1 increase the E and shift equilibrium to the right.
2 lower the \(E\) and shift equilibrium to the right.
3 lower the E and shift equlibrium to the left.
4 increase the \(\mathrm{E}\) and shift equilibrium to the left.
Explanation:
\[\begin{array}{l}
{\rm{Zn(s) + 2}}{{\rm{H}}^{\rm{ + }}}{\rm{ + (aq)}}\\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\rm{Z}}{{\rm{n}}^{{\rm{2 + }}}}{\rm{(aq) + }}{{\rm{H}}_{\rm{2}}}{\rm{(g)}}
\end{array}\]
\({{\rm{E}}_{{\rm{cell}}}}{\rm{ = E}}{{\rm{^\circ }}_{{\rm{cell}}}}{\rm{ - }}\frac{{{\rm{0}}{\rm{.059}}}}{{\rm{2}}}{\rm{log}}\frac{{{\rm{[Z}}{{\rm{n}}^{{\rm{2 + }}}}{\rm{][}}{{\rm{H}}_{\rm{2}}}{\rm{]}}}}{{{{{\rm{[}}{{\rm{H}}^{\rm{ + }}}{\rm{]}}}^{\rm{2}}}}}\)
Addition of \({{\rm{H}}_{\rm{2}}}{\rm{S}}{{\rm{O}}_{\rm{4}}}\) will increase \(\left[ {{{\rm{H}}^{\rm{ + }}}} \right]\) and
\({{\rm{E}}_{{\rm{cell }}}}\) will also increase and the equilibrium will shift towards RHS