1 \({\mathrm{\mathrm{MnO}_{4}^{2-}}}\) and \({\mathrm{\mathrm{Mn}_{2} \mathrm{O}_{7}}}\)
2 \({\mathrm{\mathrm{Mn}_{2} \mathrm{O}_{3}}}\) and \({\mathrm{\mathrm{MnO}_{4}^{2-}}}\)
3 \({\mathrm{\mathrm{MnO}_{4}^{2-}}}\) and \({\mathrm{\mathrm{MnO}_{4}^{-}}}\)
4 \({\mathrm{\mathrm{Mn}_{2} \mathrm{O}_{7}}}\) and \({\mathrm{\mathrm{MnO}_{4}^{-}}}\)
Explanation:
\({\text{Mn}}{{\text{O}}_{\text{2}}}\xrightarrow[{{\text{Oxidised}}{\kern 1pt} {\text{with}}{\kern 1pt} {\text{air}}{\kern 1pt} {\text{or}}{\kern 1pt} {\text{KN}}{{\text{O}}_{\text{3}}}}]{{{\text{Fused with KOH}}}}\mathop {{\text{MnO}}_{\text{4}}^{2 - }}\limits_{{\text{Manganate}}{\kern 1pt} {\text{ion}}} \)
\(\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\xrightarrow[{{\text{Oxidation}}\,\,{\text{in}}\,\,{\text{alkaline}}\,\,{\text{solution}}}]{{{\text{Electrolytic}}}}\mathop {{\text{MnO}}_{\text{4}}^ - }\limits_{{\text{Permanganate}}\,\,{\text{ion}}} \)
So, the correct option is (3).