Compounds of transition elements
CHXII08:THE D- & F-BLOCK ELEMENTS

321275 \(\mathrm{NaCl}\) reacts with conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) to give reddish fumes (B), which react with
\(\mathrm{NaOH}\) to give yellow solution (C) . (B) and
(C) respectively are :

1 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\)
2 \(\mathrm{Na}_{2} \mathrm{CrO}_{4}, \mathrm{CrO}_{2} \mathrm{Cl}_{2}\)
3 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{KHSO}_{4}\)
4 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{CrO}_{4}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321276 When sulphur dioxide is passed in an acidified \(\mathrm{\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}}\) solution, the oxidation state of sulphur is changed from

1 +4 to +6
2 +6 to +4
3 +4 to 0
4 +4 to +2
CHXII08:THE D- & F-BLOCK ELEMENTS

321277 When orange solution containing \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) ion is treated with an alkali, a yellow solution is formed and when \(\mathrm{\mathrm{H}^{+}}\)ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?

1 \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) changes to \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) in basic medium
2 \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) changes to \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) in acid medium
3 Both are in equillibrium hence addition of acid or base shift the equillibrium, hence the colour change.
4 All the above.
CHXII08:THE D- & F-BLOCK ELEMENTS

321278 The ionic charges on chromate ion and dichromate ion respectively is

1 \(\mathrm{-2,-2}\)
2 \(\mathrm{-3,-2}\)
3 \(\mathrm{-2,-4}\)
4 \(\mathrm{-4,-2}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321275 \(\mathrm{NaCl}\) reacts with conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) to give reddish fumes (B), which react with
\(\mathrm{NaOH}\) to give yellow solution (C) . (B) and
(C) respectively are :

1 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\)
2 \(\mathrm{Na}_{2} \mathrm{CrO}_{4}, \mathrm{CrO}_{2} \mathrm{Cl}_{2}\)
3 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{KHSO}_{4}\)
4 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{CrO}_{4}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321276 When sulphur dioxide is passed in an acidified \(\mathrm{\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}}\) solution, the oxidation state of sulphur is changed from

1 +4 to +6
2 +6 to +4
3 +4 to 0
4 +4 to +2
CHXII08:THE D- & F-BLOCK ELEMENTS

321277 When orange solution containing \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) ion is treated with an alkali, a yellow solution is formed and when \(\mathrm{\mathrm{H}^{+}}\)ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?

1 \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) changes to \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) in basic medium
2 \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) changes to \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) in acid medium
3 Both are in equillibrium hence addition of acid or base shift the equillibrium, hence the colour change.
4 All the above.
CHXII08:THE D- & F-BLOCK ELEMENTS

321278 The ionic charges on chromate ion and dichromate ion respectively is

1 \(\mathrm{-2,-2}\)
2 \(\mathrm{-3,-2}\)
3 \(\mathrm{-2,-4}\)
4 \(\mathrm{-4,-2}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321275 \(\mathrm{NaCl}\) reacts with conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) to give reddish fumes (B), which react with
\(\mathrm{NaOH}\) to give yellow solution (C) . (B) and
(C) respectively are :

1 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\)
2 \(\mathrm{Na}_{2} \mathrm{CrO}_{4}, \mathrm{CrO}_{2} \mathrm{Cl}_{2}\)
3 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{KHSO}_{4}\)
4 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{CrO}_{4}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321276 When sulphur dioxide is passed in an acidified \(\mathrm{\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}}\) solution, the oxidation state of sulphur is changed from

1 +4 to +6
2 +6 to +4
3 +4 to 0
4 +4 to +2
CHXII08:THE D- & F-BLOCK ELEMENTS

321277 When orange solution containing \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) ion is treated with an alkali, a yellow solution is formed and when \(\mathrm{\mathrm{H}^{+}}\)ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?

1 \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) changes to \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) in basic medium
2 \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) changes to \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) in acid medium
3 Both are in equillibrium hence addition of acid or base shift the equillibrium, hence the colour change.
4 All the above.
CHXII08:THE D- & F-BLOCK ELEMENTS

321278 The ionic charges on chromate ion and dichromate ion respectively is

1 \(\mathrm{-2,-2}\)
2 \(\mathrm{-3,-2}\)
3 \(\mathrm{-2,-4}\)
4 \(\mathrm{-4,-2}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321275 \(\mathrm{NaCl}\) reacts with conc. \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) to give reddish fumes (B), which react with
\(\mathrm{NaOH}\) to give yellow solution (C) . (B) and
(C) respectively are :

1 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\)
2 \(\mathrm{Na}_{2} \mathrm{CrO}_{4}, \mathrm{CrO}_{2} \mathrm{Cl}_{2}\)
3 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{KHSO}_{4}\)
4 \(\mathrm{CrO}_{2} \mathrm{Cl}_{2}, \mathrm{Na}_{2} \mathrm{CrO}_{4}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321276 When sulphur dioxide is passed in an acidified \(\mathrm{\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}}\) solution, the oxidation state of sulphur is changed from

1 +4 to +6
2 +6 to +4
3 +4 to 0
4 +4 to +2
CHXII08:THE D- & F-BLOCK ELEMENTS

321277 When orange solution containing \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) ion is treated with an alkali, a yellow solution is formed and when \(\mathrm{\mathrm{H}^{+}}\)ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?

1 \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) changes to \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) in basic medium
2 \(\mathrm{\mathrm{CrO}_{4}^{2-}}\) changes to \(\mathrm{\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}}\) in acid medium
3 Both are in equillibrium hence addition of acid or base shift the equillibrium, hence the colour change.
4 All the above.
CHXII08:THE D- & F-BLOCK ELEMENTS

321278 The ionic charges on chromate ion and dichromate ion respectively is

1 \(\mathrm{-2,-2}\)
2 \(\mathrm{-3,-2}\)
3 \(\mathrm{-2,-4}\)
4 \(\mathrm{-4,-2}\)