Isomerism in Coordination Compounds
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CHXII09:COORDINATION COMPOUNDS

322021 The total number of stereoisomers for the complex \(\left[\mathrm{Cr}(\mathrm{ox})_{2} \mathrm{ClBr}\right]^{3-}\) (where ox = oxalate) is

1 2
2 4
3 1
4 3
CHXII09:COORDINATION COMPOUNDS

322022 The total number of structural isomers of the complex compound \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) is

1 4
2 3
3 6
4 5
CHXII09:COORDINATION COMPOUNDS

322023 Match the (column I) with (Column -II) with their appropriate choice:
Column I
Column II
A
\(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\)
P
Solvate isomerism
B
\(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
Q
Coordination isomerism
C
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\)
R
Optical isomerism
D
\(\mathrm{Cis}-\left[\mathrm{Co}(\text { en })_{2} \mathrm{Cl}_{2}\right]^{+}\)
S
Geometrical isomerism

1 \({\text{A - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
2 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
3 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
4 \({\text{A - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
CHXII09:COORDINATION COMPOUNDS

322024 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4}\left(\mathrm{NO}_{2}\right)_{2}\right] \mathrm{Cl}\) exhibits:

1 Linkage isomerism, ionization isomerism and geometrical isomerism.
2 Ionisation isomerism, geometrical isomerism and optical isomerism
3 Linkage isomerism, geometrical isomerismand optical isomerism
4 Linkage isomerism, ionization isomerism and optical isomerism.
CHXII09:COORDINATION COMPOUNDS

322021 The total number of stereoisomers for the complex \(\left[\mathrm{Cr}(\mathrm{ox})_{2} \mathrm{ClBr}\right]^{3-}\) (where ox = oxalate) is

1 2
2 4
3 1
4 3
CHXII09:COORDINATION COMPOUNDS

322022 The total number of structural isomers of the complex compound \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) is

1 4
2 3
3 6
4 5
CHXII09:COORDINATION COMPOUNDS

322023 Match the (column I) with (Column -II) with their appropriate choice:
Column I
Column II
A
\(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\)
P
Solvate isomerism
B
\(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
Q
Coordination isomerism
C
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\)
R
Optical isomerism
D
\(\mathrm{Cis}-\left[\mathrm{Co}(\text { en })_{2} \mathrm{Cl}_{2}\right]^{+}\)
S
Geometrical isomerism

1 \({\text{A - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
2 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
3 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
4 \({\text{A - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
CHXII09:COORDINATION COMPOUNDS

322024 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4}\left(\mathrm{NO}_{2}\right)_{2}\right] \mathrm{Cl}\) exhibits:

1 Linkage isomerism, ionization isomerism and geometrical isomerism.
2 Ionisation isomerism, geometrical isomerism and optical isomerism
3 Linkage isomerism, geometrical isomerismand optical isomerism
4 Linkage isomerism, ionization isomerism and optical isomerism.
CHXII09:COORDINATION COMPOUNDS

322021 The total number of stereoisomers for the complex \(\left[\mathrm{Cr}(\mathrm{ox})_{2} \mathrm{ClBr}\right]^{3-}\) (where ox = oxalate) is

1 2
2 4
3 1
4 3
CHXII09:COORDINATION COMPOUNDS

322022 The total number of structural isomers of the complex compound \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) is

1 4
2 3
3 6
4 5
CHXII09:COORDINATION COMPOUNDS

322023 Match the (column I) with (Column -II) with their appropriate choice:
Column I
Column II
A
\(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\)
P
Solvate isomerism
B
\(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
Q
Coordination isomerism
C
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\)
R
Optical isomerism
D
\(\mathrm{Cis}-\left[\mathrm{Co}(\text { en })_{2} \mathrm{Cl}_{2}\right]^{+}\)
S
Geometrical isomerism

1 \({\text{A - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
2 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
3 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
4 \({\text{A - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
CHXII09:COORDINATION COMPOUNDS

322024 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4}\left(\mathrm{NO}_{2}\right)_{2}\right] \mathrm{Cl}\) exhibits:

1 Linkage isomerism, ionization isomerism and geometrical isomerism.
2 Ionisation isomerism, geometrical isomerism and optical isomerism
3 Linkage isomerism, geometrical isomerismand optical isomerism
4 Linkage isomerism, ionization isomerism and optical isomerism.
CHXII09:COORDINATION COMPOUNDS

322021 The total number of stereoisomers for the complex \(\left[\mathrm{Cr}(\mathrm{ox})_{2} \mathrm{ClBr}\right]^{3-}\) (where ox = oxalate) is

1 2
2 4
3 1
4 3
CHXII09:COORDINATION COMPOUNDS

322022 The total number of structural isomers of the complex compound \(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{PtCl}_{4}\right]\) is

1 4
2 3
3 6
4 5
CHXII09:COORDINATION COMPOUNDS

322023 Match the (column I) with (Column -II) with their appropriate choice:
Column I
Column II
A
\(\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]\left[\mathrm{CuCl}_{4}\right]\)
P
Solvate isomerism
B
\(\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}\)
Q
Coordination isomerism
C
\(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]\)
R
Optical isomerism
D
\(\mathrm{Cis}-\left[\mathrm{Co}(\text { en })_{2} \mathrm{Cl}_{2}\right]^{+}\)
S
Geometrical isomerism

1 \({\text{A - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
2 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - R}}\)
3 \({\text{A - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - Q,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
4 \({\text{A - S,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{B - R,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{C - P,}}{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,{\text{D - Q}}\)
CHXII09:COORDINATION COMPOUNDS

322024 \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4}\left(\mathrm{NO}_{2}\right)_{2}\right] \mathrm{Cl}\) exhibits:

1 Linkage isomerism, ionization isomerism and geometrical isomerism.
2 Ionisation isomerism, geometrical isomerism and optical isomerism
3 Linkage isomerism, geometrical isomerismand optical isomerism
4 Linkage isomerism, ionization isomerism and optical isomerism.