322591
In reactions, the correct order of reactivity for the following compounds: and is:
1
2
3
4
Explanation:
Steric hindrance around the carbon atom undergoing the inversion process will slow down the reaction, hence less hindrance faster will the reaction. So, the order is
CHXII10:HALOALKANES AND HALOARENES
322592
Assertion : reaction of an optically active alkyl halide with an aqueous solution of always gives an alcohol with opposite sign of rotation. Reason : reactions always proceed with inversion of configuration.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
In an reaction involving an optically active alkyl halide and an aqueous solution of , the nucleophile attacks from the opposite side and there is inversion of configuration. As a result,the product formed is the enantiomer of the starting optically active alkyl halide, leading to an alcohol with the opposite optical rotation. So option (1) is correct.
CHXII10:HALOALKANES AND HALOARENES
322593
Increasing the concentration of a nucleophile in a typical reaction by a factor of 10 will cause the reaction rate to:
1 Increase by a factor of 10
2 Increase by a factor of
3 Decrease by a factor of 10
4 Remain about the same
Explanation:
Rate So, when increases by 10 factor, rate also increases by 10 factor.
CHXII10:HALOALKANES AND HALOARENES
322594
Tertiary alkyl halide is practically inert to substitution by mechanism because of
1 insolubility
2 instability
3 inductive effect
4 steric hindrance
Explanation:
As bulkiness increases, nucleophilic attack decreases.
322591
In reactions, the correct order of reactivity for the following compounds: and is:
1
2
3
4
Explanation:
Steric hindrance around the carbon atom undergoing the inversion process will slow down the reaction, hence less hindrance faster will the reaction. So, the order is
CHXII10:HALOALKANES AND HALOARENES
322592
Assertion : reaction of an optically active alkyl halide with an aqueous solution of always gives an alcohol with opposite sign of rotation. Reason : reactions always proceed with inversion of configuration.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
In an reaction involving an optically active alkyl halide and an aqueous solution of , the nucleophile attacks from the opposite side and there is inversion of configuration. As a result,the product formed is the enantiomer of the starting optically active alkyl halide, leading to an alcohol with the opposite optical rotation. So option (1) is correct.
CHXII10:HALOALKANES AND HALOARENES
322593
Increasing the concentration of a nucleophile in a typical reaction by a factor of 10 will cause the reaction rate to:
1 Increase by a factor of 10
2 Increase by a factor of
3 Decrease by a factor of 10
4 Remain about the same
Explanation:
Rate So, when increases by 10 factor, rate also increases by 10 factor.
CHXII10:HALOALKANES AND HALOARENES
322594
Tertiary alkyl halide is practically inert to substitution by mechanism because of
1 insolubility
2 instability
3 inductive effect
4 steric hindrance
Explanation:
As bulkiness increases, nucleophilic attack decreases.
322591
In reactions, the correct order of reactivity for the following compounds: and is:
1
2
3
4
Explanation:
Steric hindrance around the carbon atom undergoing the inversion process will slow down the reaction, hence less hindrance faster will the reaction. So, the order is
CHXII10:HALOALKANES AND HALOARENES
322592
Assertion : reaction of an optically active alkyl halide with an aqueous solution of always gives an alcohol with opposite sign of rotation. Reason : reactions always proceed with inversion of configuration.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
In an reaction involving an optically active alkyl halide and an aqueous solution of , the nucleophile attacks from the opposite side and there is inversion of configuration. As a result,the product formed is the enantiomer of the starting optically active alkyl halide, leading to an alcohol with the opposite optical rotation. So option (1) is correct.
CHXII10:HALOALKANES AND HALOARENES
322593
Increasing the concentration of a nucleophile in a typical reaction by a factor of 10 will cause the reaction rate to:
1 Increase by a factor of 10
2 Increase by a factor of
3 Decrease by a factor of 10
4 Remain about the same
Explanation:
Rate So, when increases by 10 factor, rate also increases by 10 factor.
CHXII10:HALOALKANES AND HALOARENES
322594
Tertiary alkyl halide is practically inert to substitution by mechanism because of
1 insolubility
2 instability
3 inductive effect
4 steric hindrance
Explanation:
As bulkiness increases, nucleophilic attack decreases.
322591
In reactions, the correct order of reactivity for the following compounds: and is:
1
2
3
4
Explanation:
Steric hindrance around the carbon atom undergoing the inversion process will slow down the reaction, hence less hindrance faster will the reaction. So, the order is
CHXII10:HALOALKANES AND HALOARENES
322592
Assertion : reaction of an optically active alkyl halide with an aqueous solution of always gives an alcohol with opposite sign of rotation. Reason : reactions always proceed with inversion of configuration.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
In an reaction involving an optically active alkyl halide and an aqueous solution of , the nucleophile attacks from the opposite side and there is inversion of configuration. As a result,the product formed is the enantiomer of the starting optically active alkyl halide, leading to an alcohol with the opposite optical rotation. So option (1) is correct.
CHXII10:HALOALKANES AND HALOARENES
322593
Increasing the concentration of a nucleophile in a typical reaction by a factor of 10 will cause the reaction rate to:
1 Increase by a factor of 10
2 Increase by a factor of
3 Decrease by a factor of 10
4 Remain about the same
Explanation:
Rate So, when increases by 10 factor, rate also increases by 10 factor.
CHXII10:HALOALKANES AND HALOARENES
322594
Tertiary alkyl halide is practically inert to substitution by mechanism because of
1 insolubility
2 instability
3 inductive effect
4 steric hindrance
Explanation:
As bulkiness increases, nucleophilic attack decreases.