Redox Reactions and Electrode Processes
CHXI08:REDOX REACTIONS

315395 The more positive the value of \(\mathrm{E^{\circ}}\), the greater is the tendency of the species to get reduced. Using the standard electrode potential of redox couples given below find out which of the following is the strongest oxidising agent.
\(\mathrm{E^{\Theta}}\) values: \(\mathrm{\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}=+0.77 ; I_{2}(s) / I^{-}=+0.54}\);
\(\mathrm{\mathrm{Cu}^{2+} / \mathrm{Cu}=+0.34 ; \mathrm{Ag}^{+} / \mathrm{Ag}=+0.80 \mathrm{~V}}\)

1 \(\mathrm{\mathrm{Fe}^{3+}}\)
2 \(\mathrm{I_{2}(s)}\)
3 \(\mathrm{\mathrm{Cu}^{2+}}\)
4 \(\mathrm{\mathrm{Ag}^{+}}\)
CHXI08:REDOX REACTIONS

315396 (I) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{O}_{3} \rightarrow \mathrm{H}_{2} \mathrm{O}+2 \mathrm{O}_{2}\)
(II) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{Ag}_{2} \mathrm{O} \rightarrow 2 \mathrm{Ag}+\mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\)
Role of hydrogen peroxide in the above reactions is, respectively

1 Oxidizing agent in (I) and reducing agent in (II)
2 Reducing agent in (I) and oxidizing agent in (II)
3 Reducing agent in (I) and (II)
4 Oxidizing agent in (I) and (II)
CHXI08:REDOX REACTIONS

315397 Statement A :
A negative value of \(\mathrm{E^{\circ}}\) means that the redox couple is weaker reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\) couple.
Statement B :
A negative \(\mathrm{\mathrm{E}^{\circ}}\) means that the redox couple is stronger reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\).

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI08:REDOX REACTIONS

315398 Standard reduction electrode potentials of three metals A, B and C are \(\mathrm{+0.5 \mathrm{~V},-3.0 \mathrm{~V}}\) and \({\rm{ - 1}}{\rm{.2 }}\) \(\mathrm{\mathrm{V}}\). The reducing powers are in the order

1 \(A{\rm{ }} > B{\rm{ }} > C\)
2 \(\mathrm{\mathrm{C}>\mathrm{B}>\mathrm{A}}\)
3 \(\mathrm{\mathrm{A}>\mathrm{C}>\mathrm{B}}\)
4 \(\mathrm{\mathrm{B}>\mathrm{C}>\mathrm{A}}\)
CHXI08:REDOX REACTIONS

315395 The more positive the value of \(\mathrm{E^{\circ}}\), the greater is the tendency of the species to get reduced. Using the standard electrode potential of redox couples given below find out which of the following is the strongest oxidising agent.
\(\mathrm{E^{\Theta}}\) values: \(\mathrm{\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}=+0.77 ; I_{2}(s) / I^{-}=+0.54}\);
\(\mathrm{\mathrm{Cu}^{2+} / \mathrm{Cu}=+0.34 ; \mathrm{Ag}^{+} / \mathrm{Ag}=+0.80 \mathrm{~V}}\)

1 \(\mathrm{\mathrm{Fe}^{3+}}\)
2 \(\mathrm{I_{2}(s)}\)
3 \(\mathrm{\mathrm{Cu}^{2+}}\)
4 \(\mathrm{\mathrm{Ag}^{+}}\)
CHXI08:REDOX REACTIONS

315396 (I) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{O}_{3} \rightarrow \mathrm{H}_{2} \mathrm{O}+2 \mathrm{O}_{2}\)
(II) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{Ag}_{2} \mathrm{O} \rightarrow 2 \mathrm{Ag}+\mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\)
Role of hydrogen peroxide in the above reactions is, respectively

1 Oxidizing agent in (I) and reducing agent in (II)
2 Reducing agent in (I) and oxidizing agent in (II)
3 Reducing agent in (I) and (II)
4 Oxidizing agent in (I) and (II)
CHXI08:REDOX REACTIONS

315397 Statement A :
A negative value of \(\mathrm{E^{\circ}}\) means that the redox couple is weaker reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\) couple.
Statement B :
A negative \(\mathrm{\mathrm{E}^{\circ}}\) means that the redox couple is stronger reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\).

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI08:REDOX REACTIONS

315398 Standard reduction electrode potentials of three metals A, B and C are \(\mathrm{+0.5 \mathrm{~V},-3.0 \mathrm{~V}}\) and \({\rm{ - 1}}{\rm{.2 }}\) \(\mathrm{\mathrm{V}}\). The reducing powers are in the order

1 \(A{\rm{ }} > B{\rm{ }} > C\)
2 \(\mathrm{\mathrm{C}>\mathrm{B}>\mathrm{A}}\)
3 \(\mathrm{\mathrm{A}>\mathrm{C}>\mathrm{B}}\)
4 \(\mathrm{\mathrm{B}>\mathrm{C}>\mathrm{A}}\)
CHXI08:REDOX REACTIONS

315395 The more positive the value of \(\mathrm{E^{\circ}}\), the greater is the tendency of the species to get reduced. Using the standard electrode potential of redox couples given below find out which of the following is the strongest oxidising agent.
\(\mathrm{E^{\Theta}}\) values: \(\mathrm{\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}=+0.77 ; I_{2}(s) / I^{-}=+0.54}\);
\(\mathrm{\mathrm{Cu}^{2+} / \mathrm{Cu}=+0.34 ; \mathrm{Ag}^{+} / \mathrm{Ag}=+0.80 \mathrm{~V}}\)

1 \(\mathrm{\mathrm{Fe}^{3+}}\)
2 \(\mathrm{I_{2}(s)}\)
3 \(\mathrm{\mathrm{Cu}^{2+}}\)
4 \(\mathrm{\mathrm{Ag}^{+}}\)
CHXI08:REDOX REACTIONS

315396 (I) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{O}_{3} \rightarrow \mathrm{H}_{2} \mathrm{O}+2 \mathrm{O}_{2}\)
(II) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{Ag}_{2} \mathrm{O} \rightarrow 2 \mathrm{Ag}+\mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\)
Role of hydrogen peroxide in the above reactions is, respectively

1 Oxidizing agent in (I) and reducing agent in (II)
2 Reducing agent in (I) and oxidizing agent in (II)
3 Reducing agent in (I) and (II)
4 Oxidizing agent in (I) and (II)
CHXI08:REDOX REACTIONS

315397 Statement A :
A negative value of \(\mathrm{E^{\circ}}\) means that the redox couple is weaker reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\) couple.
Statement B :
A negative \(\mathrm{\mathrm{E}^{\circ}}\) means that the redox couple is stronger reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\).

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI08:REDOX REACTIONS

315398 Standard reduction electrode potentials of three metals A, B and C are \(\mathrm{+0.5 \mathrm{~V},-3.0 \mathrm{~V}}\) and \({\rm{ - 1}}{\rm{.2 }}\) \(\mathrm{\mathrm{V}}\). The reducing powers are in the order

1 \(A{\rm{ }} > B{\rm{ }} > C\)
2 \(\mathrm{\mathrm{C}>\mathrm{B}>\mathrm{A}}\)
3 \(\mathrm{\mathrm{A}>\mathrm{C}>\mathrm{B}}\)
4 \(\mathrm{\mathrm{B}>\mathrm{C}>\mathrm{A}}\)
CHXI08:REDOX REACTIONS

315395 The more positive the value of \(\mathrm{E^{\circ}}\), the greater is the tendency of the species to get reduced. Using the standard electrode potential of redox couples given below find out which of the following is the strongest oxidising agent.
\(\mathrm{E^{\Theta}}\) values: \(\mathrm{\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}=+0.77 ; I_{2}(s) / I^{-}=+0.54}\);
\(\mathrm{\mathrm{Cu}^{2+} / \mathrm{Cu}=+0.34 ; \mathrm{Ag}^{+} / \mathrm{Ag}=+0.80 \mathrm{~V}}\)

1 \(\mathrm{\mathrm{Fe}^{3+}}\)
2 \(\mathrm{I_{2}(s)}\)
3 \(\mathrm{\mathrm{Cu}^{2+}}\)
4 \(\mathrm{\mathrm{Ag}^{+}}\)
CHXI08:REDOX REACTIONS

315396 (I) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{O}_{3} \rightarrow \mathrm{H}_{2} \mathrm{O}+2 \mathrm{O}_{2}\)
(II) \(\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{Ag}_{2} \mathrm{O} \rightarrow 2 \mathrm{Ag}+\mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}\)
Role of hydrogen peroxide in the above reactions is, respectively

1 Oxidizing agent in (I) and reducing agent in (II)
2 Reducing agent in (I) and oxidizing agent in (II)
3 Reducing agent in (I) and (II)
4 Oxidizing agent in (I) and (II)
CHXI08:REDOX REACTIONS

315397 Statement A :
A negative value of \(\mathrm{E^{\circ}}\) means that the redox couple is weaker reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\) couple.
Statement B :
A negative \(\mathrm{\mathrm{E}^{\circ}}\) means that the redox couple is stronger reducing agent than the \(\mathrm{\mathrm{H}^{+} / \mathrm{H}_{2}}\).

1 Statement A is correct but Statement B is incorrect.
2 Statement A is incorrect but Statement B is correct.
3 Both statements are correct.
4 Both Statements are incorrect.
CHXI08:REDOX REACTIONS

315398 Standard reduction electrode potentials of three metals A, B and C are \(\mathrm{+0.5 \mathrm{~V},-3.0 \mathrm{~V}}\) and \({\rm{ - 1}}{\rm{.2 }}\) \(\mathrm{\mathrm{V}}\). The reducing powers are in the order

1 \(A{\rm{ }} > B{\rm{ }} > C\)
2 \(\mathrm{\mathrm{C}>\mathrm{B}>\mathrm{A}}\)
3 \(\mathrm{\mathrm{A}>\mathrm{C}>\mathrm{B}}\)
4 \(\mathrm{\mathrm{B}>\mathrm{C}>\mathrm{A}}\)