322099
Assertion : \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) is more stable than \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) Reason : \(\ln \mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\), the EAN of \(\mathrm{Fe}\) is 36.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
Explanation:
Conceptual Questions
CHXII09:COORDINATION COMPOUNDS
322100
According to effective atomic number rule the central metal acquires:
1 Inert gas configuration
2 Duplet
3 Octet
4 Quartet
Explanation:
According to effective atomic number rule the central metal acquires inert gas configuration.
EAN of \(\mathrm{Fe}\) in \(\mathrm{K}_{3} \mathrm{Fe}(\mathrm{CN})_{6}\) is; \(26-3+2 \times 6=35\), i.e., not 36 the next inert gas.
CHXII09:COORDINATION COMPOUNDS
322103
Which of the following co-ordinate complexes is an exception to EAN rule? (Given atomic number \({\rm{Pt = 78,Fe = 26,}}\) \({\rm{Zn = 30,Cu = 29)}}\)
Effective Atomic Number (EAN) can be calculated by the following relation, \(\mathrm{EAN}=\mathrm{Z}\) (atomic number of the metal) - number of electrons lost in the ion formation + number of electrons gained from the donor atoms of the ligands.
322099
Assertion : \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) is more stable than \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) Reason : \(\ln \mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\), the EAN of \(\mathrm{Fe}\) is 36.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
Explanation:
Conceptual Questions
CHXII09:COORDINATION COMPOUNDS
322100
According to effective atomic number rule the central metal acquires:
1 Inert gas configuration
2 Duplet
3 Octet
4 Quartet
Explanation:
According to effective atomic number rule the central metal acquires inert gas configuration.
EAN of \(\mathrm{Fe}\) in \(\mathrm{K}_{3} \mathrm{Fe}(\mathrm{CN})_{6}\) is; \(26-3+2 \times 6=35\), i.e., not 36 the next inert gas.
CHXII09:COORDINATION COMPOUNDS
322103
Which of the following co-ordinate complexes is an exception to EAN rule? (Given atomic number \({\rm{Pt = 78,Fe = 26,}}\) \({\rm{Zn = 30,Cu = 29)}}\)
Effective Atomic Number (EAN) can be calculated by the following relation, \(\mathrm{EAN}=\mathrm{Z}\) (atomic number of the metal) - number of electrons lost in the ion formation + number of electrons gained from the donor atoms of the ligands.
322099
Assertion : \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) is more stable than \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) Reason : \(\ln \mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\), the EAN of \(\mathrm{Fe}\) is 36.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
Explanation:
Conceptual Questions
CHXII09:COORDINATION COMPOUNDS
322100
According to effective atomic number rule the central metal acquires:
1 Inert gas configuration
2 Duplet
3 Octet
4 Quartet
Explanation:
According to effective atomic number rule the central metal acquires inert gas configuration.
EAN of \(\mathrm{Fe}\) in \(\mathrm{K}_{3} \mathrm{Fe}(\mathrm{CN})_{6}\) is; \(26-3+2 \times 6=35\), i.e., not 36 the next inert gas.
CHXII09:COORDINATION COMPOUNDS
322103
Which of the following co-ordinate complexes is an exception to EAN rule? (Given atomic number \({\rm{Pt = 78,Fe = 26,}}\) \({\rm{Zn = 30,Cu = 29)}}\)
Effective Atomic Number (EAN) can be calculated by the following relation, \(\mathrm{EAN}=\mathrm{Z}\) (atomic number of the metal) - number of electrons lost in the ion formation + number of electrons gained from the donor atoms of the ligands.
322099
Assertion : \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) is more stable than \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) Reason : \(\ln \mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\), the EAN of \(\mathrm{Fe}\) is 36.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
Explanation:
Conceptual Questions
CHXII09:COORDINATION COMPOUNDS
322100
According to effective atomic number rule the central metal acquires:
1 Inert gas configuration
2 Duplet
3 Octet
4 Quartet
Explanation:
According to effective atomic number rule the central metal acquires inert gas configuration.
EAN of \(\mathrm{Fe}\) in \(\mathrm{K}_{3} \mathrm{Fe}(\mathrm{CN})_{6}\) is; \(26-3+2 \times 6=35\), i.e., not 36 the next inert gas.
CHXII09:COORDINATION COMPOUNDS
322103
Which of the following co-ordinate complexes is an exception to EAN rule? (Given atomic number \({\rm{Pt = 78,Fe = 26,}}\) \({\rm{Zn = 30,Cu = 29)}}\)
Effective Atomic Number (EAN) can be calculated by the following relation, \(\mathrm{EAN}=\mathrm{Z}\) (atomic number of the metal) - number of electrons lost in the ion formation + number of electrons gained from the donor atoms of the ligands.
322099
Assertion : \(\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) is more stable than \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\) Reason : \(\ln \mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\), the EAN of \(\mathrm{Fe}\) is 36.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
Explanation:
Conceptual Questions
CHXII09:COORDINATION COMPOUNDS
322100
According to effective atomic number rule the central metal acquires:
1 Inert gas configuration
2 Duplet
3 Octet
4 Quartet
Explanation:
According to effective atomic number rule the central metal acquires inert gas configuration.
EAN of \(\mathrm{Fe}\) in \(\mathrm{K}_{3} \mathrm{Fe}(\mathrm{CN})_{6}\) is; \(26-3+2 \times 6=35\), i.e., not 36 the next inert gas.
CHXII09:COORDINATION COMPOUNDS
322103
Which of the following co-ordinate complexes is an exception to EAN rule? (Given atomic number \({\rm{Pt = 78,Fe = 26,}}\) \({\rm{Zn = 30,Cu = 29)}}\)
Effective Atomic Number (EAN) can be calculated by the following relation, \(\mathrm{EAN}=\mathrm{Z}\) (atomic number of the metal) - number of electrons lost in the ion formation + number of electrons gained from the donor atoms of the ligands.