Depression of Freezing Point
CHXII02:SOLUTIONS

319079 When a solution containing non-volatile solute freezes, which equilibrium would exist?

1 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solvent }}\)
2 \({\text{solid solute}} \rightleftharpoons {\text{liquid solution}}\)
3 \({\text{solid solute}} \rightleftharpoons {\text{liquid solvent }}\)
4 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solution}}\)
CHXII02:SOLUTIONS

319080 When 0.2 mole of urea is dissolved in 100 g of a solvent, the depression of freezing point is \({\mathrm{0.50^{\circ} \mathrm{C}}}\). When 0.3 mole of non-volatile solute is dissolved in 100 g of the same solvent, the depression of freezing point will be ____ \(^\circ {\text{C}}\).

1 0.2
2 10.2
3 0.5
4 0.75
CHXII02:SOLUTIONS

319081 How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K (\({{\rm{K}}_{\rm{f}}}\) for water is \({\rm{1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K}}{\mkern 1mu} {\mkern 1mu} {\rm{kg}}{\mkern 1mu} {\mkern 1mu} {\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}\)) (Assume Molarity is equal to Molality)

1 880.07g
2 899.04g
3 886.02g
4 868.06g
CHXII02:SOLUTIONS

319082 Assertion :
The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different.
Reason :
Water is polar and benzene is non - polar.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect
CHXII02:SOLUTIONS

319083 A solution of sucrose \(\left( {{\rm{molar}}\,\,{\rm{mass}}\,\,{\rm{342}}\,\,{\rm{g}}\,\,{\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}} \right)\) has been produced by dissolving 68.5 g sucrose in 1000 g water. The freezing point of the solution obtained will be
\(\left( {{{\rm{K}}_{\rm{f}}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{kg/mol}}} \right)\)

1 \({\rm{ + 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
2 \({\rm{ - 0}}{\rm{.57}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
3 \({\rm{ - 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
4 \({\rm{ - 0}}{\rm{.52}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
CHXII02:SOLUTIONS

319079 When a solution containing non-volatile solute freezes, which equilibrium would exist?

1 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solvent }}\)
2 \({\text{solid solute}} \rightleftharpoons {\text{liquid solution}}\)
3 \({\text{solid solute}} \rightleftharpoons {\text{liquid solvent }}\)
4 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solution}}\)
CHXII02:SOLUTIONS

319080 When 0.2 mole of urea is dissolved in 100 g of a solvent, the depression of freezing point is \({\mathrm{0.50^{\circ} \mathrm{C}}}\). When 0.3 mole of non-volatile solute is dissolved in 100 g of the same solvent, the depression of freezing point will be ____ \(^\circ {\text{C}}\).

1 0.2
2 10.2
3 0.5
4 0.75
CHXII02:SOLUTIONS

319081 How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K (\({{\rm{K}}_{\rm{f}}}\) for water is \({\rm{1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K}}{\mkern 1mu} {\mkern 1mu} {\rm{kg}}{\mkern 1mu} {\mkern 1mu} {\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}\)) (Assume Molarity is equal to Molality)

1 880.07g
2 899.04g
3 886.02g
4 868.06g
CHXII02:SOLUTIONS

319082 Assertion :
The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different.
Reason :
Water is polar and benzene is non - polar.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect
CHXII02:SOLUTIONS

319083 A solution of sucrose \(\left( {{\rm{molar}}\,\,{\rm{mass}}\,\,{\rm{342}}\,\,{\rm{g}}\,\,{\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}} \right)\) has been produced by dissolving 68.5 g sucrose in 1000 g water. The freezing point of the solution obtained will be
\(\left( {{{\rm{K}}_{\rm{f}}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{kg/mol}}} \right)\)

1 \({\rm{ + 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
2 \({\rm{ - 0}}{\rm{.57}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
3 \({\rm{ - 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
4 \({\rm{ - 0}}{\rm{.52}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
CHXII02:SOLUTIONS

319079 When a solution containing non-volatile solute freezes, which equilibrium would exist?

1 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solvent }}\)
2 \({\text{solid solute}} \rightleftharpoons {\text{liquid solution}}\)
3 \({\text{solid solute}} \rightleftharpoons {\text{liquid solvent }}\)
4 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solution}}\)
CHXII02:SOLUTIONS

319080 When 0.2 mole of urea is dissolved in 100 g of a solvent, the depression of freezing point is \({\mathrm{0.50^{\circ} \mathrm{C}}}\). When 0.3 mole of non-volatile solute is dissolved in 100 g of the same solvent, the depression of freezing point will be ____ \(^\circ {\text{C}}\).

1 0.2
2 10.2
3 0.5
4 0.75
CHXII02:SOLUTIONS

319081 How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K (\({{\rm{K}}_{\rm{f}}}\) for water is \({\rm{1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K}}{\mkern 1mu} {\mkern 1mu} {\rm{kg}}{\mkern 1mu} {\mkern 1mu} {\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}\)) (Assume Molarity is equal to Molality)

1 880.07g
2 899.04g
3 886.02g
4 868.06g
CHXII02:SOLUTIONS

319082 Assertion :
The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different.
Reason :
Water is polar and benzene is non - polar.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect
CHXII02:SOLUTIONS

319083 A solution of sucrose \(\left( {{\rm{molar}}\,\,{\rm{mass}}\,\,{\rm{342}}\,\,{\rm{g}}\,\,{\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}} \right)\) has been produced by dissolving 68.5 g sucrose in 1000 g water. The freezing point of the solution obtained will be
\(\left( {{{\rm{K}}_{\rm{f}}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{kg/mol}}} \right)\)

1 \({\rm{ + 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
2 \({\rm{ - 0}}{\rm{.57}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
3 \({\rm{ - 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
4 \({\rm{ - 0}}{\rm{.52}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
CHXII02:SOLUTIONS

319079 When a solution containing non-volatile solute freezes, which equilibrium would exist?

1 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solvent }}\)
2 \({\text{solid solute}} \rightleftharpoons {\text{liquid solution}}\)
3 \({\text{solid solute}} \rightleftharpoons {\text{liquid solvent }}\)
4 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solution}}\)
CHXII02:SOLUTIONS

319080 When 0.2 mole of urea is dissolved in 100 g of a solvent, the depression of freezing point is \({\mathrm{0.50^{\circ} \mathrm{C}}}\). When 0.3 mole of non-volatile solute is dissolved in 100 g of the same solvent, the depression of freezing point will be ____ \(^\circ {\text{C}}\).

1 0.2
2 10.2
3 0.5
4 0.75
CHXII02:SOLUTIONS

319081 How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K (\({{\rm{K}}_{\rm{f}}}\) for water is \({\rm{1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K}}{\mkern 1mu} {\mkern 1mu} {\rm{kg}}{\mkern 1mu} {\mkern 1mu} {\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}\)) (Assume Molarity is equal to Molality)

1 880.07g
2 899.04g
3 886.02g
4 868.06g
CHXII02:SOLUTIONS

319082 Assertion :
The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different.
Reason :
Water is polar and benzene is non - polar.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect
CHXII02:SOLUTIONS

319083 A solution of sucrose \(\left( {{\rm{molar}}\,\,{\rm{mass}}\,\,{\rm{342}}\,\,{\rm{g}}\,\,{\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}} \right)\) has been produced by dissolving 68.5 g sucrose in 1000 g water. The freezing point of the solution obtained will be
\(\left( {{{\rm{K}}_{\rm{f}}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{kg/mol}}} \right)\)

1 \({\rm{ + 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
2 \({\rm{ - 0}}{\rm{.57}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
3 \({\rm{ - 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
4 \({\rm{ - 0}}{\rm{.52}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
CHXII02:SOLUTIONS

319079 When a solution containing non-volatile solute freezes, which equilibrium would exist?

1 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solvent }}\)
2 \({\text{solid solute}} \rightleftharpoons {\text{liquid solution}}\)
3 \({\text{solid solute}} \rightleftharpoons {\text{liquid solvent }}\)
4 \({\text{solid solvent}} \rightleftharpoons {\text{liquid solution}}\)
CHXII02:SOLUTIONS

319080 When 0.2 mole of urea is dissolved in 100 g of a solvent, the depression of freezing point is \({\mathrm{0.50^{\circ} \mathrm{C}}}\). When 0.3 mole of non-volatile solute is dissolved in 100 g of the same solvent, the depression of freezing point will be ____ \(^\circ {\text{C}}\).

1 0.2
2 10.2
3 0.5
4 0.75
CHXII02:SOLUTIONS

319081 How many grams of methyl alcohol should be added to 10 litre tank of water to prevent its freezing at 268 K (\({{\rm{K}}_{\rm{f}}}\) for water is \({\rm{1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K}}{\mkern 1mu} {\mkern 1mu} {\rm{kg}}{\mkern 1mu} {\mkern 1mu} {\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}\)) (Assume Molarity is equal to Molality)

1 880.07g
2 899.04g
3 886.02g
4 868.06g
CHXII02:SOLUTIONS

319082 Assertion :
The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different.
Reason :
Water is polar and benzene is non - polar.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and Reason are incorrect
CHXII02:SOLUTIONS

319083 A solution of sucrose \(\left( {{\rm{molar}}\,\,{\rm{mass}}\,\,{\rm{342}}\,\,{\rm{g}}\,\,{\rm{mo}}{{\rm{l}}^{{\rm{ - 1}}}}} \right)\) has been produced by dissolving 68.5 g sucrose in 1000 g water. The freezing point of the solution obtained will be
\(\left( {{{\rm{K}}_{\rm{f}}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {{\rm{H}}_{\rm{2}}}{\rm{O = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{kg/mol}}} \right)\)

1 \({\rm{ + 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
2 \({\rm{ - 0}}{\rm{.57}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)
3 \({\rm{ - 0}}{\rm{.37}}{{\rm{2}}^{\rm{^\circ }}}{\rm{C}}\)
4 \({\rm{ - 0}}{\rm{.52}}{{\rm{0}}^{\rm{^\circ }}}{\rm{C}}\)