Chemical Reactions of Aldehydes and Ketones
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323650 Rearrangement of an oxime to an amide in presence of strong acid is called

1 Curtius rearrangement
2 Fries rearrangement
3 Beckmann rearrangement
4 Sandmeyer reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323651 Ketones can be oxidised to esters by

1 Alkaline \(\mathrm{KMnO}_{4}\)
2 Baeyer Villiger oxidation
3 Iodoform reaction
4 PCC
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323652 Assertion :
Esters which contain \(\alpha\)-hydrogens undergo Claisen condensation.
Reason :
\(\mathrm{LiAlH}_{4}\) reduction of esters gives acids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323653 In the reaction,
supporting img
The major product formed is

1 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CHO}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{COOH}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COOH}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COCH}_{3}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323650 Rearrangement of an oxime to an amide in presence of strong acid is called

1 Curtius rearrangement
2 Fries rearrangement
3 Beckmann rearrangement
4 Sandmeyer reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323651 Ketones can be oxidised to esters by

1 Alkaline \(\mathrm{KMnO}_{4}\)
2 Baeyer Villiger oxidation
3 Iodoform reaction
4 PCC
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323652 Assertion :
Esters which contain \(\alpha\)-hydrogens undergo Claisen condensation.
Reason :
\(\mathrm{LiAlH}_{4}\) reduction of esters gives acids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323653 In the reaction,
supporting img
The major product formed is

1 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CHO}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{COOH}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COOH}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COCH}_{3}\)
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CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323650 Rearrangement of an oxime to an amide in presence of strong acid is called

1 Curtius rearrangement
2 Fries rearrangement
3 Beckmann rearrangement
4 Sandmeyer reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323651 Ketones can be oxidised to esters by

1 Alkaline \(\mathrm{KMnO}_{4}\)
2 Baeyer Villiger oxidation
3 Iodoform reaction
4 PCC
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323652 Assertion :
Esters which contain \(\alpha\)-hydrogens undergo Claisen condensation.
Reason :
\(\mathrm{LiAlH}_{4}\) reduction of esters gives acids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323653 In the reaction,
supporting img
The major product formed is

1 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CHO}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{COOH}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COOH}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COCH}_{3}\)
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323650 Rearrangement of an oxime to an amide in presence of strong acid is called

1 Curtius rearrangement
2 Fries rearrangement
3 Beckmann rearrangement
4 Sandmeyer reaction
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323651 Ketones can be oxidised to esters by

1 Alkaline \(\mathrm{KMnO}_{4}\)
2 Baeyer Villiger oxidation
3 Iodoform reaction
4 PCC
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323652 Assertion :
Esters which contain \(\alpha\)-hydrogens undergo Claisen condensation.
Reason :
\(\mathrm{LiAlH}_{4}\) reduction of esters gives acids.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII12:ALDEHYDES KETONES AND CARBOXYLIC ACIDS

323653 In the reaction,
supporting img
The major product formed is

1 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}_{2}-\mathrm{CHO}\)
2 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{COOH}\)
3 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COOH}\)
4 \(\mathrm{C}_{6} \mathrm{H}_{5}-\mathrm{CH}=\mathrm{CH}-\mathrm{COCH}_{3}\)