}{\mathrm{C}} \mathrm{COOH}\) does not have \({\rm{\alpha - H}}\) atom/s and hence does not undergo HVZ reaction.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323762
Assertion : \(\mathrm{CH}_{3} \mathrm{COOH}\) but not \(\mathrm{HCOOH}\) can be halogenated in presence of red \(\mathrm{P}\) and \(\mathrm{Cl}_{2}\). Reason : Both formic acid and \(\mathrm{CH}_{3} \mathrm{COOH}\) are highly soluble in water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
It is HVZ reaction, in which carboxylic acids are halogenated using red \(\mathrm{P}\) and halogen, to replace \(\alpha\) - hydrogen. Formic acid lacks an \(\alpha\) - carbon and cannot be halogenated this way. Aliphatic carboxylic acids up to four carbon atoms are water miscible due to hydrogen bonding with water. \({\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}\xrightarrow[{{\text{ (ii) }}{{\text{H}}_{\text{2}}}{\text{O}}}]{{{\text{ (i) C}}{{\text{l}}_{\text{2}}}{\text{/}}\,\,{\text{Red}}\,\,{\text{P}}}}{\text{ClC}}{{\text{H}}_{\text{2}}}{\text{COOH}}\) So the option (2) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323763
The end product \({\rm{(Z)}}\) in the following reaction sequence is
323760
Assertion : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not give \(\mathrm{HVZ}\) reaction. Reason : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not have \(\alpha\) hydrogen atom.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The HVZ reaction is a method used to introduce a bromine atom at the \(\alpha\)-carbon position (the carbon adjacent to the carboxyl group) of carboxylic acids. But \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) cannot undergo this reaction because the \(\alpha\)-carbon in this compound does not contain a hydrogen atom. So the option (1) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323761
The carboxylic acid which does not undergo HellVolhard Zelinsky reaction is
\(\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\alpha}{\mathrm{C}} \mathrm{COOH}\) does not have \({\rm{\alpha - H}}\) atom/s and hence does not undergo HVZ reaction.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323762
Assertion : \(\mathrm{CH}_{3} \mathrm{COOH}\) but not \(\mathrm{HCOOH}\) can be halogenated in presence of red \(\mathrm{P}\) and \(\mathrm{Cl}_{2}\). Reason : Both formic acid and \(\mathrm{CH}_{3} \mathrm{COOH}\) are highly soluble in water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
It is HVZ reaction, in which carboxylic acids are halogenated using red \(\mathrm{P}\) and halogen, to replace \(\alpha\) - hydrogen. Formic acid lacks an \(\alpha\) - carbon and cannot be halogenated this way. Aliphatic carboxylic acids up to four carbon atoms are water miscible due to hydrogen bonding with water. \({\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}\xrightarrow[{{\text{ (ii) }}{{\text{H}}_{\text{2}}}{\text{O}}}]{{{\text{ (i) C}}{{\text{l}}_{\text{2}}}{\text{/}}\,\,{\text{Red}}\,\,{\text{P}}}}{\text{ClC}}{{\text{H}}_{\text{2}}}{\text{COOH}}\) So the option (2) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323763
The end product \({\rm{(Z)}}\) in the following reaction sequence is
323760
Assertion : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not give \(\mathrm{HVZ}\) reaction. Reason : \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) does not have \(\alpha\) hydrogen atom.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The HVZ reaction is a method used to introduce a bromine atom at the \(\alpha\)-carbon position (the carbon adjacent to the carboxyl group) of carboxylic acids. But \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCOOH}\) cannot undergo this reaction because the \(\alpha\)-carbon in this compound does not contain a hydrogen atom. So the option (1) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323761
The carboxylic acid which does not undergo HellVolhard Zelinsky reaction is
\(\left(\mathrm{CH}_{3}\right)_{3} \stackrel{\alpha}{\mathrm{C}} \mathrm{COOH}\) does not have \({\rm{\alpha - H}}\) atom/s and hence does not undergo HVZ reaction.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323762
Assertion : \(\mathrm{CH}_{3} \mathrm{COOH}\) but not \(\mathrm{HCOOH}\) can be halogenated in presence of red \(\mathrm{P}\) and \(\mathrm{Cl}_{2}\). Reason : Both formic acid and \(\mathrm{CH}_{3} \mathrm{COOH}\) are highly soluble in water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
It is HVZ reaction, in which carboxylic acids are halogenated using red \(\mathrm{P}\) and halogen, to replace \(\alpha\) - hydrogen. Formic acid lacks an \(\alpha\) - carbon and cannot be halogenated this way. Aliphatic carboxylic acids up to four carbon atoms are water miscible due to hydrogen bonding with water. \({\text{C}}{{\text{H}}_{\text{3}}}{\text{COOH}}\xrightarrow[{{\text{ (ii) }}{{\text{H}}_{\text{2}}}{\text{O}}}]{{{\text{ (i) C}}{{\text{l}}_{\text{2}}}{\text{/}}\,\,{\text{Red}}\,\,{\text{P}}}}{\text{ClC}}{{\text{H}}_{\text{2}}}{\text{COOH}}\) So the option (2) is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS
323763
The end product \({\rm{(Z)}}\) in the following reaction sequence is
