Compounds of transition elements
CHXII08:THE D- & F-BLOCK ELEMENTS

321331 \(\mathrm{\mathrm{KMnO}_{4}}\) can be prepared from \(\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}\) as per the reaction:
\(\mathrm{3 \mathrm{MnO}_{4}^{2-}+2 \mathrm{H}_{2} \mathrm{O} \rightleftharpoons 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+4 \mathrm{OH}^{-}}\).
The reaction can go to completion by removing \(\mathrm{\mathrm{OH}^{-}}\)ions by adding.

1 \(\mathrm{\mathrm{SO}_{2}}\)
2 \(\mathrm{\mathrm{HCl}}\)
3 \(\mathrm{\mathrm{KOH}}\)
4 \(\mathrm{\mathrm{CO}_{2}}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321332 When \(\mathrm{\mathrm{KMnO}_{4}}\) solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because

1 \(\mathrm{\mathrm{CO}_{2}}\) is formed as the product.
2 Reaction is exothermic.
3 \(\mathrm{\mathrm{MnO}_{4}^{-}}\)catalyses the reaction.
4 \(\mathrm{\mathrm{Mn}^{2+}}\) acts as autocatalyst.
CHXII08:THE D- & F-BLOCK ELEMENTS

321333 Number of electrons transferred in each case when \(\mathrm{KMnO}_{4}\) acts as an oxidizing agent to give\(\mathrm{MnO}_{2}, \mathrm{Mn}^{2+}, \mathrm{Mn}(\mathrm{OH})_{3}, \mathrm{MnO}_{4}^{2-}\) are, respectively.

1 \(3,5,4\), and 1
2 \(4,3,1\), and 5
3 \(1,3,4\), and 5
4 \(5,4,3\), and 1
CHXII08:THE D- & F-BLOCK ELEMENTS

321334 Identify the correct statements from below.
(I) The chromate ion is square planar.
(II) Dichromates are generally prepared from chromates.
(III) The green manganate ion is diamagnetic.
(IV) Dark green coloured \({\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}}\)disproportionates in a neutral or acidic medium to give permanganate.
(V) With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below

1 (I),(IV), (V) only
2 (II), (IV), (V) only
3 (II), (III), (IV) only
4 (I), (II), (III) only
CHXII08:THE D- & F-BLOCK ELEMENTS

321331 \(\mathrm{\mathrm{KMnO}_{4}}\) can be prepared from \(\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}\) as per the reaction:
\(\mathrm{3 \mathrm{MnO}_{4}^{2-}+2 \mathrm{H}_{2} \mathrm{O} \rightleftharpoons 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+4 \mathrm{OH}^{-}}\).
The reaction can go to completion by removing \(\mathrm{\mathrm{OH}^{-}}\)ions by adding.

1 \(\mathrm{\mathrm{SO}_{2}}\)
2 \(\mathrm{\mathrm{HCl}}\)
3 \(\mathrm{\mathrm{KOH}}\)
4 \(\mathrm{\mathrm{CO}_{2}}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321332 When \(\mathrm{\mathrm{KMnO}_{4}}\) solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because

1 \(\mathrm{\mathrm{CO}_{2}}\) is formed as the product.
2 Reaction is exothermic.
3 \(\mathrm{\mathrm{MnO}_{4}^{-}}\)catalyses the reaction.
4 \(\mathrm{\mathrm{Mn}^{2+}}\) acts as autocatalyst.
CHXII08:THE D- & F-BLOCK ELEMENTS

321333 Number of electrons transferred in each case when \(\mathrm{KMnO}_{4}\) acts as an oxidizing agent to give\(\mathrm{MnO}_{2}, \mathrm{Mn}^{2+}, \mathrm{Mn}(\mathrm{OH})_{3}, \mathrm{MnO}_{4}^{2-}\) are, respectively.

1 \(3,5,4\), and 1
2 \(4,3,1\), and 5
3 \(1,3,4\), and 5
4 \(5,4,3\), and 1
CHXII08:THE D- & F-BLOCK ELEMENTS

321334 Identify the correct statements from below.
(I) The chromate ion is square planar.
(II) Dichromates are generally prepared from chromates.
(III) The green manganate ion is diamagnetic.
(IV) Dark green coloured \({\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}}\)disproportionates in a neutral or acidic medium to give permanganate.
(V) With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below

1 (I),(IV), (V) only
2 (II), (IV), (V) only
3 (II), (III), (IV) only
4 (I), (II), (III) only
CHXII08:THE D- & F-BLOCK ELEMENTS

321331 \(\mathrm{\mathrm{KMnO}_{4}}\) can be prepared from \(\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}\) as per the reaction:
\(\mathrm{3 \mathrm{MnO}_{4}^{2-}+2 \mathrm{H}_{2} \mathrm{O} \rightleftharpoons 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+4 \mathrm{OH}^{-}}\).
The reaction can go to completion by removing \(\mathrm{\mathrm{OH}^{-}}\)ions by adding.

1 \(\mathrm{\mathrm{SO}_{2}}\)
2 \(\mathrm{\mathrm{HCl}}\)
3 \(\mathrm{\mathrm{KOH}}\)
4 \(\mathrm{\mathrm{CO}_{2}}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321332 When \(\mathrm{\mathrm{KMnO}_{4}}\) solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because

1 \(\mathrm{\mathrm{CO}_{2}}\) is formed as the product.
2 Reaction is exothermic.
3 \(\mathrm{\mathrm{MnO}_{4}^{-}}\)catalyses the reaction.
4 \(\mathrm{\mathrm{Mn}^{2+}}\) acts as autocatalyst.
CHXII08:THE D- & F-BLOCK ELEMENTS

321333 Number of electrons transferred in each case when \(\mathrm{KMnO}_{4}\) acts as an oxidizing agent to give\(\mathrm{MnO}_{2}, \mathrm{Mn}^{2+}, \mathrm{Mn}(\mathrm{OH})_{3}, \mathrm{MnO}_{4}^{2-}\) are, respectively.

1 \(3,5,4\), and 1
2 \(4,3,1\), and 5
3 \(1,3,4\), and 5
4 \(5,4,3\), and 1
CHXII08:THE D- & F-BLOCK ELEMENTS

321334 Identify the correct statements from below.
(I) The chromate ion is square planar.
(II) Dichromates are generally prepared from chromates.
(III) The green manganate ion is diamagnetic.
(IV) Dark green coloured \({\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}}\)disproportionates in a neutral or acidic medium to give permanganate.
(V) With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below

1 (I),(IV), (V) only
2 (II), (IV), (V) only
3 (II), (III), (IV) only
4 (I), (II), (III) only
CHXII08:THE D- & F-BLOCK ELEMENTS

321331 \(\mathrm{\mathrm{KMnO}_{4}}\) can be prepared from \(\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}\) as per the reaction:
\(\mathrm{3 \mathrm{MnO}_{4}^{2-}+2 \mathrm{H}_{2} \mathrm{O} \rightleftharpoons 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+4 \mathrm{OH}^{-}}\).
The reaction can go to completion by removing \(\mathrm{\mathrm{OH}^{-}}\)ions by adding.

1 \(\mathrm{\mathrm{SO}_{2}}\)
2 \(\mathrm{\mathrm{HCl}}\)
3 \(\mathrm{\mathrm{KOH}}\)
4 \(\mathrm{\mathrm{CO}_{2}}\)
CHXII08:THE D- & F-BLOCK ELEMENTS

321332 When \(\mathrm{\mathrm{KMnO}_{4}}\) solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because

1 \(\mathrm{\mathrm{CO}_{2}}\) is formed as the product.
2 Reaction is exothermic.
3 \(\mathrm{\mathrm{MnO}_{4}^{-}}\)catalyses the reaction.
4 \(\mathrm{\mathrm{Mn}^{2+}}\) acts as autocatalyst.
CHXII08:THE D- & F-BLOCK ELEMENTS

321333 Number of electrons transferred in each case when \(\mathrm{KMnO}_{4}\) acts as an oxidizing agent to give\(\mathrm{MnO}_{2}, \mathrm{Mn}^{2+}, \mathrm{Mn}(\mathrm{OH})_{3}, \mathrm{MnO}_{4}^{2-}\) are, respectively.

1 \(3,5,4\), and 1
2 \(4,3,1\), and 5
3 \(1,3,4\), and 5
4 \(5,4,3\), and 1
CHXII08:THE D- & F-BLOCK ELEMENTS

321334 Identify the correct statements from below.
(I) The chromate ion is square planar.
(II) Dichromates are generally prepared from chromates.
(III) The green manganate ion is diamagnetic.
(IV) Dark green coloured \({\mathrm{\mathrm{K}_{2} \mathrm{MnO}_{4}}}\)disproportionates in a neutral or acidic medium to give permanganate.
(V) With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below

1 (I),(IV), (V) only
2 (II), (IV), (V) only
3 (II), (III), (IV) only
4 (I), (II), (III) only