13. AMINES[KARNATAKA CET EXCLUSIVE]
CHEMISTRY(KCET)

285618 The method by which aniline cannot be prepared is

1 nitration of benzene followed by reduction with Sn and conc. HCl
2 degradation of benzamide with bromine in alkaline solution
3 reduction of nitrobenzene with \(\mathrm{H}_2 / \mathrm{Pd}\) in ethanol
4 potassium salt of phthalimide treated with chlorobenzene followed by the hydrolysis with aqueous NaOH solution.
CHEMISTRY(KCET)

285619 A hydrocarbon\(A\left(\mathrm{C}_4 \mathrm{H}_8\right)\) on reaction with HCl gives a compound \(B\left(\mathrm{C}_4 \mathrm{H}_9 \mathrm{Cl}\right)\) which on reaction with 1 mol of \(\mathrm{NH}_3\) gives compound \(C\left(\mathrm{C}_4 \mathrm{H}_{11} \mathrm{~N}\right)\). On reacting with \(\mathrm{NaNO}_2\) and HCl followed by treatment with
water, compound \(C\) yields an optically active compound \(D\). The compound \(D\) is
Ans:b
Exp:(b) For obtaining optically active carbon, -Cl should be present on \(2^{\circ}\) carbon.
(B)
(D)

CHEMISTRY(KCET)

285620 Which of the following has the lowest boiling point?

1 \(\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NH}_2\)
2 \(\mathrm{CH}_3-\mathrm{O}-\mathrm{CH}_3\)
3 HCOOH
4 \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}\)
CHEMISTRY(KCET)

285621

CHEMISTRY(KCET)

285618 The method by which aniline cannot be prepared is

1 nitration of benzene followed by reduction with Sn and conc. HCl
2 degradation of benzamide with bromine in alkaline solution
3 reduction of nitrobenzene with \(\mathrm{H}_2 / \mathrm{Pd}\) in ethanol
4 potassium salt of phthalimide treated with chlorobenzene followed by the hydrolysis with aqueous NaOH solution.
CHEMISTRY(KCET)

285619 A hydrocarbon\(A\left(\mathrm{C}_4 \mathrm{H}_8\right)\) on reaction with HCl gives a compound \(B\left(\mathrm{C}_4 \mathrm{H}_9 \mathrm{Cl}\right)\) which on reaction with 1 mol of \(\mathrm{NH}_3\) gives compound \(C\left(\mathrm{C}_4 \mathrm{H}_{11} \mathrm{~N}\right)\). On reacting with \(\mathrm{NaNO}_2\) and HCl followed by treatment with
water, compound \(C\) yields an optically active compound \(D\). The compound \(D\) is
Ans:b
Exp:(b) For obtaining optically active carbon, -Cl should be present on \(2^{\circ}\) carbon.
(B)
(D)

CHEMISTRY(KCET)

285620 Which of the following has the lowest boiling point?

1 \(\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NH}_2\)
2 \(\mathrm{CH}_3-\mathrm{O}-\mathrm{CH}_3\)
3 HCOOH
4 \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}\)
CHEMISTRY(KCET)

285621

CHEMISTRY(KCET)

285618 The method by which aniline cannot be prepared is

1 nitration of benzene followed by reduction with Sn and conc. HCl
2 degradation of benzamide with bromine in alkaline solution
3 reduction of nitrobenzene with \(\mathrm{H}_2 / \mathrm{Pd}\) in ethanol
4 potassium salt of phthalimide treated with chlorobenzene followed by the hydrolysis with aqueous NaOH solution.
CHEMISTRY(KCET)

285619 A hydrocarbon\(A\left(\mathrm{C}_4 \mathrm{H}_8\right)\) on reaction with HCl gives a compound \(B\left(\mathrm{C}_4 \mathrm{H}_9 \mathrm{Cl}\right)\) which on reaction with 1 mol of \(\mathrm{NH}_3\) gives compound \(C\left(\mathrm{C}_4 \mathrm{H}_{11} \mathrm{~N}\right)\). On reacting with \(\mathrm{NaNO}_2\) and HCl followed by treatment with
water, compound \(C\) yields an optically active compound \(D\). The compound \(D\) is
Ans:b
Exp:(b) For obtaining optically active carbon, -Cl should be present on \(2^{\circ}\) carbon.
(B)
(D)

CHEMISTRY(KCET)

285620 Which of the following has the lowest boiling point?

1 \(\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NH}_2\)
2 \(\mathrm{CH}_3-\mathrm{O}-\mathrm{CH}_3\)
3 HCOOH
4 \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}\)
CHEMISTRY(KCET)

285621

NEET Test Series from KOTA - 10 Papers In MS WORD WhatsApp Here
CHEMISTRY(KCET)

285618 The method by which aniline cannot be prepared is

1 nitration of benzene followed by reduction with Sn and conc. HCl
2 degradation of benzamide with bromine in alkaline solution
3 reduction of nitrobenzene with \(\mathrm{H}_2 / \mathrm{Pd}\) in ethanol
4 potassium salt of phthalimide treated with chlorobenzene followed by the hydrolysis with aqueous NaOH solution.
CHEMISTRY(KCET)

285619 A hydrocarbon\(A\left(\mathrm{C}_4 \mathrm{H}_8\right)\) on reaction with HCl gives a compound \(B\left(\mathrm{C}_4 \mathrm{H}_9 \mathrm{Cl}\right)\) which on reaction with 1 mol of \(\mathrm{NH}_3\) gives compound \(C\left(\mathrm{C}_4 \mathrm{H}_{11} \mathrm{~N}\right)\). On reacting with \(\mathrm{NaNO}_2\) and HCl followed by treatment with
water, compound \(C\) yields an optically active compound \(D\). The compound \(D\) is
Ans:b
Exp:(b) For obtaining optically active carbon, -Cl should be present on \(2^{\circ}\) carbon.
(B)
(D)

CHEMISTRY(KCET)

285620 Which of the following has the lowest boiling point?

1 \(\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NH}_2\)
2 \(\mathrm{CH}_3-\mathrm{O}-\mathrm{CH}_3\)
3 HCOOH
4 \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}\)
CHEMISTRY(KCET)

285621