321780
If a didenate ligand ethane -1,2-diamine is progressively added in the molar ratio
en : \(\mathrm{Ni}=1: 1,2: 1,3: 1\) to \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)\right]^{2+}\) aq solution, following co-ordination entities are formed
I. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4} \mathrm{en}\right]_{(\mathrm{aq})}^{2+}\) - pale blue
II. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]_{(\mathrm{aq})}^{2+}\) - blue / purple
III. \(\left[\mathrm{Ni}(\mathrm{en})_{3}\right]_{(\mathrm{aq})}^{2+}\) - violet
The wavelength in nm of light absorbed in case of I and III are respectively.
321783
Consider the following complexes :
(I) \({\mathrm{\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}}}\)
(II) \({\mathrm{\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}}}\)
(III) \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}}}\)
(IV) \({\mathrm{\left[\mathrm{Cu}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]^{2+}}}\)
The correct order of (I), (II), (III) and (IV) in terms of wave number of light absorbed is
321780
If a didenate ligand ethane -1,2-diamine is progressively added in the molar ratio
en : \(\mathrm{Ni}=1: 1,2: 1,3: 1\) to \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)\right]^{2+}\) aq solution, following co-ordination entities are formed
I. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4} \mathrm{en}\right]_{(\mathrm{aq})}^{2+}\) - pale blue
II. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]_{(\mathrm{aq})}^{2+}\) - blue / purple
III. \(\left[\mathrm{Ni}(\mathrm{en})_{3}\right]_{(\mathrm{aq})}^{2+}\) - violet
The wavelength in nm of light absorbed in case of I and III are respectively.
321783
Consider the following complexes :
(I) \({\mathrm{\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}}}\)
(II) \({\mathrm{\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}}}\)
(III) \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}}}\)
(IV) \({\mathrm{\left[\mathrm{Cu}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]^{2+}}}\)
The correct order of (I), (II), (III) and (IV) in terms of wave number of light absorbed is
321780
If a didenate ligand ethane -1,2-diamine is progressively added in the molar ratio
en : \(\mathrm{Ni}=1: 1,2: 1,3: 1\) to \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)\right]^{2+}\) aq solution, following co-ordination entities are formed
I. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4} \mathrm{en}\right]_{(\mathrm{aq})}^{2+}\) - pale blue
II. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]_{(\mathrm{aq})}^{2+}\) - blue / purple
III. \(\left[\mathrm{Ni}(\mathrm{en})_{3}\right]_{(\mathrm{aq})}^{2+}\) - violet
The wavelength in nm of light absorbed in case of I and III are respectively.
321783
Consider the following complexes :
(I) \({\mathrm{\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}}}\)
(II) \({\mathrm{\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}}}\)
(III) \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}}}\)
(IV) \({\mathrm{\left[\mathrm{Cu}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]^{2+}}}\)
The correct order of (I), (II), (III) and (IV) in terms of wave number of light absorbed is
321780
If a didenate ligand ethane -1,2-diamine is progressively added in the molar ratio
en : \(\mathrm{Ni}=1: 1,2: 1,3: 1\) to \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)\right]^{2+}\) aq solution, following co-ordination entities are formed
I. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4} \mathrm{en}\right]_{(\mathrm{aq})}^{2+}\) - pale blue
II. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]_{(\mathrm{aq})}^{2+}\) - blue / purple
III. \(\left[\mathrm{Ni}(\mathrm{en})_{3}\right]_{(\mathrm{aq})}^{2+}\) - violet
The wavelength in nm of light absorbed in case of I and III are respectively.
321783
Consider the following complexes :
(I) \({\mathrm{\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}}}\)
(II) \({\mathrm{\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}}}\)
(III) \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}}}\)
(IV) \({\mathrm{\left[\mathrm{Cu}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]^{2+}}}\)
The correct order of (I), (II), (III) and (IV) in terms of wave number of light absorbed is
321780
If a didenate ligand ethane -1,2-diamine is progressively added in the molar ratio
en : \(\mathrm{Ni}=1: 1,2: 1,3: 1\) to \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}_{6}\right)\right]^{2+}\) aq solution, following co-ordination entities are formed
I. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4} \mathrm{en}\right]_{(\mathrm{aq})}^{2+}\) - pale blue
II. \(\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}(\text { en })_{2}\right]_{(\mathrm{aq})}^{2+}\) - blue / purple
III. \(\left[\mathrm{Ni}(\mathrm{en})_{3}\right]_{(\mathrm{aq})}^{2+}\) - violet
The wavelength in nm of light absorbed in case of I and III are respectively.
321783
Consider the following complexes :
(I) \({\mathrm{\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}}}\)
(II) \({\mathrm{\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}}}\)
(III) \({\mathrm{\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}}}\)
(IV) \({\mathrm{\left[\mathrm{Cu}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\right]^{2+}}}\)
The correct order of (I), (II), (III) and (IV) in terms of wave number of light absorbed is