Chemical Properties and General Characteristics of Group – 13 Elements
CHXI11:THE P-BLOCK ELEMENTS

316294 Thiosulphate reacts differently with iodine and bromine in the reactions given below:
\({\mathrm{2 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{I}_{2} \rightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2-}+2 \mathrm{I}^{-}}}\)
\({\mathrm{\mathrm{S}_{2} \mathrm{O}_{3}^{2-}+5 \mathrm{Br}_{2}+5 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{SO}_{4}^{2-}+10 \mathrm{Br}^{-}+10 \mathrm{H}^{+}}}\)
Which of the following statement justifies the above dual behaviour of thiosulphate?

1 Bromine is a weaker oxidant than iodine.
2 Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
3 Bromine undergoes oxidation and iodine undergoes reduction in these reactions.
4 Bromine is a stronger oxidant than iodine.
CHXI11:THE P-BLOCK ELEMENTS

316295 Assertion :
\(\mathrm{F}_{2}\) has high reactivity.
Reason :
\({\rm{F}} - {\rm{F}}\) bond has low bond dissociation enthalpy.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316296 Assertion :
Trisilylamine is a relatively stronger base compared with trimethylamine.
Reason :
In trisilylamine, \(\mathrm{N}\) atom is \({\text{s}}{{\text{p}}^{\text{2}}}\) - hybridized and lone pair on \(\mathrm{N}\) is involved in back \(\pi\) bonding

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316297 The reducing character of hydrides of group 14 elements is :

1 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{PbH}_{4}\)
2 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{SnH}_{4}\)
3 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{SiH}_{4}\)
4 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{CH}_{4}\)
CHXI11:THE P-BLOCK ELEMENTS

316298 Hydrides of germanium are called ____

1 Stannane
2 Plumbane
3 Germanes
4 Silane
CHXI11:THE P-BLOCK ELEMENTS

316294 Thiosulphate reacts differently with iodine and bromine in the reactions given below:
\({\mathrm{2 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{I}_{2} \rightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2-}+2 \mathrm{I}^{-}}}\)
\({\mathrm{\mathrm{S}_{2} \mathrm{O}_{3}^{2-}+5 \mathrm{Br}_{2}+5 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{SO}_{4}^{2-}+10 \mathrm{Br}^{-}+10 \mathrm{H}^{+}}}\)
Which of the following statement justifies the above dual behaviour of thiosulphate?

1 Bromine is a weaker oxidant than iodine.
2 Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
3 Bromine undergoes oxidation and iodine undergoes reduction in these reactions.
4 Bromine is a stronger oxidant than iodine.
CHXI11:THE P-BLOCK ELEMENTS

316295 Assertion :
\(\mathrm{F}_{2}\) has high reactivity.
Reason :
\({\rm{F}} - {\rm{F}}\) bond has low bond dissociation enthalpy.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316296 Assertion :
Trisilylamine is a relatively stronger base compared with trimethylamine.
Reason :
In trisilylamine, \(\mathrm{N}\) atom is \({\text{s}}{{\text{p}}^{\text{2}}}\) - hybridized and lone pair on \(\mathrm{N}\) is involved in back \(\pi\) bonding

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316297 The reducing character of hydrides of group 14 elements is :

1 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{PbH}_{4}\)
2 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{SnH}_{4}\)
3 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{SiH}_{4}\)
4 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{CH}_{4}\)
CHXI11:THE P-BLOCK ELEMENTS

316298 Hydrides of germanium are called ____

1 Stannane
2 Plumbane
3 Germanes
4 Silane
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CHXI11:THE P-BLOCK ELEMENTS

316294 Thiosulphate reacts differently with iodine and bromine in the reactions given below:
\({\mathrm{2 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{I}_{2} \rightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2-}+2 \mathrm{I}^{-}}}\)
\({\mathrm{\mathrm{S}_{2} \mathrm{O}_{3}^{2-}+5 \mathrm{Br}_{2}+5 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{SO}_{4}^{2-}+10 \mathrm{Br}^{-}+10 \mathrm{H}^{+}}}\)
Which of the following statement justifies the above dual behaviour of thiosulphate?

1 Bromine is a weaker oxidant than iodine.
2 Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
3 Bromine undergoes oxidation and iodine undergoes reduction in these reactions.
4 Bromine is a stronger oxidant than iodine.
CHXI11:THE P-BLOCK ELEMENTS

316295 Assertion :
\(\mathrm{F}_{2}\) has high reactivity.
Reason :
\({\rm{F}} - {\rm{F}}\) bond has low bond dissociation enthalpy.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316296 Assertion :
Trisilylamine is a relatively stronger base compared with trimethylamine.
Reason :
In trisilylamine, \(\mathrm{N}\) atom is \({\text{s}}{{\text{p}}^{\text{2}}}\) - hybridized and lone pair on \(\mathrm{N}\) is involved in back \(\pi\) bonding

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316297 The reducing character of hydrides of group 14 elements is :

1 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{PbH}_{4}\)
2 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{SnH}_{4}\)
3 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{SiH}_{4}\)
4 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{CH}_{4}\)
CHXI11:THE P-BLOCK ELEMENTS

316298 Hydrides of germanium are called ____

1 Stannane
2 Plumbane
3 Germanes
4 Silane
CHXI11:THE P-BLOCK ELEMENTS

316294 Thiosulphate reacts differently with iodine and bromine in the reactions given below:
\({\mathrm{2 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{I}_{2} \rightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2-}+2 \mathrm{I}^{-}}}\)
\({\mathrm{\mathrm{S}_{2} \mathrm{O}_{3}^{2-}+5 \mathrm{Br}_{2}+5 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{SO}_{4}^{2-}+10 \mathrm{Br}^{-}+10 \mathrm{H}^{+}}}\)
Which of the following statement justifies the above dual behaviour of thiosulphate?

1 Bromine is a weaker oxidant than iodine.
2 Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
3 Bromine undergoes oxidation and iodine undergoes reduction in these reactions.
4 Bromine is a stronger oxidant than iodine.
CHXI11:THE P-BLOCK ELEMENTS

316295 Assertion :
\(\mathrm{F}_{2}\) has high reactivity.
Reason :
\({\rm{F}} - {\rm{F}}\) bond has low bond dissociation enthalpy.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316296 Assertion :
Trisilylamine is a relatively stronger base compared with trimethylamine.
Reason :
In trisilylamine, \(\mathrm{N}\) atom is \({\text{s}}{{\text{p}}^{\text{2}}}\) - hybridized and lone pair on \(\mathrm{N}\) is involved in back \(\pi\) bonding

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316297 The reducing character of hydrides of group 14 elements is :

1 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{PbH}_{4}\)
2 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{SnH}_{4}\)
3 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{SiH}_{4}\)
4 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{CH}_{4}\)
CHXI11:THE P-BLOCK ELEMENTS

316298 Hydrides of germanium are called ____

1 Stannane
2 Plumbane
3 Germanes
4 Silane
CHXI11:THE P-BLOCK ELEMENTS

316294 Thiosulphate reacts differently with iodine and bromine in the reactions given below:
\({\mathrm{2 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{I}_{2} \rightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2-}+2 \mathrm{I}^{-}}}\)
\({\mathrm{\mathrm{S}_{2} \mathrm{O}_{3}^{2-}+5 \mathrm{Br}_{2}+5 \mathrm{H}_{2} \mathrm{O} \rightarrow 2 \mathrm{SO}_{4}^{2-}+10 \mathrm{Br}^{-}+10 \mathrm{H}^{+}}}\)
Which of the following statement justifies the above dual behaviour of thiosulphate?

1 Bromine is a weaker oxidant than iodine.
2 Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
3 Bromine undergoes oxidation and iodine undergoes reduction in these reactions.
4 Bromine is a stronger oxidant than iodine.
CHXI11:THE P-BLOCK ELEMENTS

316295 Assertion :
\(\mathrm{F}_{2}\) has high reactivity.
Reason :
\({\rm{F}} - {\rm{F}}\) bond has low bond dissociation enthalpy.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316296 Assertion :
Trisilylamine is a relatively stronger base compared with trimethylamine.
Reason :
In trisilylamine, \(\mathrm{N}\) atom is \({\text{s}}{{\text{p}}^{\text{2}}}\) - hybridized and lone pair on \(\mathrm{N}\) is involved in back \(\pi\) bonding

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but reason is correct.
CHXI11:THE P-BLOCK ELEMENTS

316297 The reducing character of hydrides of group 14 elements is :

1 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{PbH}_{4}\)
2 Maximum for \(\mathrm{CH}_{4}\) and minimum for \(\mathrm{SnH}_{4}\)
3 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{SiH}_{4}\)
4 Maximum for \(\mathrm{PbH}_{4}\) and minimum for \(\mathrm{CH}_{4}\)
CHXI11:THE P-BLOCK ELEMENTS

316298 Hydrides of germanium are called ____

1 Stannane
2 Plumbane
3 Germanes
4 Silane