323192
If (dl) or ( \({\mathrm{\pm}}\) ) 2-methyl butanoic acid were esterified by reaction with (dl) or \({\mathrm{( \pm)}}\) 2-butanol, how many optically active compounds would be present in the final equilibrium reaction mixture?
1 1
2 2
3 3
4 4
Explanation:
Ester consists of two stereoisomers.Chiral centre during whole reaction are not effected,that's why all esters are optical active.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323193
Assertion : tert-Butoxide is a stronger base than \(\mathrm{OH}^{-}\)or \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}\)but is a much poorer nucleophile. Reason : A negatively charged ion is always a more powerful nucleophile than its conjugate acid.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Steric hindrance in the tert-butoxide ion, owing to its larger size compared to smaller alkoxide ions, significantly impedes the attack on a carbon atom in nucleophilic substitution reactions. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323194
Assertion : Acidic character of alcohols follows the order primary \(>\) secondary \(>\) tertiary. Reason : Acidic character of alcohols is due to the presence of polar \(-\mathrm{O}-\mathrm{H}\) group.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The acidity of alcohols depends on the \(+\mathrm{I}\) effect of alkyl groups, making tertiary alcohols less acidic due to stronger electron-releasing effects than primary alcohols. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323195
Assertion : Addition of \(\mathrm{CH}_{3} \mathrm{OH}\) to phenyl magnesium bromide gives benzene. Reason : \(\mathrm{CH}_{3} \mathrm{OH}\) is a stronger acid than benzene.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Methanol acts an acid and donates its proton to phenyl magnesium bromide which acts as a base and accepts the proton, to produce benzene. Methanol is a stronger acid than benzene as benzene is resonance stabilized. So the option (1) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323196
\(0.336\;{\rm{g}}\,\,{\rm{KOH}}\) hydrolyses with \(0.436 \mathrm{~g}\) of acetyl derivative of polyhydric alcohol. (molecular mass \(=92\) ). Then the number of hydroxyl groups in the alcohol are ____.
1 5
2 2
3 3
4 4
Explanation:
We know that, \(\frac{{\rm{w}}}{{\rm{W}}}({\rm{M}} + 42\,{\rm{n}}) = 56\,{\rm{n}}\) Where \(\mathrm{w}\) is the amount of alkali, \(\mathrm{W}\) is amount of acetyl derivative, M is the molecular mass of alcohol and n is the number of hydroxyl groups. \(\frac{{0.336}}{{0.436}}(92 + 42\,{\rm{n}}) = 56\,{\rm{n}}\) \(92 + 42{\rm{n}} = \frac{{0.436}}{{0.336}} \times 56{\rm{n}} = \frac{{218}}{3}{\rm{n}}\) or \(276+126 \mathrm{n}=218 \mathrm{n}\) or \(\mathrm{n}=3\) (the alcohol is trihydric.)
323192
If (dl) or ( \({\mathrm{\pm}}\) ) 2-methyl butanoic acid were esterified by reaction with (dl) or \({\mathrm{( \pm)}}\) 2-butanol, how many optically active compounds would be present in the final equilibrium reaction mixture?
1 1
2 2
3 3
4 4
Explanation:
Ester consists of two stereoisomers.Chiral centre during whole reaction are not effected,that's why all esters are optical active.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323193
Assertion : tert-Butoxide is a stronger base than \(\mathrm{OH}^{-}\)or \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}\)but is a much poorer nucleophile. Reason : A negatively charged ion is always a more powerful nucleophile than its conjugate acid.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Steric hindrance in the tert-butoxide ion, owing to its larger size compared to smaller alkoxide ions, significantly impedes the attack on a carbon atom in nucleophilic substitution reactions. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323194
Assertion : Acidic character of alcohols follows the order primary \(>\) secondary \(>\) tertiary. Reason : Acidic character of alcohols is due to the presence of polar \(-\mathrm{O}-\mathrm{H}\) group.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The acidity of alcohols depends on the \(+\mathrm{I}\) effect of alkyl groups, making tertiary alcohols less acidic due to stronger electron-releasing effects than primary alcohols. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323195
Assertion : Addition of \(\mathrm{CH}_{3} \mathrm{OH}\) to phenyl magnesium bromide gives benzene. Reason : \(\mathrm{CH}_{3} \mathrm{OH}\) is a stronger acid than benzene.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Methanol acts an acid and donates its proton to phenyl magnesium bromide which acts as a base and accepts the proton, to produce benzene. Methanol is a stronger acid than benzene as benzene is resonance stabilized. So the option (1) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323196
\(0.336\;{\rm{g}}\,\,{\rm{KOH}}\) hydrolyses with \(0.436 \mathrm{~g}\) of acetyl derivative of polyhydric alcohol. (molecular mass \(=92\) ). Then the number of hydroxyl groups in the alcohol are ____.
1 5
2 2
3 3
4 4
Explanation:
We know that, \(\frac{{\rm{w}}}{{\rm{W}}}({\rm{M}} + 42\,{\rm{n}}) = 56\,{\rm{n}}\) Where \(\mathrm{w}\) is the amount of alkali, \(\mathrm{W}\) is amount of acetyl derivative, M is the molecular mass of alcohol and n is the number of hydroxyl groups. \(\frac{{0.336}}{{0.436}}(92 + 42\,{\rm{n}}) = 56\,{\rm{n}}\) \(92 + 42{\rm{n}} = \frac{{0.436}}{{0.336}} \times 56{\rm{n}} = \frac{{218}}{3}{\rm{n}}\) or \(276+126 \mathrm{n}=218 \mathrm{n}\) or \(\mathrm{n}=3\) (the alcohol is trihydric.)
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CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323192
If (dl) or ( \({\mathrm{\pm}}\) ) 2-methyl butanoic acid were esterified by reaction with (dl) or \({\mathrm{( \pm)}}\) 2-butanol, how many optically active compounds would be present in the final equilibrium reaction mixture?
1 1
2 2
3 3
4 4
Explanation:
Ester consists of two stereoisomers.Chiral centre during whole reaction are not effected,that's why all esters are optical active.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323193
Assertion : tert-Butoxide is a stronger base than \(\mathrm{OH}^{-}\)or \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}\)but is a much poorer nucleophile. Reason : A negatively charged ion is always a more powerful nucleophile than its conjugate acid.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Steric hindrance in the tert-butoxide ion, owing to its larger size compared to smaller alkoxide ions, significantly impedes the attack on a carbon atom in nucleophilic substitution reactions. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323194
Assertion : Acidic character of alcohols follows the order primary \(>\) secondary \(>\) tertiary. Reason : Acidic character of alcohols is due to the presence of polar \(-\mathrm{O}-\mathrm{H}\) group.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The acidity of alcohols depends on the \(+\mathrm{I}\) effect of alkyl groups, making tertiary alcohols less acidic due to stronger electron-releasing effects than primary alcohols. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323195
Assertion : Addition of \(\mathrm{CH}_{3} \mathrm{OH}\) to phenyl magnesium bromide gives benzene. Reason : \(\mathrm{CH}_{3} \mathrm{OH}\) is a stronger acid than benzene.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Methanol acts an acid and donates its proton to phenyl magnesium bromide which acts as a base and accepts the proton, to produce benzene. Methanol is a stronger acid than benzene as benzene is resonance stabilized. So the option (1) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323196
\(0.336\;{\rm{g}}\,\,{\rm{KOH}}\) hydrolyses with \(0.436 \mathrm{~g}\) of acetyl derivative of polyhydric alcohol. (molecular mass \(=92\) ). Then the number of hydroxyl groups in the alcohol are ____.
1 5
2 2
3 3
4 4
Explanation:
We know that, \(\frac{{\rm{w}}}{{\rm{W}}}({\rm{M}} + 42\,{\rm{n}}) = 56\,{\rm{n}}\) Where \(\mathrm{w}\) is the amount of alkali, \(\mathrm{W}\) is amount of acetyl derivative, M is the molecular mass of alcohol and n is the number of hydroxyl groups. \(\frac{{0.336}}{{0.436}}(92 + 42\,{\rm{n}}) = 56\,{\rm{n}}\) \(92 + 42{\rm{n}} = \frac{{0.436}}{{0.336}} \times 56{\rm{n}} = \frac{{218}}{3}{\rm{n}}\) or \(276+126 \mathrm{n}=218 \mathrm{n}\) or \(\mathrm{n}=3\) (the alcohol is trihydric.)
323192
If (dl) or ( \({\mathrm{\pm}}\) ) 2-methyl butanoic acid were esterified by reaction with (dl) or \({\mathrm{( \pm)}}\) 2-butanol, how many optically active compounds would be present in the final equilibrium reaction mixture?
1 1
2 2
3 3
4 4
Explanation:
Ester consists of two stereoisomers.Chiral centre during whole reaction are not effected,that's why all esters are optical active.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323193
Assertion : tert-Butoxide is a stronger base than \(\mathrm{OH}^{-}\)or \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}\)but is a much poorer nucleophile. Reason : A negatively charged ion is always a more powerful nucleophile than its conjugate acid.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Steric hindrance in the tert-butoxide ion, owing to its larger size compared to smaller alkoxide ions, significantly impedes the attack on a carbon atom in nucleophilic substitution reactions. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323194
Assertion : Acidic character of alcohols follows the order primary \(>\) secondary \(>\) tertiary. Reason : Acidic character of alcohols is due to the presence of polar \(-\mathrm{O}-\mathrm{H}\) group.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The acidity of alcohols depends on the \(+\mathrm{I}\) effect of alkyl groups, making tertiary alcohols less acidic due to stronger electron-releasing effects than primary alcohols. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323195
Assertion : Addition of \(\mathrm{CH}_{3} \mathrm{OH}\) to phenyl magnesium bromide gives benzene. Reason : \(\mathrm{CH}_{3} \mathrm{OH}\) is a stronger acid than benzene.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Methanol acts an acid and donates its proton to phenyl magnesium bromide which acts as a base and accepts the proton, to produce benzene. Methanol is a stronger acid than benzene as benzene is resonance stabilized. So the option (1) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323196
\(0.336\;{\rm{g}}\,\,{\rm{KOH}}\) hydrolyses with \(0.436 \mathrm{~g}\) of acetyl derivative of polyhydric alcohol. (molecular mass \(=92\) ). Then the number of hydroxyl groups in the alcohol are ____.
1 5
2 2
3 3
4 4
Explanation:
We know that, \(\frac{{\rm{w}}}{{\rm{W}}}({\rm{M}} + 42\,{\rm{n}}) = 56\,{\rm{n}}\) Where \(\mathrm{w}\) is the amount of alkali, \(\mathrm{W}\) is amount of acetyl derivative, M is the molecular mass of alcohol and n is the number of hydroxyl groups. \(\frac{{0.336}}{{0.436}}(92 + 42\,{\rm{n}}) = 56\,{\rm{n}}\) \(92 + 42{\rm{n}} = \frac{{0.436}}{{0.336}} \times 56{\rm{n}} = \frac{{218}}{3}{\rm{n}}\) or \(276+126 \mathrm{n}=218 \mathrm{n}\) or \(\mathrm{n}=3\) (the alcohol is trihydric.)
323192
If (dl) or ( \({\mathrm{\pm}}\) ) 2-methyl butanoic acid were esterified by reaction with (dl) or \({\mathrm{( \pm)}}\) 2-butanol, how many optically active compounds would be present in the final equilibrium reaction mixture?
1 1
2 2
3 3
4 4
Explanation:
Ester consists of two stereoisomers.Chiral centre during whole reaction are not effected,that's why all esters are optical active.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323193
Assertion : tert-Butoxide is a stronger base than \(\mathrm{OH}^{-}\)or \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}\)but is a much poorer nucleophile. Reason : A negatively charged ion is always a more powerful nucleophile than its conjugate acid.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Steric hindrance in the tert-butoxide ion, owing to its larger size compared to smaller alkoxide ions, significantly impedes the attack on a carbon atom in nucleophilic substitution reactions. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323194
Assertion : Acidic character of alcohols follows the order primary \(>\) secondary \(>\) tertiary. Reason : Acidic character of alcohols is due to the presence of polar \(-\mathrm{O}-\mathrm{H}\) group.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The acidity of alcohols depends on the \(+\mathrm{I}\) effect of alkyl groups, making tertiary alcohols less acidic due to stronger electron-releasing effects than primary alcohols. So the option (2) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323195
Assertion : Addition of \(\mathrm{CH}_{3} \mathrm{OH}\) to phenyl magnesium bromide gives benzene. Reason : \(\mathrm{CH}_{3} \mathrm{OH}\) is a stronger acid than benzene.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Methanol acts an acid and donates its proton to phenyl magnesium bromide which acts as a base and accepts the proton, to produce benzene. Methanol is a stronger acid than benzene as benzene is resonance stabilized. So the option (1) is correct.
CHXII11:ALCOHOLS, PHENOLS AND ETHERS
323196
\(0.336\;{\rm{g}}\,\,{\rm{KOH}}\) hydrolyses with \(0.436 \mathrm{~g}\) of acetyl derivative of polyhydric alcohol. (molecular mass \(=92\) ). Then the number of hydroxyl groups in the alcohol are ____.
1 5
2 2
3 3
4 4
Explanation:
We know that, \(\frac{{\rm{w}}}{{\rm{W}}}({\rm{M}} + 42\,{\rm{n}}) = 56\,{\rm{n}}\) Where \(\mathrm{w}\) is the amount of alkali, \(\mathrm{W}\) is amount of acetyl derivative, M is the molecular mass of alcohol and n is the number of hydroxyl groups. \(\frac{{0.336}}{{0.436}}(92 + 42\,{\rm{n}}) = 56\,{\rm{n}}\) \(92 + 42{\rm{n}} = \frac{{0.436}}{{0.336}} \times 56{\rm{n}} = \frac{{218}}{3}{\rm{n}}\) or \(276+126 \mathrm{n}=218 \mathrm{n}\) or \(\mathrm{n}=3\) (the alcohol is trihydric.)