Heat of Reaction
NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHXI06:THERMODYNAMICS

369464 Consider the reactions given below. On the basis of these reactions find out which of the algebraic relations given is correct?
(i) \(\mathrm{\mathrm{C}_{(g)}+4 \mathrm{H}_{(\mathrm{g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{x} \mathrm{kJ} \mathrm{mol}^{-1}}\)
(ii) \(\mathrm{\mathrm{C}_{(\text {graphite })}+2 \mathrm{H}_{2(\mathrm{~g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{ykJ} \mathrm{mol}^{-1}}\)

1 \(\mathrm{x=y}\)
2 \(\mathrm{x=2 y}\)
3 \(\mathrm{x>y}\)
4 \(\mathrm{x < y}\)
CHXI06:THERMODYNAMICS

369465 The specific heats of iodine vapours and solid are 0.031 and \({\rm{0}}{\rm{.055}}\,{\rm{Cal/g}}\), respectively. If heat of sublimation of iodine is \({\rm{24}}\,{\rm{Cal/g}}\) at \(\mathrm{200^{\circ} \mathrm{C}}\), what is its value at \(\mathrm{250^{\circ} \mathrm{C}}\) ?

1 \({\rm{22}}{\rm{.8}}\,{\rm{Cal/g}}\)
2 \({\rm{11}}{\rm{.2}}\,{\rm{Cal/g}}\)
3 \({\rm{15}}{\rm{.8}}\,{\rm{Cal/g}}\)
4 \({\rm{24}}{\rm{.4}}\,{\rm{Cal/g}}\)
CHXI06:THERMODYNAMICS

369466 In Harber's process of ammonia manufacture :
\(\rm{\mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(g)} \rightarrow 2 \mathrm{NH}_{3(g)} ; \Delta \mathrm{H}_{25^{\circ} \mathrm{C}}^{o}=-92.2 \mathrm{~kJ}}\)
\(\begin{array}{*{20}{c}}{{\rm{Molecule}}}&{{{\rm{N}}_{{\rm{2(g)}}}}}&{{{\rm{H}}_{{\rm{2(g)}}}}}&{{\rm{N}}{{\rm{H}}_{{\rm{3(g)}}}}}\\{{{\rm{C}}_{\rm{P}}}{\rm{J/}}\left( {{\rm{K}}\,{\rm{mol}}} \right)}&{{\rm{29}}{\rm{.1}}}&{{\rm{28}}{\rm{.8}}}&{{\rm{35}}{\rm{.1}}}\end{array}\)
If \(\mathrm{\mathrm{C}_{\mathrm{p}}}\) is independent of temperature, then reaction at \(\mathrm{100^{\circ} \mathrm{C}}\) as compared to that of \(\mathrm{25^{\circ} \mathrm{C}}\) will be :

1 More endothermic
2 Less endothermic
3 More exothermic
4 Less exothermic
CHXI06:THERMODYNAMICS

369467 If \(\mathrm{38.55 \mathrm{~kJ}}\) of heat is absorbed, when 6.0 of \(\mathrm{\mathrm{O}_{2}}\) react \(\mathrm{C l F}\) according to reaction.
\(\mathrm{2 \mathrm{CIF}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}_{2}(\mathrm{~g})+\mathrm{OF}_{2}(\mathrm{~g})}\)
What is the standard enthalpy of reaction?

1 \(\mathrm{102.8 \mathrm{~kJ}}\)
2 \(\mathrm{49.80 \mathrm{~kJ}}\)
3 \(\mathrm{72.28 \mathrm{~kJ}}\)
4 \(\mathrm{205.6 \mathrm{~kJ}}\)
CHXI06:THERMODYNAMICS

369464 Consider the reactions given below. On the basis of these reactions find out which of the algebraic relations given is correct?
(i) \(\mathrm{\mathrm{C}_{(g)}+4 \mathrm{H}_{(\mathrm{g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{x} \mathrm{kJ} \mathrm{mol}^{-1}}\)
(ii) \(\mathrm{\mathrm{C}_{(\text {graphite })}+2 \mathrm{H}_{2(\mathrm{~g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{ykJ} \mathrm{mol}^{-1}}\)

1 \(\mathrm{x=y}\)
2 \(\mathrm{x=2 y}\)
3 \(\mathrm{x>y}\)
4 \(\mathrm{x < y}\)
CHXI06:THERMODYNAMICS

369465 The specific heats of iodine vapours and solid are 0.031 and \({\rm{0}}{\rm{.055}}\,{\rm{Cal/g}}\), respectively. If heat of sublimation of iodine is \({\rm{24}}\,{\rm{Cal/g}}\) at \(\mathrm{200^{\circ} \mathrm{C}}\), what is its value at \(\mathrm{250^{\circ} \mathrm{C}}\) ?

1 \({\rm{22}}{\rm{.8}}\,{\rm{Cal/g}}\)
2 \({\rm{11}}{\rm{.2}}\,{\rm{Cal/g}}\)
3 \({\rm{15}}{\rm{.8}}\,{\rm{Cal/g}}\)
4 \({\rm{24}}{\rm{.4}}\,{\rm{Cal/g}}\)
CHXI06:THERMODYNAMICS

369466 In Harber's process of ammonia manufacture :
\(\rm{\mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(g)} \rightarrow 2 \mathrm{NH}_{3(g)} ; \Delta \mathrm{H}_{25^{\circ} \mathrm{C}}^{o}=-92.2 \mathrm{~kJ}}\)
\(\begin{array}{*{20}{c}}{{\rm{Molecule}}}&{{{\rm{N}}_{{\rm{2(g)}}}}}&{{{\rm{H}}_{{\rm{2(g)}}}}}&{{\rm{N}}{{\rm{H}}_{{\rm{3(g)}}}}}\\{{{\rm{C}}_{\rm{P}}}{\rm{J/}}\left( {{\rm{K}}\,{\rm{mol}}} \right)}&{{\rm{29}}{\rm{.1}}}&{{\rm{28}}{\rm{.8}}}&{{\rm{35}}{\rm{.1}}}\end{array}\)
If \(\mathrm{\mathrm{C}_{\mathrm{p}}}\) is independent of temperature, then reaction at \(\mathrm{100^{\circ} \mathrm{C}}\) as compared to that of \(\mathrm{25^{\circ} \mathrm{C}}\) will be :

1 More endothermic
2 Less endothermic
3 More exothermic
4 Less exothermic
CHXI06:THERMODYNAMICS

369467 If \(\mathrm{38.55 \mathrm{~kJ}}\) of heat is absorbed, when 6.0 of \(\mathrm{\mathrm{O}_{2}}\) react \(\mathrm{C l F}\) according to reaction.
\(\mathrm{2 \mathrm{CIF}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}_{2}(\mathrm{~g})+\mathrm{OF}_{2}(\mathrm{~g})}\)
What is the standard enthalpy of reaction?

1 \(\mathrm{102.8 \mathrm{~kJ}}\)
2 \(\mathrm{49.80 \mathrm{~kJ}}\)
3 \(\mathrm{72.28 \mathrm{~kJ}}\)
4 \(\mathrm{205.6 \mathrm{~kJ}}\)
CHXI06:THERMODYNAMICS

369464 Consider the reactions given below. On the basis of these reactions find out which of the algebraic relations given is correct?
(i) \(\mathrm{\mathrm{C}_{(g)}+4 \mathrm{H}_{(\mathrm{g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{x} \mathrm{kJ} \mathrm{mol}^{-1}}\)
(ii) \(\mathrm{\mathrm{C}_{(\text {graphite })}+2 \mathrm{H}_{2(\mathrm{~g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{ykJ} \mathrm{mol}^{-1}}\)

1 \(\mathrm{x=y}\)
2 \(\mathrm{x=2 y}\)
3 \(\mathrm{x>y}\)
4 \(\mathrm{x < y}\)
CHXI06:THERMODYNAMICS

369465 The specific heats of iodine vapours and solid are 0.031 and \({\rm{0}}{\rm{.055}}\,{\rm{Cal/g}}\), respectively. If heat of sublimation of iodine is \({\rm{24}}\,{\rm{Cal/g}}\) at \(\mathrm{200^{\circ} \mathrm{C}}\), what is its value at \(\mathrm{250^{\circ} \mathrm{C}}\) ?

1 \({\rm{22}}{\rm{.8}}\,{\rm{Cal/g}}\)
2 \({\rm{11}}{\rm{.2}}\,{\rm{Cal/g}}\)
3 \({\rm{15}}{\rm{.8}}\,{\rm{Cal/g}}\)
4 \({\rm{24}}{\rm{.4}}\,{\rm{Cal/g}}\)
CHXI06:THERMODYNAMICS

369466 In Harber's process of ammonia manufacture :
\(\rm{\mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(g)} \rightarrow 2 \mathrm{NH}_{3(g)} ; \Delta \mathrm{H}_{25^{\circ} \mathrm{C}}^{o}=-92.2 \mathrm{~kJ}}\)
\(\begin{array}{*{20}{c}}{{\rm{Molecule}}}&{{{\rm{N}}_{{\rm{2(g)}}}}}&{{{\rm{H}}_{{\rm{2(g)}}}}}&{{\rm{N}}{{\rm{H}}_{{\rm{3(g)}}}}}\\{{{\rm{C}}_{\rm{P}}}{\rm{J/}}\left( {{\rm{K}}\,{\rm{mol}}} \right)}&{{\rm{29}}{\rm{.1}}}&{{\rm{28}}{\rm{.8}}}&{{\rm{35}}{\rm{.1}}}\end{array}\)
If \(\mathrm{\mathrm{C}_{\mathrm{p}}}\) is independent of temperature, then reaction at \(\mathrm{100^{\circ} \mathrm{C}}\) as compared to that of \(\mathrm{25^{\circ} \mathrm{C}}\) will be :

1 More endothermic
2 Less endothermic
3 More exothermic
4 Less exothermic
CHXI06:THERMODYNAMICS

369467 If \(\mathrm{38.55 \mathrm{~kJ}}\) of heat is absorbed, when 6.0 of \(\mathrm{\mathrm{O}_{2}}\) react \(\mathrm{C l F}\) according to reaction.
\(\mathrm{2 \mathrm{CIF}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}_{2}(\mathrm{~g})+\mathrm{OF}_{2}(\mathrm{~g})}\)
What is the standard enthalpy of reaction?

1 \(\mathrm{102.8 \mathrm{~kJ}}\)
2 \(\mathrm{49.80 \mathrm{~kJ}}\)
3 \(\mathrm{72.28 \mathrm{~kJ}}\)
4 \(\mathrm{205.6 \mathrm{~kJ}}\)
CHXI06:THERMODYNAMICS

369464 Consider the reactions given below. On the basis of these reactions find out which of the algebraic relations given is correct?
(i) \(\mathrm{\mathrm{C}_{(g)}+4 \mathrm{H}_{(\mathrm{g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{x} \mathrm{kJ} \mathrm{mol}^{-1}}\)
(ii) \(\mathrm{\mathrm{C}_{(\text {graphite })}+2 \mathrm{H}_{2(\mathrm{~g})} \rightarrow \mathrm{CH}_{4(\mathrm{~g})} ; \Delta_{\mathrm{r}} \mathrm{H}=\mathrm{ykJ} \mathrm{mol}^{-1}}\)

1 \(\mathrm{x=y}\)
2 \(\mathrm{x=2 y}\)
3 \(\mathrm{x>y}\)
4 \(\mathrm{x < y}\)
CHXI06:THERMODYNAMICS

369465 The specific heats of iodine vapours and solid are 0.031 and \({\rm{0}}{\rm{.055}}\,{\rm{Cal/g}}\), respectively. If heat of sublimation of iodine is \({\rm{24}}\,{\rm{Cal/g}}\) at \(\mathrm{200^{\circ} \mathrm{C}}\), what is its value at \(\mathrm{250^{\circ} \mathrm{C}}\) ?

1 \({\rm{22}}{\rm{.8}}\,{\rm{Cal/g}}\)
2 \({\rm{11}}{\rm{.2}}\,{\rm{Cal/g}}\)
3 \({\rm{15}}{\rm{.8}}\,{\rm{Cal/g}}\)
4 \({\rm{24}}{\rm{.4}}\,{\rm{Cal/g}}\)
CHXI06:THERMODYNAMICS

369466 In Harber's process of ammonia manufacture :
\(\rm{\mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(g)} \rightarrow 2 \mathrm{NH}_{3(g)} ; \Delta \mathrm{H}_{25^{\circ} \mathrm{C}}^{o}=-92.2 \mathrm{~kJ}}\)
\(\begin{array}{*{20}{c}}{{\rm{Molecule}}}&{{{\rm{N}}_{{\rm{2(g)}}}}}&{{{\rm{H}}_{{\rm{2(g)}}}}}&{{\rm{N}}{{\rm{H}}_{{\rm{3(g)}}}}}\\{{{\rm{C}}_{\rm{P}}}{\rm{J/}}\left( {{\rm{K}}\,{\rm{mol}}} \right)}&{{\rm{29}}{\rm{.1}}}&{{\rm{28}}{\rm{.8}}}&{{\rm{35}}{\rm{.1}}}\end{array}\)
If \(\mathrm{\mathrm{C}_{\mathrm{p}}}\) is independent of temperature, then reaction at \(\mathrm{100^{\circ} \mathrm{C}}\) as compared to that of \(\mathrm{25^{\circ} \mathrm{C}}\) will be :

1 More endothermic
2 Less endothermic
3 More exothermic
4 Less exothermic
CHXI06:THERMODYNAMICS

369467 If \(\mathrm{38.55 \mathrm{~kJ}}\) of heat is absorbed, when 6.0 of \(\mathrm{\mathrm{O}_{2}}\) react \(\mathrm{C l F}\) according to reaction.
\(\mathrm{2 \mathrm{CIF}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{Cl}_{2}(\mathrm{~g})+\mathrm{OF}_{2}(\mathrm{~g})}\)
What is the standard enthalpy of reaction?

1 \(\mathrm{102.8 \mathrm{~kJ}}\)
2 \(\mathrm{49.80 \mathrm{~kJ}}\)
3 \(\mathrm{72.28 \mathrm{~kJ}}\)
4 \(\mathrm{205.6 \mathrm{~kJ}}\)