321983
Assertion : \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\) does not show optical isomerism. Reason : It has a plane of symmetry.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The essential requirement for a substance to exhibit optical activity is the absence of a plane of symmetry within its molecular or structural arrangement. In the given structure of \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\), there is a plane of symmetry that makes the complex optically inactive. So the option (1) is correct.
CHXII09:COORDINATION COMPOUNDS
321984
Which can exist both as diastereoisomer and enantiomer?
\(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) can exist both as diastereoisomer and enantiomer.
The \((+)\) and \((-)\) forms of cis \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are enantiomers. The cis and trans forms of \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are diastereoisomers.
CHXII09:COORDINATION COMPOUNDS
321985
Select optically active complex.
1 Only (IV)
2 (I) and (IV)
3 (I), (II) and (III)
4 (I) and (III)
Explanation:
Only IV. Mabcdef has non-superimposable mirror image having no elements of symmetry.
CHXII09:COORDINATION COMPOUNDS
321986
For which of the following tetrahedral complex, isomers are possible?
321983
Assertion : \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\) does not show optical isomerism. Reason : It has a plane of symmetry.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The essential requirement for a substance to exhibit optical activity is the absence of a plane of symmetry within its molecular or structural arrangement. In the given structure of \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\), there is a plane of symmetry that makes the complex optically inactive. So the option (1) is correct.
CHXII09:COORDINATION COMPOUNDS
321984
Which can exist both as diastereoisomer and enantiomer?
\(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) can exist both as diastereoisomer and enantiomer.
The \((+)\) and \((-)\) forms of cis \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are enantiomers. The cis and trans forms of \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are diastereoisomers.
CHXII09:COORDINATION COMPOUNDS
321985
Select optically active complex.
1 Only (IV)
2 (I) and (IV)
3 (I), (II) and (III)
4 (I) and (III)
Explanation:
Only IV. Mabcdef has non-superimposable mirror image having no elements of symmetry.
CHXII09:COORDINATION COMPOUNDS
321986
For which of the following tetrahedral complex, isomers are possible?
321983
Assertion : \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\) does not show optical isomerism. Reason : It has a plane of symmetry.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The essential requirement for a substance to exhibit optical activity is the absence of a plane of symmetry within its molecular or structural arrangement. In the given structure of \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\), there is a plane of symmetry that makes the complex optically inactive. So the option (1) is correct.
CHXII09:COORDINATION COMPOUNDS
321984
Which can exist both as diastereoisomer and enantiomer?
\(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) can exist both as diastereoisomer and enantiomer.
The \((+)\) and \((-)\) forms of cis \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are enantiomers. The cis and trans forms of \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are diastereoisomers.
CHXII09:COORDINATION COMPOUNDS
321985
Select optically active complex.
1 Only (IV)
2 (I) and (IV)
3 (I), (II) and (III)
4 (I) and (III)
Explanation:
Only IV. Mabcdef has non-superimposable mirror image having no elements of symmetry.
CHXII09:COORDINATION COMPOUNDS
321986
For which of the following tetrahedral complex, isomers are possible?
321983
Assertion : \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\) does not show optical isomerism. Reason : It has a plane of symmetry.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The essential requirement for a substance to exhibit optical activity is the absence of a plane of symmetry within its molecular or structural arrangement. In the given structure of \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\), there is a plane of symmetry that makes the complex optically inactive. So the option (1) is correct.
CHXII09:COORDINATION COMPOUNDS
321984
Which can exist both as diastereoisomer and enantiomer?
\(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) can exist both as diastereoisomer and enantiomer.
The \((+)\) and \((-)\) forms of cis \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are enantiomers. The cis and trans forms of \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are diastereoisomers.
CHXII09:COORDINATION COMPOUNDS
321985
Select optically active complex.
1 Only (IV)
2 (I) and (IV)
3 (I), (II) and (III)
4 (I) and (III)
Explanation:
Only IV. Mabcdef has non-superimposable mirror image having no elements of symmetry.
CHXII09:COORDINATION COMPOUNDS
321986
For which of the following tetrahedral complex, isomers are possible?
321983
Assertion : \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\) does not show optical isomerism. Reason : It has a plane of symmetry.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
The essential requirement for a substance to exhibit optical activity is the absence of a plane of symmetry within its molecular or structural arrangement. In the given structure of \(\left[\mathrm{Co}\left(\mathrm{NO}_{2}\right)_{3}\left(\mathrm{NH}_{3}\right)_{3}\right]\), there is a plane of symmetry that makes the complex optically inactive. So the option (1) is correct.
CHXII09:COORDINATION COMPOUNDS
321984
Which can exist both as diastereoisomer and enantiomer?
\(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) can exist both as diastereoisomer and enantiomer.
The \((+)\) and \((-)\) forms of cis \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are enantiomers. The cis and trans forms of \(\left[\mathrm{Pt}(\mathrm{en})_{2} \mathrm{ClBr}\right]^{2+}\) are diastereoisomers.
CHXII09:COORDINATION COMPOUNDS
321985
Select optically active complex.
1 Only (IV)
2 (I) and (IV)
3 (I), (II) and (III)
4 (I) and (III)
Explanation:
Only IV. Mabcdef has non-superimposable mirror image having no elements of symmetry.
CHXII09:COORDINATION COMPOUNDS
321986
For which of the following tetrahedral complex, isomers are possible?
