323096
Which of the following statements are correct regarding dehydration of alcohols?
I. Conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) or conc. \(\mathrm{H}_{3} \mathrm{PO}_{4}\) or anhyd. \(\mathrm{ZnCl}_{2}\) or \(\mathrm{Al}_{2} \mathrm{O}_{3}\) can be used as dehydrating agent for alcohol.
II. The mechanism involves: Protonation \(\rightarrow\) Formation of carbocation \(\rightarrow\) Deprotonation
III. Primary alcohols are the easiest to dehydrate.
IV. Formation of carbocation is the rate determining step.
323097
Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Alcohols do not react with NaBr but when \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is added they form alkyl bromides.
Reason :
Protonation of the – OH group by \(\mathrm{H}_{2} \mathrm{SO}_{4}\) convert it into the \(-\stackrel{\oplus}{\mathrm{O}} \mathrm{H}_{2}\) group which has a better-leaving tendency.
323096
Which of the following statements are correct regarding dehydration of alcohols?
I. Conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) or conc. \(\mathrm{H}_{3} \mathrm{PO}_{4}\) or anhyd. \(\mathrm{ZnCl}_{2}\) or \(\mathrm{Al}_{2} \mathrm{O}_{3}\) can be used as dehydrating agent for alcohol.
II. The mechanism involves: Protonation \(\rightarrow\) Formation of carbocation \(\rightarrow\) Deprotonation
III. Primary alcohols are the easiest to dehydrate.
IV. Formation of carbocation is the rate determining step.
323097
Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Alcohols do not react with NaBr but when \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is added they form alkyl bromides.
Reason :
Protonation of the – OH group by \(\mathrm{H}_{2} \mathrm{SO}_{4}\) convert it into the \(-\stackrel{\oplus}{\mathrm{O}} \mathrm{H}_{2}\) group which has a better-leaving tendency.
323096
Which of the following statements are correct regarding dehydration of alcohols?
I. Conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) or conc. \(\mathrm{H}_{3} \mathrm{PO}_{4}\) or anhyd. \(\mathrm{ZnCl}_{2}\) or \(\mathrm{Al}_{2} \mathrm{O}_{3}\) can be used as dehydrating agent for alcohol.
II. The mechanism involves: Protonation \(\rightarrow\) Formation of carbocation \(\rightarrow\) Deprotonation
III. Primary alcohols are the easiest to dehydrate.
IV. Formation of carbocation is the rate determining step.
323097
Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Alcohols do not react with NaBr but when \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is added they form alkyl bromides.
Reason :
Protonation of the – OH group by \(\mathrm{H}_{2} \mathrm{SO}_{4}\) convert it into the \(-\stackrel{\oplus}{\mathrm{O}} \mathrm{H}_{2}\) group which has a better-leaving tendency.
323096
Which of the following statements are correct regarding dehydration of alcohols?
I. Conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) or conc. \(\mathrm{H}_{3} \mathrm{PO}_{4}\) or anhyd. \(\mathrm{ZnCl}_{2}\) or \(\mathrm{Al}_{2} \mathrm{O}_{3}\) can be used as dehydrating agent for alcohol.
II. The mechanism involves: Protonation \(\rightarrow\) Formation of carbocation \(\rightarrow\) Deprotonation
III. Primary alcohols are the easiest to dehydrate.
IV. Formation of carbocation is the rate determining step.
323097
Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Alcohols do not react with NaBr but when \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is added they form alkyl bromides.
Reason :
Protonation of the – OH group by \(\mathrm{H}_{2} \mathrm{SO}_{4}\) convert it into the \(-\stackrel{\oplus}{\mathrm{O}} \mathrm{H}_{2}\) group which has a better-leaving tendency.