Solubility Equilibria of Sparingly Soluble Salts
CHXI07:EQUILIBRIUM

314923 How do we differentiate between \(\mathrm{Fe}^{3+}\) and \(\mathrm{Cr}^{3+}\) in group III in salt analysis?

1 By taking excess of \(\mathrm{NH}_{4} \mathrm{OH}\)
2 By increasing \(\mathrm{NH}_{4}^{+}\)ion concentration
3 By decreasing \(\mathrm{OH}^{-}\)ion concentration
4 Both (2) and (3)
CHXI07:EQUILIBRIUM

314924 Assertion :
For gravimetric estimation, silver ion is precipitated as silver chloride.
Reason :
Silver chloride precipitate is white in colour and can easily be formed.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314925 The values of \(\mathrm{K}_{\mathrm{sp}}\) of two sparingly soluble salts \(\mathrm{Ni}(\mathrm{OH})_{2}\) and \(\mathrm{AgCN}\) are \(2.0 \times 10^{-15}\) and \(6 \times 0^{-17}\) respectively. Which salt is more soluble?

1 Can't be predicted
2 \(\mathrm{Ni}(\mathrm{OH})_{2}\)
3 \(\mathrm{AgCN}\)
4 Both are equally soluble
CHXI07:EQUILIBRIUM

314926 One \(\mathrm{dm}^{3}\) solution containing \(10^{-5}\) moles each of \(\mathrm{Cl}^{-}\)ions and \(\mathrm{CrO}_{4}^{2-}\) ions is treated with \(10^{-4}\) moles of silver nitrate. Which one of the following observations is made?
\[\begin{aligned}& {\left[\mathrm{K}_{\mathrm{sp}} \mathrm{Ag}_{2} \mathrm{CrO}_{4}=4 \times 10^{-12}\right],}
{\left[\mathrm{K}_{\mathrm{sp}} \mathrm{AgCl}=1 \times 10^{-10}\right]}\end{aligned}\]

1 Precipitation does not occur.
2 Silver chromate gets precipitated first
3 Silver chloride gets precipitated first
4 Both silver chromate and silver chloride start precipitating simultaneously
CHXI07:EQUILIBRIUM

314923 How do we differentiate between \(\mathrm{Fe}^{3+}\) and \(\mathrm{Cr}^{3+}\) in group III in salt analysis?

1 By taking excess of \(\mathrm{NH}_{4} \mathrm{OH}\)
2 By increasing \(\mathrm{NH}_{4}^{+}\)ion concentration
3 By decreasing \(\mathrm{OH}^{-}\)ion concentration
4 Both (2) and (3)
CHXI07:EQUILIBRIUM

314924 Assertion :
For gravimetric estimation, silver ion is precipitated as silver chloride.
Reason :
Silver chloride precipitate is white in colour and can easily be formed.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314925 The values of \(\mathrm{K}_{\mathrm{sp}}\) of two sparingly soluble salts \(\mathrm{Ni}(\mathrm{OH})_{2}\) and \(\mathrm{AgCN}\) are \(2.0 \times 10^{-15}\) and \(6 \times 0^{-17}\) respectively. Which salt is more soluble?

1 Can't be predicted
2 \(\mathrm{Ni}(\mathrm{OH})_{2}\)
3 \(\mathrm{AgCN}\)
4 Both are equally soluble
CHXI07:EQUILIBRIUM

314926 One \(\mathrm{dm}^{3}\) solution containing \(10^{-5}\) moles each of \(\mathrm{Cl}^{-}\)ions and \(\mathrm{CrO}_{4}^{2-}\) ions is treated with \(10^{-4}\) moles of silver nitrate. Which one of the following observations is made?
\[\begin{aligned}& {\left[\mathrm{K}_{\mathrm{sp}} \mathrm{Ag}_{2} \mathrm{CrO}_{4}=4 \times 10^{-12}\right],}
{\left[\mathrm{K}_{\mathrm{sp}} \mathrm{AgCl}=1 \times 10^{-10}\right]}\end{aligned}\]

1 Precipitation does not occur.
2 Silver chromate gets precipitated first
3 Silver chloride gets precipitated first
4 Both silver chromate and silver chloride start precipitating simultaneously
CHXI07:EQUILIBRIUM

314923 How do we differentiate between \(\mathrm{Fe}^{3+}\) and \(\mathrm{Cr}^{3+}\) in group III in salt analysis?

1 By taking excess of \(\mathrm{NH}_{4} \mathrm{OH}\)
2 By increasing \(\mathrm{NH}_{4}^{+}\)ion concentration
3 By decreasing \(\mathrm{OH}^{-}\)ion concentration
4 Both (2) and (3)
CHXI07:EQUILIBRIUM

314924 Assertion :
For gravimetric estimation, silver ion is precipitated as silver chloride.
Reason :
Silver chloride precipitate is white in colour and can easily be formed.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314925 The values of \(\mathrm{K}_{\mathrm{sp}}\) of two sparingly soluble salts \(\mathrm{Ni}(\mathrm{OH})_{2}\) and \(\mathrm{AgCN}\) are \(2.0 \times 10^{-15}\) and \(6 \times 0^{-17}\) respectively. Which salt is more soluble?

1 Can't be predicted
2 \(\mathrm{Ni}(\mathrm{OH})_{2}\)
3 \(\mathrm{AgCN}\)
4 Both are equally soluble
CHXI07:EQUILIBRIUM

314926 One \(\mathrm{dm}^{3}\) solution containing \(10^{-5}\) moles each of \(\mathrm{Cl}^{-}\)ions and \(\mathrm{CrO}_{4}^{2-}\) ions is treated with \(10^{-4}\) moles of silver nitrate. Which one of the following observations is made?
\[\begin{aligned}& {\left[\mathrm{K}_{\mathrm{sp}} \mathrm{Ag}_{2} \mathrm{CrO}_{4}=4 \times 10^{-12}\right],}
{\left[\mathrm{K}_{\mathrm{sp}} \mathrm{AgCl}=1 \times 10^{-10}\right]}\end{aligned}\]

1 Precipitation does not occur.
2 Silver chromate gets precipitated first
3 Silver chloride gets precipitated first
4 Both silver chromate and silver chloride start precipitating simultaneously
CHXI07:EQUILIBRIUM

314923 How do we differentiate between \(\mathrm{Fe}^{3+}\) and \(\mathrm{Cr}^{3+}\) in group III in salt analysis?

1 By taking excess of \(\mathrm{NH}_{4} \mathrm{OH}\)
2 By increasing \(\mathrm{NH}_{4}^{+}\)ion concentration
3 By decreasing \(\mathrm{OH}^{-}\)ion concentration
4 Both (2) and (3)
CHXI07:EQUILIBRIUM

314924 Assertion :
For gravimetric estimation, silver ion is precipitated as silver chloride.
Reason :
Silver chloride precipitate is white in colour and can easily be formed.

1 Both Assertion and Reason are correct and Reason is the correct explanation of the Assertion.
2 Both Assertion and Reason are correct but Reason is not the correct explanation of the Assertion.
3 Assertion is correct but Reason is incorrect.
4 Assertion is incorrect but Reason is correct.
CHXI07:EQUILIBRIUM

314925 The values of \(\mathrm{K}_{\mathrm{sp}}\) of two sparingly soluble salts \(\mathrm{Ni}(\mathrm{OH})_{2}\) and \(\mathrm{AgCN}\) are \(2.0 \times 10^{-15}\) and \(6 \times 0^{-17}\) respectively. Which salt is more soluble?

1 Can't be predicted
2 \(\mathrm{Ni}(\mathrm{OH})_{2}\)
3 \(\mathrm{AgCN}\)
4 Both are equally soluble
CHXI07:EQUILIBRIUM

314926 One \(\mathrm{dm}^{3}\) solution containing \(10^{-5}\) moles each of \(\mathrm{Cl}^{-}\)ions and \(\mathrm{CrO}_{4}^{2-}\) ions is treated with \(10^{-4}\) moles of silver nitrate. Which one of the following observations is made?
\[\begin{aligned}& {\left[\mathrm{K}_{\mathrm{sp}} \mathrm{Ag}_{2} \mathrm{CrO}_{4}=4 \times 10^{-12}\right],}
{\left[\mathrm{K}_{\mathrm{sp}} \mathrm{AgCl}=1 \times 10^{-10}\right]}\end{aligned}\]

1 Precipitation does not occur.
2 Silver chromate gets precipitated first
3 Silver chloride gets precipitated first
4 Both silver chromate and silver chloride start precipitating simultaneously