Abnormal Molar Masses and Van't Hoff Factor
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CHXII02:SOLUTIONS

319063 The degree of dissociation \(\left( \alpha \right)\) of weak electrolyte \({{\rm{A}}_{\rm{a}}}{{\rm{B}}_{\rm{b}}}\) is related to Van’t Hoff factor (i) by the expression

1 \({\rm{\alpha = }}\frac{{{\rm{a + b - 1}}}}{{{\rm{i - 1}}}}\)
2 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{{\rm{a + b + 1}}}}\)
3 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{\left( {{\rm{a + b - 1}}} \right)}}\)
4 \({\rm{\alpha = }}\frac{{{\rm{a + b + 1}}}}{{{\rm{i - 1}}}}\)
CHXII02:SOLUTIONS

319064 A 0.5 molal aqueous solution of a weak acid (HX) is 20 percent ionised. The lowering in freezing point of this solution is
\(\left( {{{\rm{K}}_{\rm{f}}}{\rm{ = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K/m}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {\rm{water}}} \right)\)

1 0.56 K
2 \({\rm{ - 1}}{\rm{.12}}\,{\rm{K}}\)
3 1.12 K
4 \({\rm{ - 0}}{\rm{.56}}\,{\rm{K}}\)
CHXII02:SOLUTIONS

319065 Assertion :
\(\mathrm{NaCl}\) in water and organic acids in benzene show abnormal molecular mass.
Reason :
Abnormal molecular mass is obtained when the substance in the solution undergoes dissociation or association.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII02:SOLUTIONS

319066 An aqueous solution of a salt \({\rm{M}}{{\rm{X}}_{\rm{2}}}\) at certain temperature has a Van’t Hoff factor of 2. The degree of dissociation for this solution of the salt is :

1 0.67
2 0.33
3 \(0.80\)
4 \(0.50\)
CHXII02:SOLUTIONS

319063 The degree of dissociation \(\left( \alpha \right)\) of weak electrolyte \({{\rm{A}}_{\rm{a}}}{{\rm{B}}_{\rm{b}}}\) is related to Van’t Hoff factor (i) by the expression

1 \({\rm{\alpha = }}\frac{{{\rm{a + b - 1}}}}{{{\rm{i - 1}}}}\)
2 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{{\rm{a + b + 1}}}}\)
3 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{\left( {{\rm{a + b - 1}}} \right)}}\)
4 \({\rm{\alpha = }}\frac{{{\rm{a + b + 1}}}}{{{\rm{i - 1}}}}\)
CHXII02:SOLUTIONS

319064 A 0.5 molal aqueous solution of a weak acid (HX) is 20 percent ionised. The lowering in freezing point of this solution is
\(\left( {{{\rm{K}}_{\rm{f}}}{\rm{ = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K/m}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {\rm{water}}} \right)\)

1 0.56 K
2 \({\rm{ - 1}}{\rm{.12}}\,{\rm{K}}\)
3 1.12 K
4 \({\rm{ - 0}}{\rm{.56}}\,{\rm{K}}\)
CHXII02:SOLUTIONS

319065 Assertion :
\(\mathrm{NaCl}\) in water and organic acids in benzene show abnormal molecular mass.
Reason :
Abnormal molecular mass is obtained when the substance in the solution undergoes dissociation or association.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII02:SOLUTIONS

319066 An aqueous solution of a salt \({\rm{M}}{{\rm{X}}_{\rm{2}}}\) at certain temperature has a Van’t Hoff factor of 2. The degree of dissociation for this solution of the salt is :

1 0.67
2 0.33
3 \(0.80\)
4 \(0.50\)
CHXII02:SOLUTIONS

319063 The degree of dissociation \(\left( \alpha \right)\) of weak electrolyte \({{\rm{A}}_{\rm{a}}}{{\rm{B}}_{\rm{b}}}\) is related to Van’t Hoff factor (i) by the expression

1 \({\rm{\alpha = }}\frac{{{\rm{a + b - 1}}}}{{{\rm{i - 1}}}}\)
2 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{{\rm{a + b + 1}}}}\)
3 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{\left( {{\rm{a + b - 1}}} \right)}}\)
4 \({\rm{\alpha = }}\frac{{{\rm{a + b + 1}}}}{{{\rm{i - 1}}}}\)
CHXII02:SOLUTIONS

319064 A 0.5 molal aqueous solution of a weak acid (HX) is 20 percent ionised. The lowering in freezing point of this solution is
\(\left( {{{\rm{K}}_{\rm{f}}}{\rm{ = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K/m}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {\rm{water}}} \right)\)

1 0.56 K
2 \({\rm{ - 1}}{\rm{.12}}\,{\rm{K}}\)
3 1.12 K
4 \({\rm{ - 0}}{\rm{.56}}\,{\rm{K}}\)
CHXII02:SOLUTIONS

319065 Assertion :
\(\mathrm{NaCl}\) in water and organic acids in benzene show abnormal molecular mass.
Reason :
Abnormal molecular mass is obtained when the substance in the solution undergoes dissociation or association.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII02:SOLUTIONS

319066 An aqueous solution of a salt \({\rm{M}}{{\rm{X}}_{\rm{2}}}\) at certain temperature has a Van’t Hoff factor of 2. The degree of dissociation for this solution of the salt is :

1 0.67
2 0.33
3 \(0.80\)
4 \(0.50\)
CHXII02:SOLUTIONS

319063 The degree of dissociation \(\left( \alpha \right)\) of weak electrolyte \({{\rm{A}}_{\rm{a}}}{{\rm{B}}_{\rm{b}}}\) is related to Van’t Hoff factor (i) by the expression

1 \({\rm{\alpha = }}\frac{{{\rm{a + b - 1}}}}{{{\rm{i - 1}}}}\)
2 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{{\rm{a + b + 1}}}}\)
3 \({\rm{\alpha = }}\frac{{{\rm{i - 1}}}}{{\left( {{\rm{a + b - 1}}} \right)}}\)
4 \({\rm{\alpha = }}\frac{{{\rm{a + b + 1}}}}{{{\rm{i - 1}}}}\)
CHXII02:SOLUTIONS

319064 A 0.5 molal aqueous solution of a weak acid (HX) is 20 percent ionised. The lowering in freezing point of this solution is
\(\left( {{{\rm{K}}_{\rm{f}}}{\rm{ = 1}}{\rm{.86}}{\mkern 1mu} {\mkern 1mu} {\rm{K/m}}{\mkern 1mu} {\mkern 1mu} {\rm{for}}{\mkern 1mu} {\mkern 1mu} {\rm{water}}} \right)\)

1 0.56 K
2 \({\rm{ - 1}}{\rm{.12}}\,{\rm{K}}\)
3 1.12 K
4 \({\rm{ - 0}}{\rm{.56}}\,{\rm{K}}\)
CHXII02:SOLUTIONS

319065 Assertion :
\(\mathrm{NaCl}\) in water and organic acids in benzene show abnormal molecular mass.
Reason :
Abnormal molecular mass is obtained when the substance in the solution undergoes dissociation or association.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXII02:SOLUTIONS

319066 An aqueous solution of a salt \({\rm{M}}{{\rm{X}}_{\rm{2}}}\) at certain temperature has a Van’t Hoff factor of 2. The degree of dissociation for this solution of the salt is :

1 0.67
2 0.33
3 \(0.80\)
4 \(0.50\)