The vapour pressures of two component systems shows positive deviation from Raoult’s law (non-ideal solution).
CHXII02:SOLUTIONS
319476
Statement A : Ethanol and acetone show positive deviation from Raoult’s law. Statement B : Pure ethanol molecule show hydrogen bond and on adding acetone hydrogen bond between ethanol molecules breaks.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both Statements are correct.
4 Both Statements are incorrect.
Explanation:
Ethanol molecules shows hydrogen bonding. On adding acetone, its molecules get in between the host molecule and break some of hydrogen bonds between them. Due to weakening of interaction the mixture of ethanol and acetone shows the positive deviation from Raoult’s law.
CHXII02:SOLUTIONS
319477
A solution of two miscible liquids showing negative deviation from Raoult's law will have :
1 Increased vapour pressure, increased boiling point
2 Increased vapour pressure, decreased boiling point
3 Decreased vapour pressure, increased boiling point
In the solutions which show deviation from Raoult's law, more attractions are there between particles. As a result vapour pressure decreases and boiling point increases. So, the correct option is (3).
JEE Main - 2024
CHXII02:SOLUTIONS
319478
Assertion : The mixing of two completely miscible liquid, A and B showing positive deviation from Raoult’s law is followed by an absorption of heat Reason : The A-B molecular interaction forces are stronger than the molecular interaction forces.
1 If both Assertion & Reason are true and reason is the correct explanation of the assertion.
2 If both Assertion & Reason are true but reason is not the correct explanation of the assertion.
3 If Assertion is true but Reason is false.
4 If Assertion is false but Reason is true.
Explanation:
Conceptual Questions
CHXII02:SOLUTIONS
319479
Identify the mixture that shows positive deviations from Raoult's Law.
1
2
3
4
Explanation:
When a solution is formed by adding carbon disulphide to acetone , the dipolar interactions among the solute - solute and solvent - solvent molecules are stronger than solute - solvent interactions. Hence, this solution shows positive deviation from Raoult's law. So, the correct option is (4).
The vapour pressures of two component systems shows positive deviation from Raoult’s law (non-ideal solution).
CHXII02:SOLUTIONS
319476
Statement A : Ethanol and acetone show positive deviation from Raoult’s law. Statement B : Pure ethanol molecule show hydrogen bond and on adding acetone hydrogen bond between ethanol molecules breaks.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both Statements are correct.
4 Both Statements are incorrect.
Explanation:
Ethanol molecules shows hydrogen bonding. On adding acetone, its molecules get in between the host molecule and break some of hydrogen bonds between them. Due to weakening of interaction the mixture of ethanol and acetone shows the positive deviation from Raoult’s law.
CHXII02:SOLUTIONS
319477
A solution of two miscible liquids showing negative deviation from Raoult's law will have :
1 Increased vapour pressure, increased boiling point
2 Increased vapour pressure, decreased boiling point
3 Decreased vapour pressure, increased boiling point
In the solutions which show deviation from Raoult's law, more attractions are there between particles. As a result vapour pressure decreases and boiling point increases. So, the correct option is (3).
JEE Main - 2024
CHXII02:SOLUTIONS
319478
Assertion : The mixing of two completely miscible liquid, A and B showing positive deviation from Raoult’s law is followed by an absorption of heat Reason : The A-B molecular interaction forces are stronger than the molecular interaction forces.
1 If both Assertion & Reason are true and reason is the correct explanation of the assertion.
2 If both Assertion & Reason are true but reason is not the correct explanation of the assertion.
3 If Assertion is true but Reason is false.
4 If Assertion is false but Reason is true.
Explanation:
Conceptual Questions
CHXII02:SOLUTIONS
319479
Identify the mixture that shows positive deviations from Raoult's Law.
1
2
3
4
Explanation:
When a solution is formed by adding carbon disulphide to acetone , the dipolar interactions among the solute - solute and solvent - solvent molecules are stronger than solute - solvent interactions. Hence, this solution shows positive deviation from Raoult's law. So, the correct option is (4).
The vapour pressures of two component systems shows positive deviation from Raoult’s law (non-ideal solution).
CHXII02:SOLUTIONS
319476
Statement A : Ethanol and acetone show positive deviation from Raoult’s law. Statement B : Pure ethanol molecule show hydrogen bond and on adding acetone hydrogen bond between ethanol molecules breaks.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both Statements are correct.
4 Both Statements are incorrect.
Explanation:
Ethanol molecules shows hydrogen bonding. On adding acetone, its molecules get in between the host molecule and break some of hydrogen bonds between them. Due to weakening of interaction the mixture of ethanol and acetone shows the positive deviation from Raoult’s law.
CHXII02:SOLUTIONS
319477
A solution of two miscible liquids showing negative deviation from Raoult's law will have :
1 Increased vapour pressure, increased boiling point
2 Increased vapour pressure, decreased boiling point
3 Decreased vapour pressure, increased boiling point
In the solutions which show deviation from Raoult's law, more attractions are there between particles. As a result vapour pressure decreases and boiling point increases. So, the correct option is (3).
JEE Main - 2024
CHXII02:SOLUTIONS
319478
Assertion : The mixing of two completely miscible liquid, A and B showing positive deviation from Raoult’s law is followed by an absorption of heat Reason : The A-B molecular interaction forces are stronger than the molecular interaction forces.
1 If both Assertion & Reason are true and reason is the correct explanation of the assertion.
2 If both Assertion & Reason are true but reason is not the correct explanation of the assertion.
3 If Assertion is true but Reason is false.
4 If Assertion is false but Reason is true.
Explanation:
Conceptual Questions
CHXII02:SOLUTIONS
319479
Identify the mixture that shows positive deviations from Raoult's Law.
1
2
3
4
Explanation:
When a solution is formed by adding carbon disulphide to acetone , the dipolar interactions among the solute - solute and solvent - solvent molecules are stronger than solute - solvent interactions. Hence, this solution shows positive deviation from Raoult's law. So, the correct option is (4).
The vapour pressures of two component systems shows positive deviation from Raoult’s law (non-ideal solution).
CHXII02:SOLUTIONS
319476
Statement A : Ethanol and acetone show positive deviation from Raoult’s law. Statement B : Pure ethanol molecule show hydrogen bond and on adding acetone hydrogen bond between ethanol molecules breaks.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both Statements are correct.
4 Both Statements are incorrect.
Explanation:
Ethanol molecules shows hydrogen bonding. On adding acetone, its molecules get in between the host molecule and break some of hydrogen bonds between them. Due to weakening of interaction the mixture of ethanol and acetone shows the positive deviation from Raoult’s law.
CHXII02:SOLUTIONS
319477
A solution of two miscible liquids showing negative deviation from Raoult's law will have :
1 Increased vapour pressure, increased boiling point
2 Increased vapour pressure, decreased boiling point
3 Decreased vapour pressure, increased boiling point
In the solutions which show deviation from Raoult's law, more attractions are there between particles. As a result vapour pressure decreases and boiling point increases. So, the correct option is (3).
JEE Main - 2024
CHXII02:SOLUTIONS
319478
Assertion : The mixing of two completely miscible liquid, A and B showing positive deviation from Raoult’s law is followed by an absorption of heat Reason : The A-B molecular interaction forces are stronger than the molecular interaction forces.
1 If both Assertion & Reason are true and reason is the correct explanation of the assertion.
2 If both Assertion & Reason are true but reason is not the correct explanation of the assertion.
3 If Assertion is true but Reason is false.
4 If Assertion is false but Reason is true.
Explanation:
Conceptual Questions
CHXII02:SOLUTIONS
319479
Identify the mixture that shows positive deviations from Raoult's Law.
1
2
3
4
Explanation:
When a solution is formed by adding carbon disulphide to acetone , the dipolar interactions among the solute - solute and solvent - solvent molecules are stronger than solute - solvent interactions. Hence, this solution shows positive deviation from Raoult's law. So, the correct option is (4).
The vapour pressures of two component systems shows positive deviation from Raoult’s law (non-ideal solution).
CHXII02:SOLUTIONS
319476
Statement A : Ethanol and acetone show positive deviation from Raoult’s law. Statement B : Pure ethanol molecule show hydrogen bond and on adding acetone hydrogen bond between ethanol molecules breaks.
1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both Statements are correct.
4 Both Statements are incorrect.
Explanation:
Ethanol molecules shows hydrogen bonding. On adding acetone, its molecules get in between the host molecule and break some of hydrogen bonds between them. Due to weakening of interaction the mixture of ethanol and acetone shows the positive deviation from Raoult’s law.
CHXII02:SOLUTIONS
319477
A solution of two miscible liquids showing negative deviation from Raoult's law will have :
1 Increased vapour pressure, increased boiling point
2 Increased vapour pressure, decreased boiling point
3 Decreased vapour pressure, increased boiling point
In the solutions which show deviation from Raoult's law, more attractions are there between particles. As a result vapour pressure decreases and boiling point increases. So, the correct option is (3).
JEE Main - 2024
CHXII02:SOLUTIONS
319478
Assertion : The mixing of two completely miscible liquid, A and B showing positive deviation from Raoult’s law is followed by an absorption of heat Reason : The A-B molecular interaction forces are stronger than the molecular interaction forces.
1 If both Assertion & Reason are true and reason is the correct explanation of the assertion.
2 If both Assertion & Reason are true but reason is not the correct explanation of the assertion.
3 If Assertion is true but Reason is false.
4 If Assertion is false but Reason is true.
Explanation:
Conceptual Questions
CHXII02:SOLUTIONS
319479
Identify the mixture that shows positive deviations from Raoult's Law.
1
2
3
4
Explanation:
When a solution is formed by adding carbon disulphide to acetone , the dipolar interactions among the solute - solute and solvent - solvent molecules are stronger than solute - solvent interactions. Hence, this solution shows positive deviation from Raoult's law. So, the correct option is (4).