Reactions of Ethers
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323244 In the reaction, the products formed are
\({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{.C}}{{\text{H}}_{\text{2}}}{\text{.}}{{\text{O}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{ + HI}}\xrightarrow{{{\text{ Heated }}}}\)

1 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} . \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I}\)
2 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{I}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{3}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{6}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323245 Identify the correct satement about the given reactions
supporting img

1 Path-1 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism and path -2 follows \(\mathrm{S}_{\mathrm{N}}^{2}\) mechanism
2 Path-1 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism and path -2 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism
3 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{1}\) mechanism
4 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323246 \({\text{(A)}}\xrightarrow[{150^\circ {\text{C}}{\text{.500 atm}}}]{{{\text{C}}{{\text{O}}_{\text{2}}}{\text{B}}{{\text{F}}_{\text{3}}}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{COO}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\) The compound (A) is

1 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\)
2 \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\)
3 \(\mathrm{CH}_{2} \mathrm{OC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5}-\mathrm{O}-\mathrm{C}_{2} \mathrm{H}_{5}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323247 In the reaction
\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{O}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{ + CO}}\xrightarrow[{{\text{150}}^\circ {\text{C}}}]{{{\text{B}}{{\text{F}}_{\text{3}}}{\text{,500 atm}}}}{\text{X}}\), What is \(\mathrm{X}\) ?

1 Diethyl carbonate
2 Ethyl carbonate
3 Diethyl peroxide
4 Ethyl propionate
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323244 In the reaction, the products formed are
\({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{.C}}{{\text{H}}_{\text{2}}}{\text{.}}{{\text{O}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{ + HI}}\xrightarrow{{{\text{ Heated }}}}\)

1 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} . \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I}\)
2 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{I}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{3}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{6}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323245 Identify the correct satement about the given reactions
supporting img

1 Path-1 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism and path -2 follows \(\mathrm{S}_{\mathrm{N}}^{2}\) mechanism
2 Path-1 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism and path -2 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism
3 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{1}\) mechanism
4 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323246 \({\text{(A)}}\xrightarrow[{150^\circ {\text{C}}{\text{.500 atm}}}]{{{\text{C}}{{\text{O}}_{\text{2}}}{\text{B}}{{\text{F}}_{\text{3}}}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{COO}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\) The compound (A) is

1 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\)
2 \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\)
3 \(\mathrm{CH}_{2} \mathrm{OC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5}-\mathrm{O}-\mathrm{C}_{2} \mathrm{H}_{5}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323247 In the reaction
\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{O}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{ + CO}}\xrightarrow[{{\text{150}}^\circ {\text{C}}}]{{{\text{B}}{{\text{F}}_{\text{3}}}{\text{,500 atm}}}}{\text{X}}\), What is \(\mathrm{X}\) ?

1 Diethyl carbonate
2 Ethyl carbonate
3 Diethyl peroxide
4 Ethyl propionate
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323244 In the reaction, the products formed are
\({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{.C}}{{\text{H}}_{\text{2}}}{\text{.}}{{\text{O}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{ + HI}}\xrightarrow{{{\text{ Heated }}}}\)

1 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} . \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I}\)
2 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{I}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{3}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{6}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323245 Identify the correct satement about the given reactions
supporting img

1 Path-1 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism and path -2 follows \(\mathrm{S}_{\mathrm{N}}^{2}\) mechanism
2 Path-1 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism and path -2 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism
3 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{1}\) mechanism
4 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323246 \({\text{(A)}}\xrightarrow[{150^\circ {\text{C}}{\text{.500 atm}}}]{{{\text{C}}{{\text{O}}_{\text{2}}}{\text{B}}{{\text{F}}_{\text{3}}}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{COO}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\) The compound (A) is

1 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\)
2 \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\)
3 \(\mathrm{CH}_{2} \mathrm{OC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5}-\mathrm{O}-\mathrm{C}_{2} \mathrm{H}_{5}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323247 In the reaction
\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{O}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{ + CO}}\xrightarrow[{{\text{150}}^\circ {\text{C}}}]{{{\text{B}}{{\text{F}}_{\text{3}}}{\text{,500 atm}}}}{\text{X}}\), What is \(\mathrm{X}\) ?

1 Diethyl carbonate
2 Ethyl carbonate
3 Diethyl peroxide
4 Ethyl propionate
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323244 In the reaction, the products formed are
\({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{.C}}{{\text{H}}_{\text{2}}}{\text{.}}{{\text{O}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{ + HI}}\xrightarrow{{{\text{ Heated }}}}\)

1 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} . \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I}\)
2 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{I}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
3 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHCH}_{3}+\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\)
4 \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH} \cdot \mathrm{CH}_{2} \mathrm{OH}+\mathrm{C}_{2} \mathrm{H}_{6}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323245 Identify the correct satement about the given reactions
supporting img

1 Path-1 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism and path -2 follows \(\mathrm{S}_{\mathrm{N}}^{2}\) mechanism
2 Path-1 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism and path -2 follows \({{\text{S}}_{\text{N}}}^{\text{1}}\) mechanism
3 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{1}\) mechanism
4 Both path-1 & 2 follows \(\mathrm{S}_{\mathrm{N}}{ }^{2}\) mechanism
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323246 \({\text{(A)}}\xrightarrow[{150^\circ {\text{C}}{\text{.500 atm}}}]{{{\text{C}}{{\text{O}}_{\text{2}}}{\text{B}}{{\text{F}}_{\text{3}}}}}{\text{C}}{{\text{H}}_{\text{3}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{COO}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\) The compound (A) is

1 \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\)
2 \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\)
3 \(\mathrm{CH}_{2} \mathrm{OC}_{2} \mathrm{H}_{5}\)
4 \(\mathrm{C}_{2} \mathrm{H}_{5}-\mathrm{O}-\mathrm{C}_{2} \mathrm{H}_{5}\)
CHXII11:ALCOHOLS, PHENOLS AND ETHERS

323247 In the reaction
\({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{O}}{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{ + CO}}\xrightarrow[{{\text{150}}^\circ {\text{C}}}]{{{\text{B}}{{\text{F}}_{\text{3}}}{\text{,500 atm}}}}{\text{X}}\), What is \(\mathrm{X}\) ?

1 Diethyl carbonate
2 Ethyl carbonate
3 Diethyl peroxide
4 Ethyl propionate