Alkenes
CHXI13:HYDROCARBONS

318134 Consider the following reactions:
(a) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{3}}}{\text{CCH(OH)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ conc}}{\text{. }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}\)
(b) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ alc}}{\text{. KOH }}}}\)
(c) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)}_{\text{3}}}{{\text{O}}^\Theta }{{\text{K}}^ \oplus }}}\)
(d)
supporting img
Which of these reaction (s) will not produce saytzeff product ?

1 (d) only
2 (c) only
3 (b) and (d)
4 (a), (c) and (d)
CHXI13:HYDROCARBONS

318135 Assertion :
2,3-Dimethylbut-2-ene is more stable than but-2-ene.
Reason :
Six hyperconjugation structures can be written for 2,3-dimcthylbut-2-ene while but-2 -ene has tweleve.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318136 Order of stability of following compounds.
supporting img

1 III \(>\) I \(>\) IV \(>\) II
2 II \(>\) I \(>\) IV \(>\) III
3 II \(>\) IV \(>\) I \(>\) III
4 IV \(>\) III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318137 Number of \({\mathrm{\sigma}}\) and \({\mathrm{\pi}}\) bonds present in ethylene molecule is respectively

1 4 and 1
2 3 and 1
3 5 and 1
4 5 and 2
CHXI13:HYDROCARBONS

318134 Consider the following reactions:
(a) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{3}}}{\text{CCH(OH)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ conc}}{\text{. }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}\)
(b) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ alc}}{\text{. KOH }}}}\)
(c) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)}_{\text{3}}}{{\text{O}}^\Theta }{{\text{K}}^ \oplus }}}\)
(d)
supporting img
Which of these reaction (s) will not produce saytzeff product ?

1 (d) only
2 (c) only
3 (b) and (d)
4 (a), (c) and (d)
CHXI13:HYDROCARBONS

318135 Assertion :
2,3-Dimethylbut-2-ene is more stable than but-2-ene.
Reason :
Six hyperconjugation structures can be written for 2,3-dimcthylbut-2-ene while but-2 -ene has tweleve.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318136 Order of stability of following compounds.
supporting img

1 III \(>\) I \(>\) IV \(>\) II
2 II \(>\) I \(>\) IV \(>\) III
3 II \(>\) IV \(>\) I \(>\) III
4 IV \(>\) III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318137 Number of \({\mathrm{\sigma}}\) and \({\mathrm{\pi}}\) bonds present in ethylene molecule is respectively

1 4 and 1
2 3 and 1
3 5 and 1
4 5 and 2
CHXI13:HYDROCARBONS

318134 Consider the following reactions:
(a) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{3}}}{\text{CCH(OH)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ conc}}{\text{. }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}\)
(b) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ alc}}{\text{. KOH }}}}\)
(c) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)}_{\text{3}}}{{\text{O}}^\Theta }{{\text{K}}^ \oplus }}}\)
(d)
supporting img
Which of these reaction (s) will not produce saytzeff product ?

1 (d) only
2 (c) only
3 (b) and (d)
4 (a), (c) and (d)
CHXI13:HYDROCARBONS

318135 Assertion :
2,3-Dimethylbut-2-ene is more stable than but-2-ene.
Reason :
Six hyperconjugation structures can be written for 2,3-dimcthylbut-2-ene while but-2 -ene has tweleve.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318136 Order of stability of following compounds.
supporting img

1 III \(>\) I \(>\) IV \(>\) II
2 II \(>\) I \(>\) IV \(>\) III
3 II \(>\) IV \(>\) I \(>\) III
4 IV \(>\) III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318137 Number of \({\mathrm{\sigma}}\) and \({\mathrm{\pi}}\) bonds present in ethylene molecule is respectively

1 4 and 1
2 3 and 1
3 5 and 1
4 5 and 2
CHXI13:HYDROCARBONS

318134 Consider the following reactions:
(a) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{3}}}{\text{CCH(OH)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ conc}}{\text{. }}{{\text{H}}_{\text{2}}}{\text{S}}{{\text{O}}_{\text{4}}}}}\)
(b) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{\text{ alc}}{\text{. KOH }}}}\)
(c) \({\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)_{\text{2}}}{\text{CHCH(Br)C}}{{\text{H}}_{\text{3}}}\xrightarrow{{{{\left( {{\text{C}}{{\text{H}}_{\text{3}}}} \right)}_{\text{3}}}{{\text{O}}^\Theta }{{\text{K}}^ \oplus }}}\)
(d)
supporting img
Which of these reaction (s) will not produce saytzeff product ?

1 (d) only
2 (c) only
3 (b) and (d)
4 (a), (c) and (d)
CHXI13:HYDROCARBONS

318135 Assertion :
2,3-Dimethylbut-2-ene is more stable than but-2-ene.
Reason :
Six hyperconjugation structures can be written for 2,3-dimcthylbut-2-ene while but-2 -ene has tweleve.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI13:HYDROCARBONS

318136 Order of stability of following compounds.
supporting img

1 III \(>\) I \(>\) IV \(>\) II
2 II \(>\) I \(>\) IV \(>\) III
3 II \(>\) IV \(>\) I \(>\) III
4 IV \(>\) III \(>\) II \(>\) I
CHXI13:HYDROCARBONS

318137 Number of \({\mathrm{\sigma}}\) and \({\mathrm{\pi}}\) bonds present in ethylene molecule is respectively

1 4 and 1
2 3 and 1
3 5 and 1
4 5 and 2