All nitrides react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) to give \({\rm{N}}{{\rm{H}}_{\rm{3}}}\) and \({\rm{CaC}}{{\rm{N}}_{\rm{2}}}\) also react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) \({\rm{CaNCN + 3}}{{\rm{H}}_{\rm{2}}}{\rm{O}} \to {\rm{CaC}}{{\rm{O}}_{\rm{3}}}{\rm{ + N}}{{\rm{H}}_{\rm{3}}}\)
CHXI11:THE P-BLOCK ELEMENTS
316706
Assertion : \(\mathrm{AgCl}\) is more soluble in \(\mathrm{NH}_{3}\) than in water. Reason : Ammonia is more polar than water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Solubility of \(\mathrm{AgCl}\left(\right.\) at \(25^{\circ} \mathrm{C}\) ) in \(\mathrm{H}_{2} \mathrm{O}\) \(=0.0020 \mathrm{~g}\) of \(\mathrm{AgCl}\) per litre of \(\mathrm{H}_{2} \mathrm{O}\) Solubility of \(\mathrm{AgCl}\) in \(\mathrm{NH}_{3}\) (at \(25^{\circ} \mathrm{C}\) ) \({\text{ = 14}}{\text{.00 g AgCl}}\) dissolved per \(\mathrm{kg}\) of \(\mathrm{NH}_{3}\) Solubility of \(\mathrm{AgCl}\) is more in \(\mathrm{NH}_{3}\) due to formation of soluble stable complex \(\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\).Ammonia is less polar than water, as oxygen is more electronegative than nitrogen. So option (3) is correct.
CHXI11:THE P-BLOCK ELEMENTS
316707
Ammonia, on reaction with excess of chlorine, gives
1 \(\mathrm{NCl}_{3}\) and \(\mathrm{HCl}\)
2 \(\mathrm{N}_{4}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{NCl}_{3}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
316708
\(\mathrm{NH}_{3}\) produces dark blue solution when reacts with \(\mathrm{CuSO}_{4}\) solution, if \(\mathrm{PH}_{3}\) is used in place of \(\mathrm{NH}_{3}\), then
All nitrides react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) to give \({\rm{N}}{{\rm{H}}_{\rm{3}}}\) and \({\rm{CaC}}{{\rm{N}}_{\rm{2}}}\) also react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) \({\rm{CaNCN + 3}}{{\rm{H}}_{\rm{2}}}{\rm{O}} \to {\rm{CaC}}{{\rm{O}}_{\rm{3}}}{\rm{ + N}}{{\rm{H}}_{\rm{3}}}\)
CHXI11:THE P-BLOCK ELEMENTS
316706
Assertion : \(\mathrm{AgCl}\) is more soluble in \(\mathrm{NH}_{3}\) than in water. Reason : Ammonia is more polar than water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Solubility of \(\mathrm{AgCl}\left(\right.\) at \(25^{\circ} \mathrm{C}\) ) in \(\mathrm{H}_{2} \mathrm{O}\) \(=0.0020 \mathrm{~g}\) of \(\mathrm{AgCl}\) per litre of \(\mathrm{H}_{2} \mathrm{O}\) Solubility of \(\mathrm{AgCl}\) in \(\mathrm{NH}_{3}\) (at \(25^{\circ} \mathrm{C}\) ) \({\text{ = 14}}{\text{.00 g AgCl}}\) dissolved per \(\mathrm{kg}\) of \(\mathrm{NH}_{3}\) Solubility of \(\mathrm{AgCl}\) is more in \(\mathrm{NH}_{3}\) due to formation of soluble stable complex \(\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\).Ammonia is less polar than water, as oxygen is more electronegative than nitrogen. So option (3) is correct.
CHXI11:THE P-BLOCK ELEMENTS
316707
Ammonia, on reaction with excess of chlorine, gives
1 \(\mathrm{NCl}_{3}\) and \(\mathrm{HCl}\)
2 \(\mathrm{N}_{4}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{NCl}_{3}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
316708
\(\mathrm{NH}_{3}\) produces dark blue solution when reacts with \(\mathrm{CuSO}_{4}\) solution, if \(\mathrm{PH}_{3}\) is used in place of \(\mathrm{NH}_{3}\), then
All nitrides react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) to give \({\rm{N}}{{\rm{H}}_{\rm{3}}}\) and \({\rm{CaC}}{{\rm{N}}_{\rm{2}}}\) also react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) \({\rm{CaNCN + 3}}{{\rm{H}}_{\rm{2}}}{\rm{O}} \to {\rm{CaC}}{{\rm{O}}_{\rm{3}}}{\rm{ + N}}{{\rm{H}}_{\rm{3}}}\)
CHXI11:THE P-BLOCK ELEMENTS
316706
Assertion : \(\mathrm{AgCl}\) is more soluble in \(\mathrm{NH}_{3}\) than in water. Reason : Ammonia is more polar than water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Solubility of \(\mathrm{AgCl}\left(\right.\) at \(25^{\circ} \mathrm{C}\) ) in \(\mathrm{H}_{2} \mathrm{O}\) \(=0.0020 \mathrm{~g}\) of \(\mathrm{AgCl}\) per litre of \(\mathrm{H}_{2} \mathrm{O}\) Solubility of \(\mathrm{AgCl}\) in \(\mathrm{NH}_{3}\) (at \(25^{\circ} \mathrm{C}\) ) \({\text{ = 14}}{\text{.00 g AgCl}}\) dissolved per \(\mathrm{kg}\) of \(\mathrm{NH}_{3}\) Solubility of \(\mathrm{AgCl}\) is more in \(\mathrm{NH}_{3}\) due to formation of soluble stable complex \(\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\).Ammonia is less polar than water, as oxygen is more electronegative than nitrogen. So option (3) is correct.
CHXI11:THE P-BLOCK ELEMENTS
316707
Ammonia, on reaction with excess of chlorine, gives
1 \(\mathrm{NCl}_{3}\) and \(\mathrm{HCl}\)
2 \(\mathrm{N}_{4}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{NCl}_{3}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
316708
\(\mathrm{NH}_{3}\) produces dark blue solution when reacts with \(\mathrm{CuSO}_{4}\) solution, if \(\mathrm{PH}_{3}\) is used in place of \(\mathrm{NH}_{3}\), then
All nitrides react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) to give \({\rm{N}}{{\rm{H}}_{\rm{3}}}\) and \({\rm{CaC}}{{\rm{N}}_{\rm{2}}}\) also react with \({{\rm{H}}_{\rm{2}}}{\rm{O}}\) \({\rm{CaNCN + 3}}{{\rm{H}}_{\rm{2}}}{\rm{O}} \to {\rm{CaC}}{{\rm{O}}_{\rm{3}}}{\rm{ + N}}{{\rm{H}}_{\rm{3}}}\)
CHXI11:THE P-BLOCK ELEMENTS
316706
Assertion : \(\mathrm{AgCl}\) is more soluble in \(\mathrm{NH}_{3}\) than in water. Reason : Ammonia is more polar than water.
1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
Explanation:
Solubility of \(\mathrm{AgCl}\left(\right.\) at \(25^{\circ} \mathrm{C}\) ) in \(\mathrm{H}_{2} \mathrm{O}\) \(=0.0020 \mathrm{~g}\) of \(\mathrm{AgCl}\) per litre of \(\mathrm{H}_{2} \mathrm{O}\) Solubility of \(\mathrm{AgCl}\) in \(\mathrm{NH}_{3}\) (at \(25^{\circ} \mathrm{C}\) ) \({\text{ = 14}}{\text{.00 g AgCl}}\) dissolved per \(\mathrm{kg}\) of \(\mathrm{NH}_{3}\) Solubility of \(\mathrm{AgCl}\) is more in \(\mathrm{NH}_{3}\) due to formation of soluble stable complex \(\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\).Ammonia is less polar than water, as oxygen is more electronegative than nitrogen. So option (3) is correct.
CHXI11:THE P-BLOCK ELEMENTS
316707
Ammonia, on reaction with excess of chlorine, gives
1 \(\mathrm{NCl}_{3}\) and \(\mathrm{HCl}\)
2 \(\mathrm{N}_{4}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
3 \(\mathrm{NCl}_{3}\) and \(\mathrm{NH}_{4} \mathrm{Cl}\)
316708
\(\mathrm{NH}_{3}\) produces dark blue solution when reacts with \(\mathrm{CuSO}_{4}\) solution, if \(\mathrm{PH}_{3}\) is used in place of \(\mathrm{NH}_{3}\), then
