Nucleophilic Substitution Reactions of Haloalkanes
CHXII10:HALOALKANES AND HALOARENES

322591 In SN2 reactions, the correct order of reactivity for the following compounds:
CH3Cl,CH3CH2Cl,(CH3)2CHCl and (CH3)3CCl is:

1 CH3Cl>(CH3)2CHCl>CH3CH2Cl>(CH3)3CCl
2 CH3Cl>CH3CH2Cl>(CH3)2CHCl>(CH3)3CCl
3 CH3CH2Cl>CH3Cl>(CH3)2CHCl >(CH3)3CCl
4 (CH3)2CHCl>CH3CH2Cl>CH3Cl >(CH3)3CCl
CHXII10:HALOALKANES AND HALOARENES

322592 Assertion :
SN2 reaction of an optically active alkyl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation.
Reason :
SN2 reactions always proceed with inversion of configuration.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII10:HALOALKANES AND HALOARENES

322593 Increasing the concentration of a nucleophile in a typical SN2 reaction by a factor of 10 will cause the reaction rate to:

1 Increase by a factor of 10
2 Increase by a factor of 102
3 Decrease by a factor of 10
4 Remain about the same
CHXII10:HALOALKANES AND HALOARENES

322591 In SN2 reactions, the correct order of reactivity for the following compounds:
CH3Cl,CH3CH2Cl,(CH3)2CHCl and (CH3)3CCl is:

1 CH3Cl>(CH3)2CHCl>CH3CH2Cl>(CH3)3CCl
2 CH3Cl>CH3CH2Cl>(CH3)2CHCl>(CH3)3CCl
3 CH3CH2Cl>CH3Cl>(CH3)2CHCl >(CH3)3CCl
4 (CH3)2CHCl>CH3CH2Cl>CH3Cl >(CH3)3CCl
CHXII10:HALOALKANES AND HALOARENES

322592 Assertion :
SN2 reaction of an optically active alkyl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation.
Reason :
SN2 reactions always proceed with inversion of configuration.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII10:HALOALKANES AND HALOARENES

322593 Increasing the concentration of a nucleophile in a typical SN2 reaction by a factor of 10 will cause the reaction rate to:

1 Increase by a factor of 10
2 Increase by a factor of 102
3 Decrease by a factor of 10
4 Remain about the same
CHXII10:HALOALKANES AND HALOARENES

322594 Tertiary alkyl halide is practically inert to substitution by SN2 mechanism because of

1 insolubility
2 instability
3 inductive effect
4 steric hindrance
CHXII10:HALOALKANES AND HALOARENES

322591 In SN2 reactions, the correct order of reactivity for the following compounds:
CH3Cl,CH3CH2Cl,(CH3)2CHCl and (CH3)3CCl is:

1 CH3Cl>(CH3)2CHCl>CH3CH2Cl>(CH3)3CCl
2 CH3Cl>CH3CH2Cl>(CH3)2CHCl>(CH3)3CCl
3 CH3CH2Cl>CH3Cl>(CH3)2CHCl >(CH3)3CCl
4 (CH3)2CHCl>CH3CH2Cl>CH3Cl >(CH3)3CCl
CHXII10:HALOALKANES AND HALOARENES

322592 Assertion :
SN2 reaction of an optically active alkyl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation.
Reason :
SN2 reactions always proceed with inversion of configuration.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII10:HALOALKANES AND HALOARENES

322593 Increasing the concentration of a nucleophile in a typical SN2 reaction by a factor of 10 will cause the reaction rate to:

1 Increase by a factor of 10
2 Increase by a factor of 102
3 Decrease by a factor of 10
4 Remain about the same
CHXII10:HALOALKANES AND HALOARENES

322594 Tertiary alkyl halide is practically inert to substitution by SN2 mechanism because of

1 insolubility
2 instability
3 inductive effect
4 steric hindrance
CHXII10:HALOALKANES AND HALOARENES

322591 In SN2 reactions, the correct order of reactivity for the following compounds:
CH3Cl,CH3CH2Cl,(CH3)2CHCl and (CH3)3CCl is:

1 CH3Cl>(CH3)2CHCl>CH3CH2Cl>(CH3)3CCl
2 CH3Cl>CH3CH2Cl>(CH3)2CHCl>(CH3)3CCl
3 CH3CH2Cl>CH3Cl>(CH3)2CHCl >(CH3)3CCl
4 (CH3)2CHCl>CH3CH2Cl>CH3Cl >(CH3)3CCl
CHXII10:HALOALKANES AND HALOARENES

322592 Assertion :
SN2 reaction of an optically active alkyl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation.
Reason :
SN2 reactions always proceed with inversion of configuration.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII10:HALOALKANES AND HALOARENES

322593 Increasing the concentration of a nucleophile in a typical SN2 reaction by a factor of 10 will cause the reaction rate to:

1 Increase by a factor of 10
2 Increase by a factor of 102
3 Decrease by a factor of 10
4 Remain about the same
CHXII10:HALOALKANES AND HALOARENES

322594 Tertiary alkyl halide is practically inert to substitution by SN2 mechanism because of

1 insolubility
2 instability
3 inductive effect
4 steric hindrance