Compounds of transition elements
CHXII08:THE D- & F-BLOCK ELEMENTS

321348 The number of electrons gained by \(\mathrm{\mathrm{KMnO}_{4}}\) in acidic medium when it reacts with 1 mol of \(\mathrm{\mathrm{H}_{2} \mathrm{O}_{2}}\) is equal to that of:

1 s electrons in \({\rm{Ca}}\,\,{\rm{(Z = 20)}}\)
2 p electrons in Neon \(\mathrm{(Z=10)}\)
3 d electrons in Chromium \({\rm{(Z = 24)}}\)
4 f electrons in Lanthanum \(\mathrm{(Z=57)}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321349 \(\mathrm{KMnO}_{4}\) oxidises thiosulphate to \(\mathrm{SO}_{4}^{2-}\) as per reaction
\({\rm{xMnO}}_4^ - + 3\;{{\rm{S}}_{\rm{2}}}{\rm{O}}_3^{2 - } + {{\rm{H}}_{\rm{2}}}{\rm{O}} \to \)
\(\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\text{xMn}}{{\text{O}}_2} + 6{\text{SO}}_4^{2 - } + 2{\text{O}}{{\text{H}}^ - }\)
Find the value of \({\rm{x}}\) in above reaction.

1 8
2 4
3 3
4 5
CHXII08:THE D- & F-BLOCK ELEMENTS

321350 Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Equivalent mass of \(\mathrm{KMnO}_{4}\) is equal to one third of its molecular mass when it acts as an oxidising agent in faintly alkaline medium.
Reason :
Oxidation number of manganese in \(\mathrm{KMnO}_{4}\) is +7

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII08:THE D- & F-BLOCK ELEMENTS

321351 In permanganate ion \(\mathrm{\mathrm{MnO}_{4}^{-}}\), manganese has an oxidation number of +7 . Therefore it is

1 \(\mathrm{s p^{3} d^{3}}\) hybridised
2 \(\mathrm{s p^{3}}\) hybridised
3 \(\mathrm{d s p^{2}}\) hybridised
4 \(\mathrm{d^{3} s p^{3}}\) hybridised
CHXII08:THE D- & F-BLOCK ELEMENTS

321348 The number of electrons gained by \(\mathrm{\mathrm{KMnO}_{4}}\) in acidic medium when it reacts with 1 mol of \(\mathrm{\mathrm{H}_{2} \mathrm{O}_{2}}\) is equal to that of:

1 s electrons in \({\rm{Ca}}\,\,{\rm{(Z = 20)}}\)
2 p electrons in Neon \(\mathrm{(Z=10)}\)
3 d electrons in Chromium \({\rm{(Z = 24)}}\)
4 f electrons in Lanthanum \(\mathrm{(Z=57)}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321349 \(\mathrm{KMnO}_{4}\) oxidises thiosulphate to \(\mathrm{SO}_{4}^{2-}\) as per reaction
\({\rm{xMnO}}_4^ - + 3\;{{\rm{S}}_{\rm{2}}}{\rm{O}}_3^{2 - } + {{\rm{H}}_{\rm{2}}}{\rm{O}} \to \)
\(\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\text{xMn}}{{\text{O}}_2} + 6{\text{SO}}_4^{2 - } + 2{\text{O}}{{\text{H}}^ - }\)
Find the value of \({\rm{x}}\) in above reaction.

1 8
2 4
3 3
4 5
CHXII08:THE D- & F-BLOCK ELEMENTS

321350 Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Equivalent mass of \(\mathrm{KMnO}_{4}\) is equal to one third of its molecular mass when it acts as an oxidising agent in faintly alkaline medium.
Reason :
Oxidation number of manganese in \(\mathrm{KMnO}_{4}\) is +7

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII08:THE D- & F-BLOCK ELEMENTS

321351 In permanganate ion \(\mathrm{\mathrm{MnO}_{4}^{-}}\), manganese has an oxidation number of +7 . Therefore it is

1 \(\mathrm{s p^{3} d^{3}}\) hybridised
2 \(\mathrm{s p^{3}}\) hybridised
3 \(\mathrm{d s p^{2}}\) hybridised
4 \(\mathrm{d^{3} s p^{3}}\) hybridised
CHXII08:THE D- & F-BLOCK ELEMENTS

321348 The number of electrons gained by \(\mathrm{\mathrm{KMnO}_{4}}\) in acidic medium when it reacts with 1 mol of \(\mathrm{\mathrm{H}_{2} \mathrm{O}_{2}}\) is equal to that of:

1 s electrons in \({\rm{Ca}}\,\,{\rm{(Z = 20)}}\)
2 p electrons in Neon \(\mathrm{(Z=10)}\)
3 d electrons in Chromium \({\rm{(Z = 24)}}\)
4 f electrons in Lanthanum \(\mathrm{(Z=57)}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321349 \(\mathrm{KMnO}_{4}\) oxidises thiosulphate to \(\mathrm{SO}_{4}^{2-}\) as per reaction
\({\rm{xMnO}}_4^ - + 3\;{{\rm{S}}_{\rm{2}}}{\rm{O}}_3^{2 - } + {{\rm{H}}_{\rm{2}}}{\rm{O}} \to \)
\(\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\text{xMn}}{{\text{O}}_2} + 6{\text{SO}}_4^{2 - } + 2{\text{O}}{{\text{H}}^ - }\)
Find the value of \({\rm{x}}\) in above reaction.

1 8
2 4
3 3
4 5
CHXII08:THE D- & F-BLOCK ELEMENTS

321350 Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Equivalent mass of \(\mathrm{KMnO}_{4}\) is equal to one third of its molecular mass when it acts as an oxidising agent in faintly alkaline medium.
Reason :
Oxidation number of manganese in \(\mathrm{KMnO}_{4}\) is +7

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII08:THE D- & F-BLOCK ELEMENTS

321351 In permanganate ion \(\mathrm{\mathrm{MnO}_{4}^{-}}\), manganese has an oxidation number of +7 . Therefore it is

1 \(\mathrm{s p^{3} d^{3}}\) hybridised
2 \(\mathrm{s p^{3}}\) hybridised
3 \(\mathrm{d s p^{2}}\) hybridised
4 \(\mathrm{d^{3} s p^{3}}\) hybridised
CHXII08:THE D- & F-BLOCK ELEMENTS

321348 The number of electrons gained by \(\mathrm{\mathrm{KMnO}_{4}}\) in acidic medium when it reacts with 1 mol of \(\mathrm{\mathrm{H}_{2} \mathrm{O}_{2}}\) is equal to that of:

1 s electrons in \({\rm{Ca}}\,\,{\rm{(Z = 20)}}\)
2 p electrons in Neon \(\mathrm{(Z=10)}\)
3 d electrons in Chromium \({\rm{(Z = 24)}}\)
4 f electrons in Lanthanum \(\mathrm{(Z=57)}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321349 \(\mathrm{KMnO}_{4}\) oxidises thiosulphate to \(\mathrm{SO}_{4}^{2-}\) as per reaction
\({\rm{xMnO}}_4^ - + 3\;{{\rm{S}}_{\rm{2}}}{\rm{O}}_3^{2 - } + {{\rm{H}}_{\rm{2}}}{\rm{O}} \to \)
\(\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\text{xMn}}{{\text{O}}_2} + 6{\text{SO}}_4^{2 - } + 2{\text{O}}{{\text{H}}^ - }\)
Find the value of \({\rm{x}}\) in above reaction.

1 8
2 4
3 3
4 5
CHXII08:THE D- & F-BLOCK ELEMENTS

321350 Read Assertion and Reason carefully to mark the correct option given below.
Assertion :
Equivalent mass of \(\mathrm{KMnO}_{4}\) is equal to one third of its molecular mass when it acts as an oxidising agent in faintly alkaline medium.
Reason :
Oxidation number of manganese in \(\mathrm{KMnO}_{4}\) is +7

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXII08:THE D- & F-BLOCK ELEMENTS

321351 In permanganate ion \(\mathrm{\mathrm{MnO}_{4}^{-}}\), manganese has an oxidation number of +7 . Therefore it is

1 \(\mathrm{s p^{3} d^{3}}\) hybridised
2 \(\mathrm{s p^{3}}\) hybridised
3 \(\mathrm{d s p^{2}}\) hybridised
4 \(\mathrm{d^{3} s p^{3}}\) hybridised