Chemical Properties and General Characteristics of Group – 13 Elements
CHXI11:THE P-BLOCK ELEMENTS

316299 The difference in properties of \(\mathrm{CH}_{4}\) and \(\mathrm{SiH}_{4}\) is due to

1 large difference in the electronegativity of carbon and silicon
2 large difference in size of \(\mathrm{C}\) and \(\mathrm{Si}\) atoms
3 the inability of carbon to expand its octet
4 the inability of silicon to form double bonds
CHXI11:THE P-BLOCK ELEMENTS

316300 Which of the following occurs as a consequence of inert pair effect?
(A) \(\mathrm{SnCl}_{2}\) acts as a reducing agent
(B) \(\mathrm{SnCl}_{4}\) acts as an oxidising agent
(C) \(\mathrm{SnO}_{2}\) is amphoteric
(D) \(\mathrm{PbO}_{2}\) is an oxidant
(E) \(\mathrm{CCl}_{2}\) is unstable but \(\mathrm{PbCl}_{2}\) is stable

1 A, D, E
2 D, E, C
3 A, B, C, D, E
4 A, B, C
CHXI11:THE P-BLOCK ELEMENTS

316301 Given below are two statements one is labelled as (A) and the other is labelled as Reason \({\rm{(R)}}\).
Assertion :
All MX \({ }_{4}\) of 14th group except \(\mathrm{CX}_{4}\), are easily hydrolyzed by water.
Reason :
In cases other than carbon, the central atom of \(\mathrm{MX}_{4}\) has d-subshell to
accommodate lone pair of electrons from O atom of \(\mathrm{H}_{2} \mathrm{O}\).

In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Assertion and Reason are true and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are true but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and is reason incorrect.
CHXI11:THE P-BLOCK ELEMENTS

316302 Which of the following species is not stable?

1 \(\left[\mathrm{SiF}_{6}\right]^{2-}\)
2 \(\left[\mathrm{GeCl}_{6}\right]^{2-}\)
3 \(\left[\mathrm{Sn}(\mathrm{OH})_{6}\right]^{2-}\)
4 \(\left[\mathrm{SiCl}_{6}\right]^{2-}\)
CHXI11:THE P-BLOCK ELEMENTS

316299 The difference in properties of \(\mathrm{CH}_{4}\) and \(\mathrm{SiH}_{4}\) is due to

1 large difference in the electronegativity of carbon and silicon
2 large difference in size of \(\mathrm{C}\) and \(\mathrm{Si}\) atoms
3 the inability of carbon to expand its octet
4 the inability of silicon to form double bonds
CHXI11:THE P-BLOCK ELEMENTS

316300 Which of the following occurs as a consequence of inert pair effect?
(A) \(\mathrm{SnCl}_{2}\) acts as a reducing agent
(B) \(\mathrm{SnCl}_{4}\) acts as an oxidising agent
(C) \(\mathrm{SnO}_{2}\) is amphoteric
(D) \(\mathrm{PbO}_{2}\) is an oxidant
(E) \(\mathrm{CCl}_{2}\) is unstable but \(\mathrm{PbCl}_{2}\) is stable

1 A, D, E
2 D, E, C
3 A, B, C, D, E
4 A, B, C
CHXI11:THE P-BLOCK ELEMENTS

316301 Given below are two statements one is labelled as (A) and the other is labelled as Reason \({\rm{(R)}}\).
Assertion :
All MX \({ }_{4}\) of 14th group except \(\mathrm{CX}_{4}\), are easily hydrolyzed by water.
Reason :
In cases other than carbon, the central atom of \(\mathrm{MX}_{4}\) has d-subshell to
accommodate lone pair of electrons from O atom of \(\mathrm{H}_{2} \mathrm{O}\).

In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Assertion and Reason are true and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are true but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and is reason incorrect.
CHXI11:THE P-BLOCK ELEMENTS

316302 Which of the following species is not stable?

1 \(\left[\mathrm{SiF}_{6}\right]^{2-}\)
2 \(\left[\mathrm{GeCl}_{6}\right]^{2-}\)
3 \(\left[\mathrm{Sn}(\mathrm{OH})_{6}\right]^{2-}\)
4 \(\left[\mathrm{SiCl}_{6}\right]^{2-}\)
CHXI11:THE P-BLOCK ELEMENTS

316299 The difference in properties of \(\mathrm{CH}_{4}\) and \(\mathrm{SiH}_{4}\) is due to

1 large difference in the electronegativity of carbon and silicon
2 large difference in size of \(\mathrm{C}\) and \(\mathrm{Si}\) atoms
3 the inability of carbon to expand its octet
4 the inability of silicon to form double bonds
CHXI11:THE P-BLOCK ELEMENTS

316300 Which of the following occurs as a consequence of inert pair effect?
(A) \(\mathrm{SnCl}_{2}\) acts as a reducing agent
(B) \(\mathrm{SnCl}_{4}\) acts as an oxidising agent
(C) \(\mathrm{SnO}_{2}\) is amphoteric
(D) \(\mathrm{PbO}_{2}\) is an oxidant
(E) \(\mathrm{CCl}_{2}\) is unstable but \(\mathrm{PbCl}_{2}\) is stable

1 A, D, E
2 D, E, C
3 A, B, C, D, E
4 A, B, C
CHXI11:THE P-BLOCK ELEMENTS

316301 Given below are two statements one is labelled as (A) and the other is labelled as Reason \({\rm{(R)}}\).
Assertion :
All MX \({ }_{4}\) of 14th group except \(\mathrm{CX}_{4}\), are easily hydrolyzed by water.
Reason :
In cases other than carbon, the central atom of \(\mathrm{MX}_{4}\) has d-subshell to
accommodate lone pair of electrons from O atom of \(\mathrm{H}_{2} \mathrm{O}\).

In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Assertion and Reason are true and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are true but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and is reason incorrect.
CHXI11:THE P-BLOCK ELEMENTS

316302 Which of the following species is not stable?

1 \(\left[\mathrm{SiF}_{6}\right]^{2-}\)
2 \(\left[\mathrm{GeCl}_{6}\right]^{2-}\)
3 \(\left[\mathrm{Sn}(\mathrm{OH})_{6}\right]^{2-}\)
4 \(\left[\mathrm{SiCl}_{6}\right]^{2-}\)
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CHXI11:THE P-BLOCK ELEMENTS

316299 The difference in properties of \(\mathrm{CH}_{4}\) and \(\mathrm{SiH}_{4}\) is due to

1 large difference in the electronegativity of carbon and silicon
2 large difference in size of \(\mathrm{C}\) and \(\mathrm{Si}\) atoms
3 the inability of carbon to expand its octet
4 the inability of silicon to form double bonds
CHXI11:THE P-BLOCK ELEMENTS

316300 Which of the following occurs as a consequence of inert pair effect?
(A) \(\mathrm{SnCl}_{2}\) acts as a reducing agent
(B) \(\mathrm{SnCl}_{4}\) acts as an oxidising agent
(C) \(\mathrm{SnO}_{2}\) is amphoteric
(D) \(\mathrm{PbO}_{2}\) is an oxidant
(E) \(\mathrm{CCl}_{2}\) is unstable but \(\mathrm{PbCl}_{2}\) is stable

1 A, D, E
2 D, E, C
3 A, B, C, D, E
4 A, B, C
CHXI11:THE P-BLOCK ELEMENTS

316301 Given below are two statements one is labelled as (A) and the other is labelled as Reason \({\rm{(R)}}\).
Assertion :
All MX \({ }_{4}\) of 14th group except \(\mathrm{CX}_{4}\), are easily hydrolyzed by water.
Reason :
In cases other than carbon, the central atom of \(\mathrm{MX}_{4}\) has d-subshell to
accommodate lone pair of electrons from O atom of \(\mathrm{H}_{2} \mathrm{O}\).

In the light of the above statements, choose the most appropriate answer from the options given below:

1 Both Assertion and Reason are true and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are true but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Both Assertion and is reason incorrect.
CHXI11:THE P-BLOCK ELEMENTS

316302 Which of the following species is not stable?

1 \(\left[\mathrm{SiF}_{6}\right]^{2-}\)
2 \(\left[\mathrm{GeCl}_{6}\right]^{2-}\)
3 \(\left[\mathrm{Sn}(\mathrm{OH})_{6}\right]^{2-}\)
4 \(\left[\mathrm{SiCl}_{6}\right]^{2-}\)